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Categories: Chemistry: Inorganic Chemistry, Space: General

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A chemical element so visually striking that it was named for a goddess shows a 'Goldilocks' level of reactivity -- neither too much nor too little -- that makes it a strong candidate as a carbon scrubbing tool.

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Semiconductors are ubiquitous in modern technology, working to either enable or prevent the flow of electricity. In order to understand the potential of two-dimensional semiconductors for future computer and photovoltaic technologies, researchers investigated the bond that builds between the electrons and holes contained in these materials. By using a special method to break up the bond between electrons and holes, they were able to gain a microscopic insight into charge transfer processes across a semiconductor interface.

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Hydrogen stored in hydrogen boride sheets can be efficiently released electrochemically, report scientists. Through a series of experiments, they demonstrated that dispersing these sheets in an organic solvent and applying a small voltage is enough to release all the stored hydrogen efficiently. These findings suggest hydrogen boride sheets could soon become a safe and convenient way to store and transport hydrogen, which is a cleaner and more sustainable fuel.

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A research team has developed a tape that can be used to stick two-dimensional (2D) materials to many different surfaces, in an easy and user-friendly way. Their finding will aid research into and boost production of 2D materials for next-generation devices.

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Highly reducing or oxidizing photocatalysts are a fundamental challenge in photochemistry. Only a few transition metal complexes with Earth-abundant metal ions have so far advanced to excited state oxidants, including chromium, iron, and cobalt. All these photocatalysts require high energy light for excitation and their oxidizing power has not yet been fully exploited. Furthermore, precious and hence expensive metals are the decisive ingredients in most cases. A team of researchers has now developed a new molecular system based on the element manganese. Manganese, as opposed to precious metals, is the third most abundant metal after iron and titanium and hence widely available and very cheap.

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Astronomers have uncovered evidence of how the enigmatic gap in the size distribution of exoplanets at around two Earth radii emerges. Their computer simulations demonstrate that the migration of icy, so-called sub-Neptunes into the inner regions of their planetary systems could account for this phenomenon. As they draw closer to the central star, evaporating water ice forms an atmosphere that makes the planets appear larger than in their frozen state. Simultaneously, smaller rocky planets gradually lose a portion of their original gaseous envelope, causing their measured radius to shrink over time.

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In a win for chemistry, inventors have designed a closed-loop path for synthesizing an exceptionally tough carbon-fiber-reinforced polymer and later recovering all of its starting materials.

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For the first time, physicists have captured direct images of 'second sound,' the movement of heat sloshing back and forth within a superfluid. The results will expand scientists' understanding of heat flow in superconductors and neutron stars.

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A team of scientists has developed an artificial 'worm gut' to break down plastics, offering hope for a nature-inspired method to tackle the global plastic pollution problem.

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Heterostructures of two-dimensional materials have unique properties. Among them, lateral heterostructures, which can be used to make electronic devices, are challenging to synthesize. To address this, researchers used a new transmetallation technique to fabricate heterostructures with in-plane heterojunctions using Zn3BHT coordination nanosheet. This simple and powerful method enables the fabrication of ultrathin electronic devices for ultralarge-scale integrated circuits, marking a significant step forward for 2D materials research.

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Saturn's moon Mimas harbors a global ocean beneath its icy shell, discovered through analysis of its orbit by Cassini spacecraft data. This ocean formed just 5-15 million years ago, making Mimas a prime candidate for studying early ocean formation and potential for life. This discovery suggests life-essential conditions might exist on seemingly inactive moons, expanding our search for life beyond Earth.

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Two astrophysicists have finally solved a 20-year-old astrophysical puzzle concerning the lower-than-expected amounts of the element sulphur found in Planetary Nebulae (PNe) in comparison to expectations and measurements of other elements and other types of astrophysical objects. The expected levels of sulphur have long appeared to be 'missing in action'. However, they have now finally reported for duty after hiding in plain sight, as a result of leveraging highly accurate and reliable data.

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Carboxylic acid dianions (fumarate, maleate and succinate) play a role in coordination chemistry and to some extent also in the biochemistry of body cells. A team has now analyzed their electronic structures using RIXS in combination with DFT simulations. The results provide information not only on electronic structures but also on the relative stability of these molecules which can influence an industry's choice of carboxylate dianions, optimizing both the stability and geometry of coordination polymers.

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Think of it as recycling on the nanoscale: a tantalizing electrochemical process that can harvest carbon before it becomes air pollution and restructure it into the components of everyday products. The drive to capture airborne carbon dioxide from industrial waste and make it into fuel and plastics is gaining momentum after a team of researchers uncovered precisely how the process works and where it bogs down.

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Employing massive data sets collected through NASA's James Webb Space Telescope, astronomers are unearthing clues to conditions existing in the early universe. The team has catalogued the ages of stars in the Wolf--Lundmark--Melotte (WLM) galaxy, constructing the most detailed picture of it yet, according to the researchers. WLM, a neighbor of the Milky Way, is an active center of star formation that includes ancient stars formed 13 billion years ago.

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An international research team has succeeded in controlling the chirality of individual molecules through structural isomerization. The team also succeeded in synthesizing highly reactive diradicals with two unpaired electrons. These achievements were made using a scanning tunneling microscope probe at low temperatures.

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Lithium-sulfur batteries have exceptional theoretical capacity and performance in combination with an element in abundant supply. But the intricate reaction mechanism, particularly during discharge, has been challenging to solve. Researchers have identified the key pathways to a complex sulfur reduction reaction that leads to energy loss and reduced battery life span. The study's findings establish the whole reaction network for the first time and offer insight into electrocatalyst design for improved batteries.

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A carbon monoxide (CO)-runaway gap identified in the atmospheres of Earth-like planets can help expand the search for habitable planets. This gap, identified through atmospheric modeling, is an indicator of a CO-rich atmosphere on Earth-like planets orbiting Sun-like stars. CO is an important compound for the formation of prebiotic organic compounds, which are building blocks for more complex molecules for the formation of life.

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China's Chang'e-5, the first lunar sample return mission since the Soviet Union's Luna 24 in 1976, delivered 1.73 kilograms of regolith from the Oceanus Procellarum, a plane named for its vast size. The sample landed with CE-5 in late 2020 and included a new mineral, Changesite-(Y), as well as a perplexing combination of silica minerals. Researchers now compare CE-5's material composition to other lunar and Martian regolith samples and examine potential causes and origins for the lunar sample's unique makeup.

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Black holes not only existed at the dawn of time, they birthed new stars and supercharged galaxy formation, a new analysis of James Webb Space Telescope data suggests.