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Categories: Chemistry: Organic Chemistry, Space: General
Published Key advance for capturing carbon from the air
(via sciencedaily.com) Original source A chemical element so visually striking that it was named for a goddess shows a 'Goldilocks' level of reactivity -- neither too much nor too little -- that makes it a strong candidate as a carbon scrubbing tool.
Published Towards A Better Way of Releasing Hydrogen Stored in Hydrogen Boride Sheets
(via sciencedaily.com) Original source Hydrogen stored in hydrogen boride sheets can be efficiently released electrochemically, report scientists. Through a series of experiments, they demonstrated that dispersing these sheets in an organic solvent and applying a small voltage is enough to release all the stored hydrogen efficiently. These findings suggest hydrogen boride sheets could soon become a safe and convenient way to store and transport hydrogen, which is a cleaner and more sustainable fuel.
Published Mysterious gap in size distribution of super-earths explained
(via sciencedaily.com) Original source Astronomers have uncovered evidence of how the enigmatic gap in the size distribution of exoplanets at around two Earth radii emerges. Their computer simulations demonstrate that the migration of icy, so-called sub-Neptunes into the inner regions of their planetary systems could account for this phenomenon. As they draw closer to the central star, evaporating water ice forms an atmosphere that makes the planets appear larger than in their frozen state. Simultaneously, smaller rocky planets gradually lose a portion of their original gaseous envelope, causing their measured radius to shrink over time.
Published Physicists capture the first sounds of heat 'sloshing' in a superfluid
(via sciencedaily.com) Original source For the first time, physicists have captured direct images of 'second sound,' the movement of heat sloshing back and forth within a superfluid. The results will expand scientists' understanding of heat flow in superconductors and neutron stars.
Published Illuminating the invisible: Detecting proteins linked to diseases
(via sciencedaily.com) Original source Engineers have pioneered a new way to visualize the smallest protein clusters, skirting the physical limitations of light-powered microscopes and opening new avenues for detecting the proteins implicated in diseases like Alzheimer's and testing new treatments.
Published Greenhouse gas repurposed
(via sciencedaily.com) Original source Cutting-edge research converted waste carbon dioxide into a potential precursor for chemicals and carbon-free fuel.
Published Mimas' surprise: Tiny moon of Saturn holds young ocean beneath icy shell
(via sciencedaily.com) Original source Saturn's moon Mimas harbors a global ocean beneath its icy shell, discovered through analysis of its orbit by Cassini spacecraft data. This ocean formed just 5-15 million years ago, making Mimas a prime candidate for studying early ocean formation and potential for life. This discovery suggests life-essential conditions might exist on seemingly inactive moons, expanding our search for life beyond Earth.
Published Astrophysicists crack the case of 'disappearing' Sulphur in planetary nebulae
(via sciencedaily.com) Original source Two astrophysicists have finally solved a 20-year-old astrophysical puzzle concerning the lower-than-expected amounts of the element sulphur found in Planetary Nebulae (PNe) in comparison to expectations and measurements of other elements and other types of astrophysical objects. The expected levels of sulphur have long appeared to be 'missing in action'. However, they have now finally reported for duty after hiding in plain sight, as a result of leveraging highly accurate and reliable data.
Published BESSY II: Molecular orbitals determine stability
(via sciencedaily.com) Original source Carboxylic acid dianions (fumarate, maleate and succinate) play a role in coordination chemistry and to some extent also in the biochemistry of body cells. A team has now analyzed their electronic structures using RIXS in combination with DFT simulations. The results provide information not only on electronic structures but also on the relative stability of these molecules which can influence an industry's choice of carboxylate dianions, optimizing both the stability and geometry of coordination polymers.
Published A long, long time ago in a galaxy not so far away
(via sciencedaily.com) Original source Employing massive data sets collected through NASA's James Webb Space Telescope, astronomers are unearthing clues to conditions existing in the early universe. The team has catalogued the ages of stars in the Wolf--Lundmark--Melotte (WLM) galaxy, constructing the most detailed picture of it yet, according to the researchers. WLM, a neighbor of the Milky Way, is an active center of star formation that includes ancient stars formed 13 billion years ago.
Published Chemists decipher reaction process that could improve lithium-sulfur batteries
(via sciencedaily.com) Original source Lithium-sulfur batteries have exceptional theoretical capacity and performance in combination with an element in abundant supply. But the intricate reaction mechanism, particularly during discharge, has been challenging to solve. Researchers have identified the key pathways to a complex sulfur reduction reaction that leads to energy loss and reduced battery life span. The study's findings establish the whole reaction network for the first time and offer insight into electrocatalyst design for improved batteries.
Published Improving fuel cell durability with fatigue-resistant membranes
(via sciencedaily.com) Original source In hydrogen fuel cells, electrolyte membranes frequently undergo deformation and develop cracks during operation. A research team has recently introduced a fatigue-resistant polymer electrolyte membrane for hydrogen fuel cells, employing an interpenetrating network of Nafion (a plastic electrolyte) and perfluoropolyether (a rubbery polymer). This innovation will not only improve fuel cell vehicles but also promises advancements in diverse technologies beyond transportation, spanning applications from drones to desalination filters and backup power sources.
Published Newly discovered carbon monoxide-runaway gap can help identify habitable exoplanets
(via sciencedaily.com) Original source A carbon monoxide (CO)-runaway gap identified in the atmospheres of Earth-like planets can help expand the search for habitable planets. This gap, identified through atmospheric modeling, is an indicator of a CO-rich atmosphere on Earth-like planets orbiting Sun-like stars. CO is an important compound for the formation of prebiotic organic compounds, which are building blocks for more complex molecules for the formation of life.
Published Understanding the moon's history with Chang'e-5 sample
(via sciencedaily.com) Original source China's Chang'e-5, the first lunar sample return mission since the Soviet Union's Luna 24 in 1976, delivered 1.73 kilograms of regolith from the Oceanus Procellarum, a plane named for its vast size. The sample landed with CE-5 in late 2020 and included a new mineral, Changesite-(Y), as well as a perplexing combination of silica minerals. Researchers now compare CE-5's material composition to other lunar and Martian regolith samples and examine potential causes and origins for the lunar sample's unique makeup.
Published Which came first: Black holes or galaxies?
(via sciencedaily.com) Original source Black holes not only existed at the dawn of time, they birthed new stars and supercharged galaxy formation, a new analysis of James Webb Space Telescope data suggests.
Published Ultra-sensitive lead detector could significantly improve water quality monitoring
(via sciencedaily.com) Original source Engineers have developed an ultra-sensitive sensor made with graphene that can detect extraordinarily low concentrations of lead ions in water. The device achieves a record limit of detection of lead down to the femtomolar range, which is one million times more sensitive than previous technologies.
Published Neptune-like exoplanets can be cloudy or clear
(via sciencedaily.com) Original source Astronomers have shown new atmospheric detail in a set of 15 exoplanets similar to Neptune. While none could support humanity, a better understanding of their behavior might help us to understand why we don't have a small Neptune, while most solar systems seem to feature a planet of this class.
Published Edge-to-edge assembly technique for 2D nanosheets
(via sciencedaily.com) Original source A research team develops edge-to-edge assembly technique for 2D nanosheets.
Published Gas on the run -- ALMA spots the shadow of a molecular outflow from a quasar when the Universe was less than one billion years old
(via sciencedaily.com) Original source Theoretical predictions have been confirmed with the discovery of an outflow of molecular gas from a quasar when the Universe was less than a billion years old.
Published Intensifying the production of high-value compounds from industrial waste
(via sciencedaily.com) Original source New research demonstrates how glycerol carbonate, a biosourced industrial additive, can be produced in record time using CO2 and a by-product of the cooking oil recycling industry. The process relies on a hybrid approach combining fundamental physical organic chemistry and applied flow process technology. Two industrial wastes are thus converted into glycerol carbonate, a biosourced rising star with high added-value.