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Categories: Chemistry: Inorganic Chemistry, Environmental: Wildfires

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A simple new technique could boost the efficiency of some key chemical processing, by up to a factor of 100,000, researchers report. The reactions are at the heart of petrochemical processing, pharmaceutical manufacturing, and many other industrial chemical processes.

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Since the turn of the century, six new chemical elements have been discovered and subsequently added to the periodic table of elements, the very icon of chemistry. These new elements have high atomic numbers up to 118 and are significantly heavier than uranium, the element with the highest atomic number (92) found in larger quantities on Earth. This raises questions such as how many more of these superheavy species are waiting to be discovered, where -- if at all -- is a fundamental limit in the creation of these elements, and what are the characteristics of the so-called island of enhanced stability. In a recent review, experts in theoretical and experimental chemistry and physics of the heaviest elements and their nuclei summarize the major challenges and offer a fresh view on new superheavy elements and the limit of the periodic table.

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The properties of supramolecular polymers are dictated by the self-assembled state of the molecules. However, not much is known about the impact of morphologies on the properties of nano- and mesoscopic-scale polymeric assemblies. Recently, a research team demonstrated how terminus-free toroids and random coils derived from the same luminescent molecule show different photophysical properties. The team also presented a novel method for purifying the toroidal structure.

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You can mend a broken heart this valentine s day now that researchers invented a new hydrogel that can be used to heal damaged heart tissue and improve cancer treatments.

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Scientists have discovered that a known practice in information technology can also be applied to chemistry. Researchers found that to enhance the sampling in chemical simulations, all you need to do is stop and restart.

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A chemical element so visually striking that it was named for a goddess shows a 'Goldilocks' level of reactivity -- neither too much nor too little -- that makes it a strong candidate as a carbon scrubbing tool.

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Semiconductors are ubiquitous in modern technology, working to either enable or prevent the flow of electricity. In order to understand the potential of two-dimensional semiconductors for future computer and photovoltaic technologies, researchers investigated the bond that builds between the electrons and holes contained in these materials. By using a special method to break up the bond between electrons and holes, they were able to gain a microscopic insight into charge transfer processes across a semiconductor interface.

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Hydrogen stored in hydrogen boride sheets can be efficiently released electrochemically, report scientists. Through a series of experiments, they demonstrated that dispersing these sheets in an organic solvent and applying a small voltage is enough to release all the stored hydrogen efficiently. These findings suggest hydrogen boride sheets could soon become a safe and convenient way to store and transport hydrogen, which is a cleaner and more sustainable fuel.

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A research team has developed a tape that can be used to stick two-dimensional (2D) materials to many different surfaces, in an easy and user-friendly way. Their finding will aid research into and boost production of 2D materials for next-generation devices.

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Highly reducing or oxidizing photocatalysts are a fundamental challenge in photochemistry. Only a few transition metal complexes with Earth-abundant metal ions have so far advanced to excited state oxidants, including chromium, iron, and cobalt. All these photocatalysts require high energy light for excitation and their oxidizing power has not yet been fully exploited. Furthermore, precious and hence expensive metals are the decisive ingredients in most cases. A team of researchers has now developed a new molecular system based on the element manganese. Manganese, as opposed to precious metals, is the third most abundant metal after iron and titanium and hence widely available and very cheap.

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In a win for chemistry, inventors have designed a closed-loop path for synthesizing an exceptionally tough carbon-fiber-reinforced polymer and later recovering all of its starting materials.

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For the first time, physicists have captured direct images of 'second sound,' the movement of heat sloshing back and forth within a superfluid. The results will expand scientists' understanding of heat flow in superconductors and neutron stars.

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A team of scientists has developed an artificial 'worm gut' to break down plastics, offering hope for a nature-inspired method to tackle the global plastic pollution problem.

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Heterostructures of two-dimensional materials have unique properties. Among them, lateral heterostructures, which can be used to make electronic devices, are challenging to synthesize. To address this, researchers used a new transmetallation technique to fabricate heterostructures with in-plane heterojunctions using Zn3BHT coordination nanosheet. This simple and powerful method enables the fabrication of ultrathin electronic devices for ultralarge-scale integrated circuits, marking a significant step forward for 2D materials research.

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Carboxylic acid dianions (fumarate, maleate and succinate) play a role in coordination chemistry and to some extent also in the biochemistry of body cells. A team has now analyzed their electronic structures using RIXS in combination with DFT simulations. The results provide information not only on electronic structures but also on the relative stability of these molecules which can influence an industry's choice of carboxylate dianions, optimizing both the stability and geometry of coordination polymers.

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Think of it as recycling on the nanoscale: a tantalizing electrochemical process that can harvest carbon before it becomes air pollution and restructure it into the components of everyday products. The drive to capture airborne carbon dioxide from industrial waste and make it into fuel and plastics is gaining momentum after a team of researchers uncovered precisely how the process works and where it bogs down.

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An international research team has succeeded in controlling the chirality of individual molecules through structural isomerization. The team also succeeded in synthesizing highly reactive diradicals with two unpaired electrons. These achievements were made using a scanning tunneling microscope probe at low temperatures.

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Lithium-sulfur batteries have exceptional theoretical capacity and performance in combination with an element in abundant supply. But the intricate reaction mechanism, particularly during discharge, has been challenging to solve. Researchers have identified the key pathways to a complex sulfur reduction reaction that leads to energy loss and reduced battery life span. The study's findings establish the whole reaction network for the first time and offer insight into electrocatalyst design for improved batteries.

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A crystals expert has published an answer to how crystals are formed and how molecules become a part of them, solving an age-old mystery about crystal formation.

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Researchers pioneer dynamic manipulation and the generation principles of trion at the nanoscale using tip-enhanced cavity-spectroscopy.