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Categories: Chemistry: Inorganic Chemistry, Paleontology: Climate

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Nanoscale electron transfer (ET) in solids is fundamental to the development of multifunctional materials. However, ET in solids is not yet clearly understood. Now, researchers achieved a direct observation of solid-state ET through X-ray crystal analysis by fabricating a novel double-walled non-covalent crystalline nanotube, which can absorb electron donor molecules and maintain its crystalline structure during ET. This innovative approach can lead to the design of novel functional materials soon.

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Researchers uncover how the halogen bond can be exploited to direct sequential dynamics in the multi-functional crystals, offering crucial insights for developing ultrafast-response times for multilevel optical storage.

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Researchers develop a vastly more productive way to convert carbon dioxide into useful materials and compounds.

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Direct oxidation of methane to methanol is dominated by transition- or noble-metal-based catalysts, thus making the reaction quite expensive. To make the process efficient and cost-effective, researchers developed a transition-metal-free aluminosilicate ferrierite zeolite catalyst that can produce methanol by using methane and nitrous oxide as starting materials. The new catalyst ensures excellent methanol production efficiency, one of the highest recorded rates in the literature thus far.

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A team of researchers has created a new way to visualize crystals by peering inside their structures, akin to having X-ray vision. Their new technique -- which they aptly named 'Crystal Clear' -- combines the use of transparent particles and microscopes with lasers that allow scientists to see each unit that makes up the crystal and to create dynamic three-dimensional models.

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A team of scientists has combined paleoclimatic data from the last 2,000 years with powerful computer modeling and in-the-field research on lake sediments and tree rings to show that an understudied phenomenon, known as atmospheric blocking, has long influenced temperature swings in the Arctic. As temperatures warm due to climate change, atmospheric blocking will help drive ever-wilder weather events. The study focused on the Norwegian Arctic archipelago, Svalbard, at the edge of the Arctic Ocean.

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MRI scans are commonly used to diagnose a variety of conditions, anything from liver disease to brain tumors. But, as anyone who has been through one knows, patients must remain completely still to avoid blurring the images and requiring a new scan. A prototype device could change that. The self-powered sensor detects movement and shuts down an MRI scan in real time, improving the process for patients and technicians.

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A great armada entered the North Atlantic, launched from the cold shores of North America. But rather than ships off to war, this force was a fleet of icebergs. And the havoc it wrought was to the ocean current itself. The future of the Atlantic circulation will be determined by a tug-o-war between Greenland's decreasing ice flux and its increasing freshwater runoff.

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Researchers combined computer simulations and transmission electron microscopy experiments to better understand the ordering mobility and formation of microstructure domains in Fe3Al alloy. They were able to correlate structural changes with heat treatment to understand how particular mechanical behavior can be achieved. This is expected to allow the superelastic properties of Fe3Al to harnessed for the 3D printing of construction materials for absorbing seismic activity.

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A whaler's forgotten aerial photos from 1937 have given researchers the most detailed picture of the ice evolution in East Antarctica to date. The results show that the ice has remained stable and even grown slightly over almost a century, though scientists observe early signs of weakening. The research offers new insights that enhance predictions of ice changes and sea level rise.

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Researchers have demonstrated the ability to engineer materials that are both stiff and capable of insulating against heat. This combination of properties is extremely unusual and holds promise for a range of applications, such as the development of new thermal insulation coatings for electronic devices.

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Researchers unveil the interaction between polymeric materials and sulfide solid electrolytes.

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Researchers have developed a sustainable and controllable strategy to manipulate interfacial heat transfer, paving the way for improving the performance of eco-friendly cooling in various applications such as electronics, buildings and solar panels.

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Researchers have outlined a way to manipulate water molecules to make CO2R more efficient, with the ultimate goal of creating a clean energy loop. Through their new method, the team was able to perform CO2R with nearly 100% efficiency under mildly acidic conditions, using either gold or zinc as catalysts.

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Many of today's quantum devices rely on collections of qubits, also called spins. These quantum bits have only two energy levels, the '0' and the '1'. However, spins in real devices also interact with light and vibrations known as bosons, greatly complicating calculations. Researchers now demonstrate a way to describe spin-boson systems and use this to efficiently configure quantum devices in a desired state.

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Researchers have fabricated a device no wider than a human hair that will help physicists investigate the fundamental nature of matter and light. Their findings could also support the development of more efficient lasers, which are used in fields ranging from medicine to manufacturing.

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Scientists develop a porous structures for lithium metal batteries.

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Researchers discovered that sulfur trioxide can form products other than sulfuric acid in the atmosphere by interacting with organic and inorganic acids. These previously uncharacterized acid sulfuric anhydride products are almost certainly key contributors to atmospheric new particle formation and a way to efficiently incorporate carboxylic acids into atmospheric nanoparticles. Better prediction of aerosol formation can help curb air pollution and reduce uncertainties concerning climate change.

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Researchers have used computational design methods to develop non-metal organic porous framework materials, with potential applications in areas such as catalysis, water capture or hydrogen storage.

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Scientists have uncovered the properties of a rare earth element that was first discovered 80 years ago at the very same laboratory, opening a new pathway for the exploration of elements critical in modern technology, from medicine to space travel.