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Categories: Chemistry: Inorganic Chemistry, Offbeat: Computers and Math
Published Bulky additives could make cheaper solar cells last longer
(via sciencedaily.com) Original source An insight into preventing perovskite semiconductors from degrading quickly could help enable solar cells estimated to be two to four times cheaper than today's thin-film solar panels.
Published Molecularly designing polymer networks to control sound damping
(via sciencedaily.com) Original source The world is filled with a myriad of sounds and vibrations -- the gentle tones of a piano drifting down the hall, the relaxing purr of a cat laying on your chest, the annoying hum of the office lights. Imagine being able to selectively tune out noises of a certain frequency. Researchers have now synthesized polymer networks with two distinct architectures and crosslink points capable of dynamically exchanging polymer strands to understand how the network connectivity and bond exchange mechanisms govern the overall damping behavior of the network. The incorporation of dynamic bonds into the polymer network demonstrates excellent damping of sound and vibrations at well-defined frequencies.
Published Towards realizing eco-friendly and high-performance thermoelectric materials
(via sciencedaily.com) Original source In a new study, environmentally benign inverse-perovskites with high energy conversion efficiency have been reported by scientists with potential for practical application as thermoelectric materials (TEMs). Addressing the limitations typically faced with TEMs, such as insufficient energy conversion efficiency and environmental toxicity due to heavy elements, the new TEMs provide a suitable alternative to TEMs based on toxic elements with better thermoelectric properties than conventional eco-friendly TEMs.
Published Highly durable, nonnoble metal electrodes for hydrogen production from seawater
(via sciencedaily.com) Original source The water electrolysis method, a promising avenue for hydrogen production, relies on substantial freshwater consumption, thereby limiting the regions available with water resources required for water electrolysis . Researchers have developed highly durable electrodes without precious metals to enable direct hydrogen production from seawater.
Published Catalytic combo converts CO2 to solid carbon nanofibers
(via sciencedaily.com) Original source Scientists have developed a way to convert carbon dioxide (CO2), a potent greenhouse gas, into carbon nanofibers, materials with a wide range of unique properties and many potential long-term uses. Their strategy uses tandem electrochemical and thermochemical reactions run at relatively low temperatures and ambient pressure and could successfully lock carbon away to offset or even achieve negative carbon emissions.
Published Artificial muscle device produces force 34 times its weight
(via sciencedaily.com) Original source Scientists developed a soft fluidic switch using an ionic polymer artificial muscle that runs with ultra-low power to lift objects 34 times greater than its weight. Its light weight and small size make it applicable to various industrial fields such as soft electronics, smart textiles, and biomedical devices by controlling fluid flow with high precision, even in narrow spaces.
Published Potential solvents identified for building on moon and Mars
(via sciencedaily.com) Original source Researchers have taken the first steps toward finding liquid solvents that may someday help extract critical building materials from lunar and Martian-rock dust, an important piece in making long-term space travel possible. Using machine learning and computational modeling, researchers have found about half a dozen good candidates for solvents that can extract materials on the moon and Mars usable in 3D printing. The powerful solvents, called ionic liquids, are salts that are in a liquid state.
Published Generating stable qubits at room temperature
(via sciencedaily.com) Original source Quantum bits, or qubits, can revolutionize computing and sensing systems. However, cryogenic temperatures are required to ensure the stability of qubits. In a groundbreaking study, researchers observed stable molecular qubits of four electron spins at room temperature for the first time by suppressing the mobility of a dye molecule within a metal-organic framework. Their innovative molecular design opens doors to materials that could drive the development of quantum technologies capable of functioning in real-world conditions.
Published First direct imaging of small noble gas clusters at room temperature
(via sciencedaily.com) Original source Scientists have succeeded in the stabilization and direct imaging of small clusters of noble gas atoms at room temperature. This achievement opens up exciting possibilities for fundamental research in condensed matter physics and applications in quantum information technology. The key to this breakthrough was the confinement of noble gas atoms between two layers of graphene.
Published New study pinpoints the weaknesses in AI
(via sciencedaily.com) Original source ChatGPT and other solutions built on Machine Learning are surging. But even the most successful algorithms have limitations. Researchers have now proven mathematically that apart from simple problems it is not possible to create algorithms for AI that will always be stable. The study may lead to guidelines on how to better test algorithms and reminds us that machines do not have human intelligence after all.
Published Making an important industrial synthesis more environmentally friendly
(via sciencedaily.com) Original source Researchers have resolved a problem that has limited the environmental sustainability of peracid synthesis. By judicious choice of the solvent and light input, approximately room-temperature autoxidation of aldehydes proceeds in a manner that results in industrially useful peracids or carboxylic acids. This work is an important advance in green chemistry that will help minimize the carbon footprint of the chemical industry.
Published Researchers step closer to mimicking nature's mastery of chemistry
(via sciencedaily.com) Original source In nature, organic molecules are either left- or right-handed, but synthesizing molecules with a specific 'handedness' in a lab is hard to do. Make a drug or enzyme with the wrong 'handedness,' and it just won't work. Now chemists are getting closer to mimicking nature's chemical efficiency through computational modeling and physical experimentation.
Published Integrating dimensions to get more out of Moore's Law and advance electronics
(via sciencedaily.com) Original source Engineers suggest a way to fit more transistors on a chip by seamlessly implementing 3D integration with 2D materials.
Published Dry-cleaning fluid becomes a synthetic chemist's treasure
(via sciencedaily.com) Original source The widely used dry-cleaning and degreasing solvent perc can be converted to useful chemicals by a new clean, safe and inexpensive procedure. The discovery using on-demand UV activation may open the path to upcycling perc and thus contribute to a more sustainable society.
Published AI discovers that not every fingerprint is unique
(via sciencedaily.com) Original source Engineers have built a new AI that shatters a long-held belief in forensics -- that fingerprints from different fingers of the same person are unique. It turns out they are similar, only we've been comparing fingerprints the wrong way!
Published The reaction mechanism for catalytic ammonia production experimentally determined
(via sciencedaily.com) Original source Researchers have now been able to study the surface of iron and ruthenium catalysts when ammonia is formed from nitrogen and hydrogen. A better knowledge of the catalytic process and the possibility of finding even more efficient materials opens the door for a green transition in the currently very CO2-intensive chemical industry.
Published Epic of a molecular ion: With eyes of electrons
(via sciencedaily.com) Original source Researchers have achieved real-time capture of the ionization process and subsequent structural changes in gas-phase molecules through an enhanced mega-electronvolt ultrafast electron diffraction (MeV-UED) technique, enabling observation of faster and finer movements of ions.
Published How black silicon, a prized material used in solar cells, gets its dark, rough edge
(via sciencedaily.com) Original source Researchers have developed a new theoretical model explaining one way to make black silicon. The new etching model precisely explains how fluorine gas breaks certain bonds in the silicon more often than others, depending on the orientation of the bond at the surface. Black silicon is an important material used in solar cells, light sensors, antibacterial surfaces and many other applications.
Published The first domino falls for redox reactions
(via sciencedaily.com) Original source Transmitting an effect known as a domino reaction using redox chemistry has been achieved for the first time.
Published Researchers demonstrate that quantum entanglement and topology are inextricably linked
(via sciencedaily.com) Original source Researchers have demonstrated the remarkable ability to perturb pairs of spatially separated yet interconnected quantum entangled particles without altering their shared properties.