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Categories: Chemistry: Inorganic Chemistry, Offbeat: Paleontology and Archeology

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Quantum effects can play an important role in chemical reactions. Physicists have now observed a quantum mechanical tunneling reaction in experiments. The observation can also be described exactly in theory. The scientists provide an important reference for this fundamental effect in chemistry. It is the slowest reaction with charged particles ever observed.

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The demand for vanillin vastly outstrips the natural resources of this flavoring agent. A chemical process is thus used to produce the required large quantities of vanillin from petroleum, which is far less expensive than obtaining the substance from fermented genuine vanilla pods. Another alternative is to make vanillin from lignin, a waste product of the wood pulping industry. A team has now managed to further enhance their method of electrochemical production of vanillin from lignin in that they employ a 'green' oxidation method for this purpose.

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Engineers devised a way to purify protein drugs during manufacturing. Their approach, which uses nanoparticles to rapidly crystallize proteins, could help make protein drugs more affordable and accessible, especially in developing countries.

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Researchers have succeeded in producing very special catalysts, known as 'Lewis superacids', which can be used to break strong chemical bonds and speed up reactions. The production of these substances has, until now, proven extremely difficult. The chemists' discovery enables non-biodegradable fluorinated hydrocarbons, similar to Teflon, and possibly even climate-damaging greenhouse gases, such as sulphur hexafluoride, to be converted back into sustainable chemicals.

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Dinosaur claws had many functions, but now a team has shown some predatory dinosaurs used their claws for digging or even for display.

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Chaotic behavior is typically known from large systems: for example, from weather, from asteroids in space that are simultaneously attracted by several large celestial bodies, or from swinging pendulums that are coupled together. On the atomic scale, however, one does normally not encounter chaos -- other effects predominate. Now scientists have been able to detect clear indications of chaos on the nanometer scale -- in chemical reactions on tiny rhodium crystals.

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An unusual form of caesium atom is helping a research team unmask unknown particles that make up the Universe.

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Researchers have tested models of edge conduction with a device built on top of the semiconductor heterostructure which consists of gold gates that come close together. Voltage is applied on the gates to direct the edge states through the middle of the point contact, where they are close enough that quantum tunneling can occur between the edge states on opposite sides the sample. Changes in the electrical current flowing through the device are used to test the theorists' predictions.

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A new method to convert waste plastic to fuel and raw materials promises to help close the carbon cycle at mild temperature and with high yield.

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A recent excavation in Megiddo, Israel, unearthed the earliest example of a particular type of cranial surgery in the Ancient Near East -- and potentially one of the oldest examples of leprosy in the world.

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A new study explores 'balancing selection' by analyzing thousands of modern human genomes alongside ancient hominin groups, such as Neanderthal and Denisovan genomes. The research has 'implications for understanding human diversity, the origin of diseases, and biological trade-offs that may have shaped our evolution,' says evolutionary biologists.

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The world's oldest scientifically-confirmed European hedgehog has been found in Denmark by a citizen science project involving hundreds of volunteers. The hedgehog lived for 16 years, 7 years longer than the previous record holder.

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Researchers have reconstructed the brains and inner ears of two British spinosaurs, helping uncover how these large predatory dinosaurs interacted with their environment.

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Scientists have compared the relationship among the strength of flight bones, body mass, and the way modern birds fly to better understand the evolution of flight in birds and extinct animals, such as the Pteranodon.

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Caribou have been using the same Arctic calving grounds for more than 3,000 years. Female caribou shed their antlers within days of giving birth, leaving behind a record of their annual travels across Alaska and Canada's Yukon that persists on the cold tundra for hundreds or even thousands of years. Researchers recovered antlers that have sat undisturbed on the arctic tundra since the Bronze Age.

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Secret, coded letters penned by Mary Queen of Scots while she was imprisoned in England by her cousin Queen Elizabeth I have been uncovered by a multidisciplinary team of international codebreakers. Launched on the anniversary of Mary's execution, study reveals 50 new letters in cipher -- with some still believed missing -- shedding new light on her captivity.

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The CT-scanned skull of a 319-million-year-old fossilized fish, pulled from a coal mine in England more than a century ago, has revealed the oldest example of a well-preserved vertebrate brain.

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A new study has uncovered a new thalattosuchian -- an ancient 'sister' of modern-day crocodiles' ancestors.

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What drives crocodile evolution? Is climate a major factor or changes in sea levels? Determined to find answers to these questions, researchers discovered that while changing temperatures and rainfall had little impact on the crocodiles' gene flow over the past three million years, changes to sea levels during the Ice Age had a different effect.

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The discovery of more than 250 fossilized eggs reveals intimate details about the lives of titanosaurs in the Indian subcontinent, according to a new study.