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Categories: Chemistry: Inorganic Chemistry, Chemistry: Thermodynamics

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Some of the attractive hues of brightly colored, cloth-bound books from the Victorian era come from dyes that could pose a health risk to readers, collectors or librarians. The latest research on these 'poison books' used three techniques -- including one that hasn't previously been applied to books -- to assess dangerous dyes in a university collection and found some volumes had levels that might be unsafe.

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A view into how nanoscale building blocks can rearrange into different organized structures on command is now possible with an approach that combines an electron microscope, a small sample holder with microscopic channels, and computer simulations, according to a new study.

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Researchers developed a new method known as flash-within-flash Joule heating (FWF) that could transform the synthesis of high-quality solid-state materials, offering a cleaner, faster and more sustainable manufacturing process.

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Researchers developed a novel reagent that enhances the precision of drug synthesis. This innovative method introduces a new sulfur fluoride exchange (SuFEx) reagent that allows for highly controlled production of crucial sulfur-based molecules, including sulfinamides, sulfonimidamides and sulfoximines.

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A groundbreaking technology has been unveiled that improves the efficiency of thermoelectric materials, which are key in converting waste heat into electricity, by altering their geometry to resemble an hourglass. Unlike previous research that solely depended on the material properties of thermoelectric substances, this new approach is expected to have widespread applications in thermoelectric power generation.

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Society relies heavily on diverse fluidic technologies. The ability to precisely capture and release various chemical and biological fluids plays a fundamental role in many fields. A long-standing challenge is to design a platform that enables the switchable capture and release of liquids with precise spatial and temporal control and accurate volumes of the fluid. Recently, researchers have invented a new method to effectively overcome this challenge.

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A study expands understanding on how electrons move through the conductive parts of complex fluids found in electrochemical devices such as batteries. This work can help overcome existing knowledge gaps for engineers seeking to improve the performance of these devices.

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Researchers have demonstrated a technique for printing thin metal oxide films at room temperature, and have used the technique to create transparent, flexible circuits that are both robust and able to function at high temperatures.

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Electron transfer is enhanced by minimal energetic driving force at the organic-semiconductor interface in upconversion (UC) organic light emitting diodes (OLEDs), resulting in efficient blue UC-OLEDs with low extremely turn-on voltage, scientists show. Their findings deepen the understanding of electron transfer mechanisms in organic optoelectronic devices and can lead to the development of efficient new optoelectronics without energy loss.

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As global warming intensifies, people increasingly suffer from extreme heat. For those working in a high-temperature environment indoors or outdoors, keeping thermally comfortable becomes particularly crucial. A team has now developed thermally-insulated and breathable soft robotic clothing that can automatically adapt to changing ambient temperatures, thereby helping to ensure worker safety in hot environments.

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Scientists recently discovered a one-dimensional nanoscale material whose color changes as temperature changes.

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Noble gases have a reputation for being unreactive, inert elements, but more than 60 years ago Neil Bartlett demonstrated the first way to bond xenon. He created XePtF6, an orange-yellow solid. Because it's difficult to grow sufficiently large crystals that contain noble gases, some of their structures -- and therefore functions -- remain elusive. Now, researchers have successfully examined tiny crystallites of noble gas compounds. They report structures of multiple xenon compounds.

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Linked to cardiovascular and respiratory diseases in people, nanoplastics continue to build up, largely unnoticed, in the world's bodies of water. The challenge remains to develop a cost-effective solution to get rid of nanoplastics while leaving clean water behind. That's where Mizzou comes in. Recently, researchers created a new liquid-based solution that eliminates more than 98% of these microscopic plastic particles from water.

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Chemists developed a way to synthesize complex molecules called oligocyclotryptamines, originally found in plants, which could hold potential as antibiotics, analgesics, or anticancer drugs.

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A team has reported the first demonstration of selective electrochemical separation driven by halogen bonding. This was achieved by engineering a polymer that modulates the charge density on a halogen atom when electricity is applied. The polymer then attracts only certain targets -- such as halides, oxyanions, and even organic molecules -- from organic solutions, a feature that has important implications for pharmaceuticals and chemical synthesis processes.

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Scientists have made a groundbreaking discovery in the field of nanotechnology. They have developed a novel microscopy method that allows for the unprecedented visualization of nanostructures and their optical properties.

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Researchers have introduced a new advancement in the fight against climate change. Their study showcases a novel method for understanding the mechanisms of carbon dioxide re-utilization leading to fuels and chemicals. This work paves the road for the further optimization of this catalytic process driven by renewable electricity.

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A research team has developed full-color fiber light-emitting diodes utilizing perovskite quantum wires (PeQWs), paving the way for innovative wearable lighting and display devices.

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The movement of radiant heat -- felt when a hot surface warms our bodies and homes -- between buildings and their surroundings at ground level makes buildings with less skyward-facing surfaces harder to cool. A research team has demonstrated a new passive cooling technology that coats walls and windows with materials that can better manage heat movement between buildings and their surroundings at ground level. Findings could reduce the reliance on air conditioning and provide a more environmentally friendly, low-cost and scalable option for low-income communities with limited or no access to cooling and heating systems.

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Solid-state electrolytes have been explored for decades for use in energy storage systems and in the pursuit of solid-state batteries. These materials are safer alternatives to the traditional liquid electrolyte -- a solution that allows ions to move within the cell -- used in batteries today. However, new concepts are needed to push the performance of current solid polymer electrolytes to be viable for next generation materials.