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Categories: Chemistry: Inorganic Chemistry, Chemistry: Thermodynamics

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To ensure that vaccines provide strong and lasting immunization, it is often necessary to supplement the actual vaccine (antigen) with additives that stimulate the immune system: adjuvants. Today, only a few substances have been approved for use as adjuvants. A research team has now introduced a spectrum of potential adjuvants. They started with the immune stimulant ?-glactosyl ceramide (?-GalCer) and synthesized many different variants from a set of four building blocks.

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Found in fishing nets, carpet, clothing, Nylon-6 is a major contributor to plastic pollution, including ocean pollution. Now, chemists have developed a new catalyst that quickly, cleanly and completely breaks down Nylon-6 in a matter of minutes -- without generating harmful byproducts. Even better: The process does not require toxic solvents, expensive materials or extreme conditions, making it practical for everyday applications. In experiments, the new process recovered 99% of the polymer's building blocks, which can then be upcycled into higher-value products.

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Researchers have developed an AI model that can predict where a drug molecule can be chemically altered.

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Used lithium-ion batteries from cell phones, laptops and a growing number of electric vehicles are piling up, but options for recycling them remain limited mostly to burning or chemically dissolving shredded batteries. Researchers have improved on approaches that dissolve the battery in a liquid solution in order to reduce the amount of hazardous chemicals used in the process. This simple, efficient and environmentally-friendly solution overcomes the main obstacles presented by previous approaches.

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Researchers have demonstrated a compact particle accelerator less than 20 meters long that produces an electron beam with an energy of 10 billion electron volts (10 GeV). There are only two other accelerators currently operating in the U.S. that can reach such high electron energies, but both are approximately 3 kilometers long. This type of accelerator is called a wakefield laser accelerator.

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Salt batteries can store summer heat to be used in winter, but which salt works best for the purpose?

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Researchers have devised a way to produce chemicals used in medicine and agriculture for a fraction of the usual cost. Using oxygen as a reagent and copper as a catalyst to break organic molecules' carbon-carbon bonds and convert them into amines, which are widely used in pharmaceuticals. Traditional metal catalysis uses expensive metals such as platinum, silver, gold and palladium, but the researchers used oxygen and copper -- an abundant base metal.

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Researchers create transistors combining silicon with biological silk, using common microprocessor manufacturing methods. The silk protein can be easily modified with other chemical and biological molecules to change its properties, leading to circuits that respond to biology and the environment.

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Donor doping into a mother material with disordered intrinsic oxygen vacancies, instead of the widely used strategy of acceptor doping into a material without oxygen vacancies, can greatly enhance the conductivity and stability of perovskite-type proton conductors at intermediate and low temperatures of 250--400 °C.

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Glass is a fundamental material. Yet its atomic structure still baffles scientists to this day. Researchers have developed a new way to quantify ring shapes in chemically bonded networks of glass, chipping away at some of the mysteries behind glass's atomic structure.  

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Global measurements and model calculations show that the complex relationship between the chemistry and climate impact of aerosol particles can be successfully captured by a simple formula.

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Bio-based plastics often end up in recycling streams because they look and feel like conventional plastic, but the contamination of these compostable products makes it much harder to generate functional material out of recycled plastic. Scientists have now developed a biology-driven process to convert these mixtures into a new biodegradable material that can be used to make fresh products. The scientists believe the process could also enable a new field of biomanufacturing wherein valuable chemicals and even medicines are made from microbes feeding off of plastic waste.

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Chemists have developed a bioinspired supramolecular approach to convert photo-switchable molecules from their stable state into metastable one with low-energy red light. Their work enables fast, highly selective, and efficient switching, providing new tools for energy storage, activation of drugs with light, and sensing applications.

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A novel measurement technique has been developed to visualize the fluid flow and distribution within two droplets levitated and coalesced in space using fluorescence-emitting particles. This technique enabled the estimation of fluid motion within each droplet, thereby revealing the internal flow caused by surface vibration when the droplet merging promotes fluid mixing.

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A team of pioneering researchers has made a significant leap forward in the complex world of molecular chemistry. Their focus? Azaarenes, unique molecular puzzle pieces crucial to many everyday products, from eco-friendly agrochemicals to essential medicines. The team developed an innovative way to modify these molecules using light-powered enzymes -- a groundbreaking discovery that holds promise for new industrially relevant chemical reactions and sustainable energy solutions.

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As power generation from sources like solar and wind increases, along with the introduction of devices such as heat pumps and batteries, a new optimization tool will help the UK plan for a greener electricity network.   The researchers developed an algorithm to model how these smaller networks distributed electricity -- factoring in how local grids could become unbalanced by adding too many heat pumps in a single area or generating more electricity than the grid could accept.  

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Protein cages found in nature within microbes help weather its contents from the harsh intracellular environment -- an observation with many bioengineering applications. Researchers recently developed an innovative bioengineering approach using genetically modified bacteria; these bacteria can incorporate protein cages around protein crystals. This in-cell biosynthesis method efficiently produces highly customized protein complexes, which could find applications as advanced solid catalysts and functionalized nanomaterials.

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Electrochemical catalysts used in water splitting often show poor performance due to low electrical conductance of (oxy)hydroxide species produced in situ. To overcome this challenge, researchers have now designed an electrode with Schottky Junction formed at the interface of metallic Ni-W5N4 and semiconducting NiFeOOH. The proposed electrode shows excellent catalytic activity and can facilitate industrial seawater splitting continuously for 10 days.

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A research team has now directly measured the so-called Kondo effect, which governs the behavior of magnetic atoms surrounded by a sea of electrons: New observations with a scanning tunneling microscope reveal the effect in one-dimensional wires floating on graphene. 

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A new technique offers a safe, reliable, and high-throughput way to dynamically characterize microscale metamaterials. The method could speed up the development of acoustic lenses, impact-resistant films, and other futuristic materials.