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Categories: Chemistry: Thermodynamics, Geoscience: Volcanoes

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A 'back-projection' technique reveals new details of the volcanic eruption in Tonga that literally shook the world.

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Inspired by sea cucumbers, engineers have designed miniature robots that rapidly and reversibly shift between liquid and solid states. On top of being able to shape-shift, the robots are magnetic and can conduct electricity. The researchers put the robots through an obstacle course of mobility and shape-morphing tests.

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When two microscopic systems are entangled, their properties are linked to each other irrespective of the physical distance between the two. Manipulating this uniquely quantum phenomenon is what allows for quantum cryptography, communication, and computation. While parallels have been drawn between quantum entanglement and the classical physics of heat, new research demonstrates the limits of this comparison. Entanglement is even richer than we have given it credit for.

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A new study finds that microorganisms live in richly diverse and interdependent communities in high-temperature geothermal environments in the deep sea. By constructing genomes of 3,635 Bacteria and Archaea from 40 different rock communities, researchers discovered at least 500 new genera and have evidence for two new phyla. Samples from the deep-sea Brothers volcano were especially enriched with different kinds of microorganisms, many endemic to the volcano. The genomic data from this study also showed that many of these organisms depend on one another for survival. Some microorganisms cannot metabolize all of the nutrients they need to survive so they rely on nutrients created by other species in a process known as a 'metabolic handoff.'

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On the short-lived island of Hunga Tonga Hunga Ha'apai, researchers discovered a unique microbial community that metabolizes sulfur and atmospheric gases, similar to organisms found in deep sea vents or hot springs.

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Flexible compounds made with Nobel-winning click chemistry can be used in energy-storing capacitors at high temperatures and electric fields.

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Despite their huge potential, the way perovskite solar cells respond to external stimuli -- such as heat or moisture -- has a considerable impact on their stability. Researchers have identified the cause of degradation and developed a technique to improve stability, bringing us closer to widespread adoption of these cost-effective and efficient solar cells.

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Synthesizing ammonia, the key ingredient in fertilizer, is energy intensive and a significant contributor to greenhouse gas warming of the planet. Chemists designed and synthesized porous materials -- metal-organic frameworks, or MOFs -- that bind and release ammonia at more moderate pressures and temperatures than the standard Haber-Bosch process for making ammonia. The MOF doesn't bind to any of the reactants, making capture and release of ammonia less energy intensive and greener.

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Pyroelectric catalysis (pyro-catalysis) can convert environmental temperature fluctuations into clean chemical energy, like hydrogen. However, compared with the more common catalysis strategy, such as photocatalysis, pyro-catalysis is inefficient due to slow temperature changes in the ambient environment. Recently, a team has triggered a significantly faster and more efficient pyro-catalytic reaction using localized plasmonic heat sources to rapidly and efficiently heat up the pyro-catalytic material and allow it to cool down. The findings open up new avenues for efficient catalysis for biological applications, pollutant treatment and clean energy production.

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Multinuclear organometallic junctions might be the key to realizing high-performance thermoelectric devices at the nanoscale. The unique electronic structure of organometallic ruthenium alkynyl complexes allowed the researchers to achieve unprecedented heat-to-electricity conversion performance in molecular junctions, paving the way to molecular-scale temperature sensors and thermal energy harvesters.

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A new kind of solar panel has achieved 9% efficiency in converting water into hydrogen and oxygen--mimicking a crucial step in natural photosynthesis. Outdoors, it represents a major leap in the technology, nearly 10 times more efficient than solar water-splitting experiments of its kind.

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Researchers have developed a new kind of heating and cooling method that they have named the ionocaloric refrigeration cycle. They hope the technique will someday help phase out refrigerants that contribute to global warming and provide safe, efficient cooling and heating for homes.

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A team is collecting data that will be used to create models that can help improve lava flow forecasting tools that are useful in determining how hazards impact populations. One such tool, known as MOLASSES, is a simulation engine that forecasts inundation areas of lava flow.

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The main gases released by volcanoes are water vapor, carbon dioxide, and sulfur dioxide. Analyzing these gases is one of the best ways of obtaining information on volcanic systems and the magmatic processes that are underway. The ratio of carbon dioxide levels to those of sulfur dioxide can even reveal the likelihood of an impending eruption. Drones are employed to carry the necessary analytical systems to the site of activity.

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A new study demonstrates a new, counterintuitive way to protect atomically-thin electronics -- adding vibrations, to reduce vibrations. By squeezing a liquid-metal gallium droplet, graphene devices are painted with a protective coating of gallium-oxide that can cover millimeter-wide scales, making it potentially applicable for industrial large-scale fabrication. The new technique improves device performance as well as protecting 2D materials from thermal vibration in neighboring materials.

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Researchers have clarified the chemical compatibility between high temperature liquid metal tin (Sn) and reduced activation ferritic martensitic, a candidate structural material for fusion reactors. This discovery has paved the way for the development of a liquid metal tin divertor, which is an advanced heat-removal component of fusion reactors. A device called a divertor is installed in the fusion reactors to maintain the purity of the plasma. For divertors, there has been demand for liquid metals that can withstand extremely large heat loads from high-temperature plasma.

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Two seemingly different areas of physics are related in subtle ways: Quantum theory and thermodynamics. How can the laws of thermodynamics arise from the laws of quantum physics? This question has now been pursued with computer simulations, which showed that chaos plays a crucial role: Only where chaos prevails do the well-known rules of thermodynamics follow from quantum physics.

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The powerful volcanic eruption in January 2022 created ripple effects throughout the world's atmosphere and oceans. Analysis of the Hunga Tonga eruption shows how signals from the ionosphere could help monitor future volcanoes and tsunamis.

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Researchers have developed a new transparent gold nanocoating that harnesses sunlight to heat the lenses of glasses, thereby preventing them from fogging in humid conditions. This coating could potentially also be applied to car windshields.

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A polymer-based electrolyte makes for batteries that keep working -- and don't catch fire -- when heated to over 140 degrees F.