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Categories: Chemistry: Thermodynamics

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Natural gas furnaces not only heat your home, they also produce a lot of pollution. Even modern high-efficiency condensing furnaces produce significant amounts of corrosive acidic condensation and unhealthy levels of nitrogen oxides, carbon monoxide, hydrocarbons and methane. These emissions are typically vented into the atmosphere and end up polluting our soil, water and air. Scientists have developed an affordable add-on technology that removes more than 99.9% of acidic gases and other emissions to produce an ultraclean natural gas furnace. This acidic gas reduction, or AGR, technology can also be added to other natural gas-driven equipment such as water heaters, commercial boilers and industrial furnaces.

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Researchers chiral phonons to convert wasted heat into spin information -- without needing magnetic materials. The finding could lead to new classes of less expensive, energy-efficient spintronic devices for use in applications ranging from computational memory to power grids.

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Hydrogen fuel could be a more viable alternative to traditional fossil fuels, according to University of Surrey researchers who have found that a type of metal-free catalysts could contribute to the development of cost-effective and sustainable hydrogen production technologies.

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Scientists have found the secret behind a property of solid materials known as ferroelectrics, showing that quasiparticles moving in wave-like patterns among vibrating atoms carry enough heat to turn the material into a thermal switch when an electrical field is applied externally.

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Energy-efficient ways of cooling buildings and vehicles will be required in a changing climate. Researchers have now shown that electrical tuning of passive radiative cooling can be used to control temperatures of a material at ambient temperatures and air pressure.

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Researchers already knew the atoms in perovskites react favorably to light. Now they've seen precisely how the atoms move when the 2D materials are excited with light. Their study details the first direct measurement of structural dynamics under light-induced excitation in 2D perovskites.

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Inspired by sea cucumbers, engineers have designed miniature robots that rapidly and reversibly shift between liquid and solid states. On top of being able to shape-shift, the robots are magnetic and can conduct electricity. The researchers put the robots through an obstacle course of mobility and shape-morphing tests.

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When two microscopic systems are entangled, their properties are linked to each other irrespective of the physical distance between the two. Manipulating this uniquely quantum phenomenon is what allows for quantum cryptography, communication, and computation. While parallels have been drawn between quantum entanglement and the classical physics of heat, new research demonstrates the limits of this comparison. Entanglement is even richer than we have given it credit for.

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Flexible compounds made with Nobel-winning click chemistry can be used in energy-storing capacitors at high temperatures and electric fields.

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Despite their huge potential, the way perovskite solar cells respond to external stimuli -- such as heat or moisture -- has a considerable impact on their stability. Researchers have identified the cause of degradation and developed a technique to improve stability, bringing us closer to widespread adoption of these cost-effective and efficient solar cells.

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Synthesizing ammonia, the key ingredient in fertilizer, is energy intensive and a significant contributor to greenhouse gas warming of the planet. Chemists designed and synthesized porous materials -- metal-organic frameworks, or MOFs -- that bind and release ammonia at more moderate pressures and temperatures than the standard Haber-Bosch process for making ammonia. The MOF doesn't bind to any of the reactants, making capture and release of ammonia less energy intensive and greener.

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Pyroelectric catalysis (pyro-catalysis) can convert environmental temperature fluctuations into clean chemical energy, like hydrogen. However, compared with the more common catalysis strategy, such as photocatalysis, pyro-catalysis is inefficient due to slow temperature changes in the ambient environment. Recently, a team has triggered a significantly faster and more efficient pyro-catalytic reaction using localized plasmonic heat sources to rapidly and efficiently heat up the pyro-catalytic material and allow it to cool down. The findings open up new avenues for efficient catalysis for biological applications, pollutant treatment and clean energy production.

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Multinuclear organometallic junctions might be the key to realizing high-performance thermoelectric devices at the nanoscale. The unique electronic structure of organometallic ruthenium alkynyl complexes allowed the researchers to achieve unprecedented heat-to-electricity conversion performance in molecular junctions, paving the way to molecular-scale temperature sensors and thermal energy harvesters.

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A new kind of solar panel has achieved 9% efficiency in converting water into hydrogen and oxygen--mimicking a crucial step in natural photosynthesis. Outdoors, it represents a major leap in the technology, nearly 10 times more efficient than solar water-splitting experiments of its kind.

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Researchers have developed a new kind of heating and cooling method that they have named the ionocaloric refrigeration cycle. They hope the technique will someday help phase out refrigerants that contribute to global warming and provide safe, efficient cooling and heating for homes.

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A new study demonstrates a new, counterintuitive way to protect atomically-thin electronics -- adding vibrations, to reduce vibrations. By squeezing a liquid-metal gallium droplet, graphene devices are painted with a protective coating of gallium-oxide that can cover millimeter-wide scales, making it potentially applicable for industrial large-scale fabrication. The new technique improves device performance as well as protecting 2D materials from thermal vibration in neighboring materials.

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Researchers have clarified the chemical compatibility between high temperature liquid metal tin (Sn) and reduced activation ferritic martensitic, a candidate structural material for fusion reactors. This discovery has paved the way for the development of a liquid metal tin divertor, which is an advanced heat-removal component of fusion reactors. A device called a divertor is installed in the fusion reactors to maintain the purity of the plasma. For divertors, there has been demand for liquid metals that can withstand extremely large heat loads from high-temperature plasma.

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Two seemingly different areas of physics are related in subtle ways: Quantum theory and thermodynamics. How can the laws of thermodynamics arise from the laws of quantum physics? This question has now been pursued with computer simulations, which showed that chaos plays a crucial role: Only where chaos prevails do the well-known rules of thermodynamics follow from quantum physics.

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Researchers have developed a new transparent gold nanocoating that harnesses sunlight to heat the lenses of glasses, thereby preventing them from fogging in humid conditions. This coating could potentially also be applied to car windshields.

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A polymer-based electrolyte makes for batteries that keep working -- and don't catch fire -- when heated to over 140 degrees F.