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Categories: Chemistry: Organic Chemistry, Energy: Fossil Fuels

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Researchers have resolved a problem that has limited the environmental sustainability of peracid synthesis. By judicious choice of the solvent and light input, approximately room-temperature autoxidation of aldehydes proceeds in a manner that results in industrially useful peracids or carboxylic acids. This work is an important advance in green chemistry that will help minimize the carbon footprint of the chemical industry.

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In nature, organic molecules are either left- or right-handed, but synthesizing molecules with a specific 'handedness' in a lab is hard to do. Make a drug or enzyme with the wrong 'handedness,' and it just won't work. Now chemists are getting closer to mimicking nature's chemical efficiency through computational modeling and physical experimentation.

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The widely used dry-cleaning and degreasing solvent perc can be converted to useful chemicals by a new clean, safe and inexpensive procedure. The discovery using on-demand UV activation may open the path to upcycling perc and thus contribute to a more sustainable society.

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New research has revealed how light can be used to destroy infectious coronavirus particles that contaminate surfaces. Scientists are interested in how environments, such as surgeries, can be thoroughly disinfected from viruses such as SARS-CoV-2 that caused the COVID-19 pandemic.

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A new discovery takes its inspiration from Greek mythology. The compound is described as a chimera, because it battles a toxic cause of Parkinson's in two ways.

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A study has found that green ammonia could be used to fulfill the fuel demands of over 60% of global shipping by targeting just the top 10 regional fuel ports. Researchers looked at the production costs of ammonia which are similar to very low sulphur fuels, and concluded that the fuel could be a viable option to help decarbonize international shipping by 2050.

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Chemists have presented a new approach in which a single carbon atom is inserted into the carbon skeleton of cyclic compounds in order to adjust the ring size. The method could be relevant, for example, for the production of active ingredients in new pharmaceutical products.

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Hydrogen energy has emerged as a promising alternative to fossil fuels, offering a clean and sustainable energy source. However, the development of low-cost and efficient catalysts for hydrogen evolution reaction remains a crucial challenge. Scientists have recently developed a novel strategy to engineer stable and efficient ultrathin nanosheet catalysts by forming Turing structures with multiple nanotwin crystals. This innovative discovery paves the way for enhanced catalyst performance for green hydrogen production.

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To address natural resource scarcity, pollution, and other harmful effects of climate change, some scientists and policymakers emphasize the adoption of input-efficient technologies like water-saving devices and fuel-saving stoves. Proponents often refer to these input-efficient technologies as 'win-win,' for the benefits to their users and to the environment, and lament their low adoption rates by consumers, in what they call an 'efficiency paradox.' A new paper examines this paradox and finds that the benefits to consumers from input-efficiency adoption are, on average, negative.

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With a split-second muscle contraction, the greater blue-ringed octopus can change the size and color of the namesake patterns on its skin for purposes of deception, camouflage and signaling. Researchers have drawn inspiration from this natural wonder to develop a technological platform with similar capabilities for use in a variety of fields, including the military, medicine, robotics and sustainable energy.

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Engineers have succeeded in implementing a stretchable organic solar cell by applying a newly developed polymer material that demonstrated the world's highest photovoltaic conversion efficiency (19%) while functioning even when stretched for more than 40% of its original state. This new conductive polymer has high photovoltaic properties that can be stretched like rubber. The newly developed polymer is expected to play a role as a power source for next-generation wearable electronic devices.

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Coal is an abundant resource in the United States that has, unfortunately, contributed to climate change through its use as a fossil fuel. As the country transitions to other means of energy production, it will be important to consider and reevaluate coal's economic role. Coal may actually play a vital role in next-generation electronic devices.

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Chemists found a way to use electricity to boost a type of chemical reaction often used in synthesizing new candidates for pharmaceutical drugs. The research is an advance in the field of electrochemistry and shows a path forward to designing and controlling reactions -- and making them more sustainable.

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Scientists develop a new, high-resolution technique for finding potential therapeutic targets on proteins in living cells. The findings could lead to more targeted therapeutics for nearly any human disease.

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Aptamers, nucleic acids capable of selectively binding to viruses, proteins, ions, small molecules, and various other targets, are garnering attention in drug development as potential antibody substitutes for their thermal and chemical stability as well as ability to inhibit specific enzymes or target proteins through three-dimensional binding. They also hold promise for swift diagnoses of colon cancer and other challenging diseases by targeting elusive biomarkers. Despite their utility, these aptamers are susceptible to easy degradation by multiple enzymes, presenting a significant challenge.

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A research team has achieved a significant breakthrough in the field of organic semiconductors. Their successful synthesis and characterization of a novel molecule called 'BNBN anthracene' has opened up new possibilities for the development of advanced electronic devices.

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Researchers have discovered that molecules experience non-reciprocal interactions without external forces. Fundamental forces such as gravity and electromagnetism are reciprocal, where two objects are attracted to each other or are repelled by each other. In our everyday experience, however, interactions don t seem to follow this reciprocal law.

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Researchers have developed a solid electrolyte for transporting hydride ions at room temperature. This breakthrough means that the full advantages of hydrogen-based solid-state batteries and fuel cells can be had without the need for constant hydration. This will reduce their complexity and cost, which is essential for advancing towards a practical hydrogen-based energy economy.

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Lights could soon use the full color suite of perfectly efficient organic light-emitting diodes, or OLEDs, that last tens of thousands of hours. The new phosphorescent OLEDs, commonly referred to as PHOLEDs, can maintain 90% of the blue light intensity for 10-14 times longer than other designs that emit similar deep blue colors. That kind of lifespan could finally make blue PHOLEDs hardy enough to be commercially viable in lights that meet the Department of Energy's 50,000-hour lifetime target. Without a stable blue PHOLED, OLED lights need to use less-efficient technology to create white light.

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Scientists have developed a method to extract the spectral density for molecules in solvent using simple resonance Raman experiments -- a method that captures the full complexity of chemical environments.