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Categories: Chemistry: General, Physics: Quantum Physics

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Chemistry: Biochemistry Chemistry: General Chemistry: Inorganic Chemistry Chemistry: Organic Chemistry
Published

BESSY II: Molecular orbitals determine stability      (via sciencedaily.com)     Original source 

Carboxylic acid dianions (fumarate, maleate and succinate) play a role in coordination chemistry and to some extent also in the biochemistry of body cells. A team has now analyzed their electronic structures using RIXS in combination with DFT simulations. The results provide information not only on electronic structures but also on the relative stability of these molecules which can influence an industry's choice of carboxylate dianions, optimizing both the stability and geometry of coordination polymers.

Chemistry: General Chemistry: Inorganic Chemistry Engineering: Nanotechnology Environmental: General Geoscience: Environmental Issues Geoscience: Geochemistry
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Researchers reveal elusive bottleneck holding back global effort to convert carbon dioxide waste into usable products      (via sciencedaily.com)     Original source 

Think of it as recycling on the nanoscale: a tantalizing electrochemical process that can harvest carbon before it becomes air pollution and restructure it into the components of everyday products. The drive to capture airborne carbon dioxide from industrial waste and make it into fuel and plastics is gaining momentum after a team of researchers uncovered precisely how the process works and where it bogs down.

Chemistry: Biochemistry Chemistry: General Chemistry: Inorganic Chemistry Engineering: Nanotechnology Physics: General Physics: Quantum Computing Physics: Quantum Physics
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Structural isomerization of individual molecules using a scanning tunneling microscope probe      (via sciencedaily.com)     Original source 

An international research team has succeeded in controlling the chirality of individual molecules through structural isomerization. The team also succeeded in synthesizing highly reactive diradicals with two unpaired electrons. These achievements were made using a scanning tunneling microscope probe at low temperatures.

Chemistry: Biochemistry Chemistry: General Chemistry: Inorganic Chemistry Chemistry: Organic Chemistry Energy: Batteries
Published

Chemists decipher reaction process that could improve lithium-sulfur batteries      (via sciencedaily.com)     Original source 

Lithium-sulfur batteries have exceptional theoretical capacity and performance in combination with an element in abundant supply. But the intricate reaction mechanism, particularly during discharge, has been challenging to solve. Researchers have identified the key pathways to a complex sulfur reduction reaction that leads to energy loss and reduced battery life span. The study's findings establish the whole reaction network for the first time and offer insight into electrocatalyst design for improved batteries.

Chemistry: General Engineering: Robotics Research
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GPT-3 transforms chemical research      (via sciencedaily.com)     Original source 

Scientists demonstrate how GPT-3 can transform chemical analysis, making it faster and more user-friendly.

Chemistry: Biochemistry Chemistry: General Chemistry: Inorganic Chemistry
Published

Solving an age-old mystery about crystal formation      (via sciencedaily.com)     Original source 

A crystals expert has published an answer to how crystals are formed and how molecules become a part of them, solving an age-old mystery about crystal formation.

Chemistry: General Chemistry: Inorganic Chemistry Engineering: Nanotechnology Physics: General Physics: Optics
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Unveiling the generation principles of charged particles 'trion' in 2D semiconductor      (via sciencedaily.com)     Original source 

Researchers pioneer dynamic manipulation and the generation principles of trion at the nanoscale using tip-enhanced cavity-spectroscopy.

Chemistry: General Energy: Alternative Fuels Energy: Fossil Fuels Environmental: General Environmental: Water Geoscience: Environmental Issues Geoscience: Geochemistry
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Ammonia attracts the shipping industry, but researchers warn of its risks      (via sciencedaily.com)     Original source 

Switching to ammonia as a marine fuel, with the goal of decarbonization, can instead create entirely new problems. This is shown in a study where researchers carried out life cycle analyses for batteries and for three electrofuels including ammonia. Eutrophication and acidification are some of the environmental problems that can be traced to the use of ammonia -- as well as emissions of laughing gas, which is a very potent greenhouse gas.

Biology: Cell Biology Biology: Microbiology Chemistry: General Offbeat: General Offbeat: Plants and Animals
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Scientists 'break the mould' by creating new colors of 'blue cheese'      (via sciencedaily.com)     Original source 

Experts have discovered how to create different colors of blue cheese. After discovering how the classic blue-green veining is created, a team of experts were able to create a variety of different fungal strains that could be used to make cheese with colors ranging from white to yellow-green to red-brown-pink and light and dark blues.

Chemistry: Inorganic Chemistry Computer Science: Quantum Computers Engineering: Nanotechnology Physics: General Physics: Quantum Computing Physics: Quantum Physics
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Direct view of tantalum oxidation that impedes qubit coherence      (via sciencedaily.com)     Original source 

Scientists have used a combination of scanning transmission electron microscopy (STEM) and computational modeling to get a closer look and deeper understanding of tantalum oxide. When this amorphous oxide layer forms on the surface of tantalum -- a superconductor that shows great promise for making the 'qubit' building blocks of a quantum computer -- it can impede the material's ability to retain quantum information. Learning how the oxide forms may offer clues as to why this happens -- and potentially point to ways to prevent quantum coherence loss.

Computer Science: Quantum Computers Physics: General Physics: Quantum Computing Physics: Quantum Physics
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Magnesium protects tantalum, a promising material for making qubits      (via sciencedaily.com)     Original source 

Scientists have discovered that adding a layer of magnesium improves the properties of tantalum, a superconducting material that shows great promise for building qubits, the basis of quantum computers. The scientists show that a thin layer of magnesium keeps tantalum from oxidizing, improves its purity, and raises the temperature at which it operates as a superconductor. All three may increase tantalum's ability to hold onto quantum information in qubits.

Computer Science: General Computer Science: Quantum Computers Physics: General Physics: Optics Physics: Quantum Computing Physics: Quantum Physics
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A physical qubit with built-in error correction      (via sciencedaily.com)     Original source 

Researchers have succeeded in generating a logical qubit from a single light pulse that has the inherent capacity to correct errors.

Chemistry: General Chemistry: Organic Chemistry Engineering: Nanotechnology
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Edge-to-edge assembly technique for 2D nanosheets      (via sciencedaily.com)     Original source 

A research team develops edge-to-edge assembly technique for 2D nanosheets.

Energy: Nuclear Physics: General Physics: Quantum Physics
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Physicists develop highly robust time crystal      (via sciencedaily.com)     Original source 

Researchers recently succeeded in producing a highly durable time crystal that lived millions of times longer than could be shown in previous experiments. By doing so, they have corroborated an extremely interesting phenomenon that Nobel Prize laureate Frank Wilczek postulated around ten years ago and which had already found its way into science fiction movies.

Chemistry: General Engineering: Nanotechnology Physics: General Physics: Quantum Physics
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Single proton illuminates perovskite nanocrystals-based transmissive thin scintillators      (via sciencedaily.com)     Original source 

Researchers have developed a transmissive thin scintillator using perovskite nanocrystals, designed for real-time tracking and counting of single protons. The exceptional sensitivity is attributed to biexcitonic radiative emission generated through proton-induced upconversion and impact ionization.

Chemistry: Biochemistry Physics: General Physics: Optics Physics: Quantum Computing Physics: Quantum Physics
Published

Short X-ray pulses reveal the source of light-induced ferroelectricity in SrTiO3      (via sciencedaily.com)     Original source 

Researchers have gained new insights into the development of the light-induced ferroelectric state in SrTiO3. They exposed the material to mid-infrared and terahertz frequency laser pulses and found that the fluctuations of its atomic positions are reduced under these conditions. This may explain why the dipolar structure is more ordered than in equilibrium and why the laser pulses induce a ferroelectric state in the material.

Chemistry: Biochemistry Chemistry: General Chemistry: Inorganic Chemistry Engineering: Graphene Engineering: Nanotechnology
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Key dynamics of 2D nanomaterials: View to larger-scale production      (via sciencedaily.com)     Original source 

A team of researchers mapped out how flecks of 2D materials move in liquid -- knowledge that could help scientists assemble macroscopic-scale materials with the same useful properties as their 2D counterparts.

Chemistry: General Chemistry: Organic Chemistry Environmental: General Geoscience: Environmental Issues Geoscience: Geochemistry
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Intensifying the production of high-value compounds from industrial waste      (via sciencedaily.com)     Original source 

New research demonstrates how glycerol carbonate, a biosourced industrial additive, can be produced in record time using CO2 and a by-product of the cooking oil recycling industry. The process relies on a hybrid approach combining fundamental physical organic chemistry and applied flow process technology. Two industrial wastes are thus converted into glycerol carbonate, a biosourced rising star with high added-value.

Chemistry: Biochemistry Chemistry: General Environmental: Ecosystems Environmental: General Environmental: Water Geoscience: Environmental Issues Geoscience: Geochemistry Geoscience: Geography Geoscience: Oceanography
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Engineers unmask nanoplastics in oceans for the first time, revealing their true shapes and chemistry      (via sciencedaily.com)     Original source 

Millions of tons of plastic waste enter the oceans each year. The sun's ultraviolet light and ocean turbulence break down these plastics into invisible nanoparticles that threaten marine ecosystems. In a new study, engineers have presented clear images of nanoplastics in ocean water off the coasts of China, South Korea and the United States, and in the Gulf of Mexico. These tiny plastic particles, which originated from such consumer products as water bottles, food packaging and clothing, were found to have surprising diversity in shape and chemical composition.