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Categories: Chemistry: Inorganic Chemistry, Mathematics: General

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After more than a decade of developing fluorescent probes, a research team has now released the culmination of their years of work: A comprehensive collection of rhodamine-based dyes, the novel chemistry they developed to synthesize them and insights that provide a roadmap for designing future probes.

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ChatGPT may do an impressive job at correctly answering complex questions, but a new study suggests it may be absurdly easy to convince the AI chatbot that it's in the wrong.

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On the highway of heat transfer, thermal energy is moved by way of quantum particles called phonons. But at the nanoscale of today's most cutting-edge semiconductors, those phonons don't remove enough heat. That's why researchers are focused on opening a new nanoscale lane on the heat transfer highway by using hybrid quasiparticles called 'polaritons.'

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Scientists chipping away at one of the great challenges of metal-catalyzed C--H functionalization with a new method that uses a cobalt catalyst to differentiate between bonds in fluoroarenes, functionalizing them based on their intrinsic electronic properties. And their method is fast -- comparable in speed to those that rely on iridium.

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Two nanotechnology approaches converge by employing a new generation of fabrication technology. It combines the scalability of semiconductor technology with the atomic dimensions enabled by self-assembly.

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Chemists have now come up with a way to make molecules known as acenes more stable, allowing them to synthesize acenes of varying lengths. Using their new approach, they were able to build molecules that emit red, orange, yellow, green, or blue light, which could make acenes easier to deploy in a variety of applications.

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Mathematics, histopathology and genomics converge to confirm that the most aggressive clear cell renal cell carcinomas display low levels of intratumour heterogeneity, i.e. they contain fewer distinct cell types. The study supports the hypothesis that it would be advisable to apply therapeutic strategies to maintain high levels of cellular heterogeneity within the tumour in order to slow down the evolution of the cancer and improve human survival.  

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Scientists have made a significant stride toward understanding a viable process for direct air capture, or DAC, of carbon dioxide from the atmosphere. This DAC process is in early development with the aim of achieving negative emissions, where the amount of carbon dioxide removed from the envelope of gases surrounding Earth exceeds the amount emitted.

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Hydrogen is a building block for the energy transition. To obtain it with the help of solar energy, researchers have developed new high-performance nanostructures. The material holds a world record for green hydrogen production with sunlight.

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Friction is hard to predict and control, especially since surfaces that come in contact are rarely perfectly flat. New experiments demonstrate that the amount of friction between two silicon surfaces, even at large scales, is determined by the forming and rupturing of microscopic chemical bonds between them. This makes it possible to control the amount of friction using surface chemistry techniques.

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A collaborative research team has discovered a new process for making anhydrides that promises improvements in costs and sustainability.

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Long before researchers discovered the electron and its role in generating electrical current, they knew about electricity and were exploring its potential. One thing they learned early on was that metals were great conductors of both electricity and heat. And in 1853, two scientists showed that those two admirable properties of metals were somehow related: At any given temperature, the ratio of electronic conductivity to thermal conductivity was roughly the same in any metal they tested. This so-called Wiedemann-Franz law has held ever since -- except in quantum materials. Now, a theoretical argument put forth by physicists suggests that the law should, in fact, approximately hold for one type of quantum material, the cuprate superconductors.

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To ensure that vaccines provide strong and lasting immunization, it is often necessary to supplement the actual vaccine (antigen) with additives that stimulate the immune system: adjuvants. Today, only a few substances have been approved for use as adjuvants. A research team has now introduced a spectrum of potential adjuvants. They started with the immune stimulant ?-glactosyl ceramide (?-GalCer) and synthesized many different variants from a set of four building blocks.

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Found in fishing nets, carpet, clothing, Nylon-6 is a major contributor to plastic pollution, including ocean pollution. Now, chemists have developed a new catalyst that quickly, cleanly and completely breaks down Nylon-6 in a matter of minutes -- without generating harmful byproducts. Even better: The process does not require toxic solvents, expensive materials or extreme conditions, making it practical for everyday applications. In experiments, the new process recovered 99% of the polymer's building blocks, which can then be upcycled into higher-value products.

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Researchers have developed an AI model that can predict where a drug molecule can be chemically altered.

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Used lithium-ion batteries from cell phones, laptops and a growing number of electric vehicles are piling up, but options for recycling them remain limited mostly to burning or chemically dissolving shredded batteries. Researchers have improved on approaches that dissolve the battery in a liquid solution in order to reduce the amount of hazardous chemicals used in the process. This simple, efficient and environmentally-friendly solution overcomes the main obstacles presented by previous approaches.

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Researchers have demonstrated a compact particle accelerator less than 20 meters long that produces an electron beam with an energy of 10 billion electron volts (10 GeV). There are only two other accelerators currently operating in the U.S. that can reach such high electron energies, but both are approximately 3 kilometers long. This type of accelerator is called a wakefield laser accelerator.

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Researchers have devised a way to produce chemicals used in medicine and agriculture for a fraction of the usual cost. Using oxygen as a reagent and copper as a catalyst to break organic molecules' carbon-carbon bonds and convert them into amines, which are widely used in pharmaceuticals. Traditional metal catalysis uses expensive metals such as platinum, silver, gold and palladium, but the researchers used oxygen and copper -- an abundant base metal.

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Researchers create transistors combining silicon with biological silk, using common microprocessor manufacturing methods. The silk protein can be easily modified with other chemical and biological molecules to change its properties, leading to circuits that respond to biology and the environment.

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Glass is a fundamental material. Yet its atomic structure still baffles scientists to this day. Researchers have developed a new way to quantify ring shapes in chemically bonded networks of glass, chipping away at some of the mysteries behind glass's atomic structure.