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Categories: Chemistry: Inorganic Chemistry, Mathematics: Statistics

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An organometallic capsule that can reversibly assemble and disassemble in response to chemical stimuli was recently developed by chemists. Comprising ferrocene-based bent amphiphiles, this new capsule can act as a host for various types of guest molecules, such as electron acceptors and dyes. Thanks to the controllable release of its cargo, the capsule would find applications in catalysis, medicine, and biotechnology.

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Methylcyclohexane is very promising as a hydrogen carrier that can safely and efficiently transport and store hydrogen. However, the dehydrogenation process using catalysts has issues due to its durability and large energy loss. Recently, researchers have succeeded in using solid oxide fuel cells to generate electricity directly from methylcyclohexane and recover toluene for reuse. This research is expected to not only reduce energy requirements but also explore new chemical synthesis by fuel cells.

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Researchers have implemented a quantum-based method to observe a quantum effect in the way light-absorbing molecules interact with incoming photons. Known as a conical intersection, the effect puts limitations on the paths molecules can take to change between different configurations. The observation method makes use of a quantum simulator, developed from research in quantum computing, and offers an example of how advances in quantum computing are being used to investigate fundamental science.

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Scientists have developed a new method for detecting mid-infrared (MIR) light at room temperature using quantum systems.

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Using a trapped-ion quantum computer, the research team witnessed the interference pattern of a single atom caused by a 'conical intersection'. Conical intersections are known throughout chemistry and are vital to rapid photo-chemical processes such as light harvesting in human vision or photosynthesis.

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Researchers have made a significant breakthrough in the field of asymmetric synthesis of beta-lactams, which are prominent in bioactive compounds. Their innovative approach employs nickel and hydrocarbon sources that are abundant on Earth to access value-added beta-lactam products. The employment of nickel-hydride catalysis and alkenyl dioxazolone derivatives gives rise to the selective formation of four-membered lactam products.

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A team of chemists have developed a novel concept in which a mixture of molecules that behave like mirror images is converted to a single form. To this end, they use light as external energy source. The conversion is relevant e.g. for the preparation of drugs.

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A research group has established key early steps in the conversion of aromatic molecules, a major constituent of traffic and other urban volatile emissions, into aerosol. Their findings increase understanding of the chemical processes that degrade urban air quality and influence climate change.

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Researchers have designed a new type of quantum computer that uses fermionic atoms to simulate complex physical systems. The processor uses programmable neutral atom arrays and is capable of simulating fermionic models in a hardware-efficient manner using fermionic gates. The team demonstrated how the new quantum processor can efficiently simulate fermionic models from quantum chemistry and particle physics.

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If coal and natural gas power generation were 2% more efficient, then, every year, there could be 460 million fewer tons of carbon dioxide released and 2 trillion fewer gallons of water used. A recent innovation to the steam cycle used in fossil fuel power generation could achieve this.

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A research team enhanced hydrogen evolution catalyst through stepwise deposition.

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Researchers used topological data analysis to improve the predictions of physical properties of amorphous materials by machine-learning algorithms. This may allow for cheaper and faster calculations of material properties.

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Researchers have developed an epoxy resin that can be repaired and recycled, in addition to being flame-retardant and mechanically strong. Potential applications range from coating for wooden flooring to composites in aerospace and railways.

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Which structures do complex proteins adopt in solution? Biophysicists answer this question using the example of ubiquitin dimers as well as a new combination of high-resolution NMR spectroscopy and sophisticated computer simulations.

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Researchers have developed a platform that uses artificial neural networks to translate chemical structural formulae into machine-readable form. With this platform, they have created a tool with which this information from scientific publications can be automatically fed into databases. Until now, this had to be done literally by hand and was time-consuming.

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The world needs greener ways to make chemicals. In a new study, researchers demonstrate one potential path toward this goal by adapting hydrogen fuel cell technologies.

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In 1956, theoretical physicist David Pines predicted that electrons in a solid can do something strange. While they normally have a mass and an electric charge, Pines asserted that they can combine to form a composite particle that is massless, neutral, and does not interact with light. He called this particle a 'demon.' Now, researchers have finally found Pines' demon 67 years after it was predicted.

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Researchers have found a way to control the interaction of light and quantum 'spin' in organic semiconductors, that works even at room temperature.

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Chemists have discovered that tiny gold 'seed' particles, a key ingredient in one of the most common nanoparticle recipes, are one and the same as gold buckyballs, 32-atom spheres that are cousins of the Nobel Prize-winning carbon buckyballs discovered in 1985.

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Imagine using insects as a source of chemicals to make plastics that can biodegrade later -- with the help of that very same type of bug. That concept is closer to reality than you might expect. Researchers will describe their progress to date, including the isolation and purification of the insect-derived chemicals and their conversion into their bioplastics.