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Categories: Chemistry: Inorganic Chemistry, Ecology: Trees

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Highly reducing or oxidizing photocatalysts are a fundamental challenge in photochemistry. Only a few transition metal complexes with Earth-abundant metal ions have so far advanced to excited state oxidants, including chromium, iron, and cobalt. All these photocatalysts require high energy light for excitation and their oxidizing power has not yet been fully exploited. Furthermore, precious and hence expensive metals are the decisive ingredients in most cases. A team of researchers has now developed a new molecular system based on the element manganese. Manganese, as opposed to precious metals, is the third most abundant metal after iron and titanium and hence widely available and very cheap.

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In a win for chemistry, inventors have designed a closed-loop path for synthesizing an exceptionally tough carbon-fiber-reinforced polymer and later recovering all of its starting materials.

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For the first time, physicists have captured direct images of 'second sound,' the movement of heat sloshing back and forth within a superfluid. The results will expand scientists' understanding of heat flow in superconductors and neutron stars.

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The Greenland ice sheet lies thousands of miles from North America yet holds clues to the distant continent's environmental history. Nearly two miles thick in places, the ice sheet grows as snow drifts from the sky and builds up over time. But snow isn't the only thing carried in by air currents that swirl around the atmosphere, with microscopic pollen grains and pieces of ash mixing with snowfall and preserving records of the past in the ice. A new study examined these pollen grains and identified how eastern Canada's forests grew, retreated, and changed through time.

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A team of scientists has developed an artificial 'worm gut' to break down plastics, offering hope for a nature-inspired method to tackle the global plastic pollution problem.

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Heterostructures of two-dimensional materials have unique properties. Among them, lateral heterostructures, which can be used to make electronic devices, are challenging to synthesize. To address this, researchers used a new transmetallation technique to fabricate heterostructures with in-plane heterojunctions using Zn3BHT coordination nanosheet. This simple and powerful method enables the fabrication of ultrathin electronic devices for ultralarge-scale integrated circuits, marking a significant step forward for 2D materials research.

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Carboxylic acid dianions (fumarate, maleate and succinate) play a role in coordination chemistry and to some extent also in the biochemistry of body cells. A team has now analyzed their electronic structures using RIXS in combination with DFT simulations. The results provide information not only on electronic structures but also on the relative stability of these molecules which can influence an industry's choice of carboxylate dianions, optimizing both the stability and geometry of coordination polymers.

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Think of it as recycling on the nanoscale: a tantalizing electrochemical process that can harvest carbon before it becomes air pollution and restructure it into the components of everyday products. The drive to capture airborne carbon dioxide from industrial waste and make it into fuel and plastics is gaining momentum after a team of researchers uncovered precisely how the process works and where it bogs down.

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Extreme events wipe out entire forests, dramatically eliminating complex ecosystems as well as local communities. Researchers have become quite familiar with such attention-grabbing events over the years. They know less, however, about the more common moderate-severity disturbances, such as relatively small fires, ice storms, and outbreaks of pests or pathogens.

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An international research team has succeeded in controlling the chirality of individual molecules through structural isomerization. The team also succeeded in synthesizing highly reactive diradicals with two unpaired electrons. These achievements were made using a scanning tunneling microscope probe at low temperatures.

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Lithium-sulfur batteries have exceptional theoretical capacity and performance in combination with an element in abundant supply. But the intricate reaction mechanism, particularly during discharge, has been challenging to solve. Researchers have identified the key pathways to a complex sulfur reduction reaction that leads to energy loss and reduced battery life span. The study's findings establish the whole reaction network for the first time and offer insight into electrocatalyst design for improved batteries.

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A crystals expert has published an answer to how crystals are formed and how molecules become a part of them, solving an age-old mystery about crystal formation.

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Researchers pioneer dynamic manipulation and the generation principles of trion at the nanoscale using tip-enhanced cavity-spectroscopy.

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Scientists have used a combination of scanning transmission electron microscopy (STEM) and computational modeling to get a closer look and deeper understanding of tantalum oxide. When this amorphous oxide layer forms on the surface of tantalum -- a superconductor that shows great promise for making the 'qubit' building blocks of a quantum computer -- it can impede the material's ability to retain quantum information. Learning how the oxide forms may offer clues as to why this happens -- and potentially point to ways to prevent quantum coherence loss.

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Oxidation can degrade the properties and functionality of metals. However, a research team recently found that severely oxidized metallic glass nanotubes can attain an ultrahigh recoverable elastic strain, outperforming most conventional super-elastic metals. They also discovered the physical mechanisms underpinning this super-elasticity. Their discovery implies that oxidation in low-dimension metallic glass can result in unique properties for applications in sensors, medical devices and other nanodevices.

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In the fossil record, trees typically are preserved with only their trunks. They don't usually include any leaves to show what their canopies and overall forms may have looked like. In a new study, researchers describe fossilized trees from New Brunswick, Canada with a surprising and unique three-dimensional crown shape.

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Researchers have discovered a change in what scientists already knew about global warming dynamics. It had been widely accepted since the 1950s that global temperature rises were not consistent throughout the day and night, with greater nighttime warming being observed. However, the recent study reveals a shift in dynamics: with greater daytime warming taking place since the 1990s. This shift means that the temperature difference between day and night is widening, potentially affecting all life on Earth.

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A team of researchers mapped out how flecks of 2D materials move in liquid -- knowledge that could help scientists assemble macroscopic-scale materials with the same useful properties as their 2D counterparts.

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A joint research team has successfully induced polarization and polarity in metallic substances.

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Carbon nanostructures could become easier to design and synthesize thanks to a machine learning method that predicts how they grow on metal surfaces. The new approach will make it easier to exploit the unique chemical versatility of carbon nanotechnology.