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Categories: Chemistry: Thermodynamics, Ecology: Nature

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Hydrogen spillover is exactly what it sounds like. Small metal nanoparticles anchored on a thermally stable oxide, like silica, comprise a major class of catalysts, which are substances used to accelerate chemical reactions without being consumed themselves. The catalytic reaction usually occurs on the reactive -- and expensive -- metal, but on some catalysts, hydrogen atom-like equivalents literally spill from the metal to the oxide. These hydrogen-on-oxide species are called 'hydrogen spillover.'

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At a time of unparalleled rates of biodiversity loss, a new interconnected system to monitor biodiversity around the world is needed to guide action quickly enough to target conservation efforts to where they are most needed.

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Plant species from certain geographic regions are more successful in spreading outside their native ranges than others -- but why? Ecologists provide answers by exploring how the ecological and evolutionary histories of plants can influence their relationships with humans and their success as invaders.

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New research found that marine heat waves -- prolonged periods of unusually warm ocean temperatures -- haven't had a lasting effect on the fish communities that feed most of the world. The finding is in stark contrast to the devastating effects seen on other marine ecosystems cataloged by scientists after similar periods of warming, including widespread coral bleaching and harmful algal blooms.

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Researchers generated large scale gene expression data to investigate the molecular networks that operate in one of the closest algal relatives of land plants, a humble single-celled alga called Mesotaenium endlicherianum.

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New work could help forest managers predict which forests are most at risk from drought and which will survive.

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Carbon capture is a promising method to help slow climate change. With this approach, carbon dioxide (CO¬¬2) is trapped before it escapes into the atmosphere, but the process requires a large amount of energy and equipment. Now, researchers have designed a capture system using an electrochemical cell that can easily grab and release CO2. The device operates at room temperature and requires less energy than conventional, amine-based carbon-capture systems.

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The Mpemba effect is originally referred to the non-monotonic initial temperature dependence of the freezing start time, but it has been observed in various systems -- including colloids -- and has also become known as a mysterious relaxation phenomenon that depends on initial conditions. However, very few have previously investigated the effect in quantum systems. Now, the temperature quantum Mpemba effect can be realized over a wide range of initial conditions.

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If coal and natural gas power generation were 2% more efficient, then, every year, there could be 460 million fewer tons of carbon dioxide released and 2 trillion fewer gallons of water used. A recent innovation to the steam cycle used in fossil fuel power generation could achieve this.

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Indoor air pollution may have met its match. Scientists have designed catalyst-coated lampshades that transform indoor air pollutants into harmless compounds. The lampshades work with halogen and incandescent light bulbs, and the team is extending the technology so it will also be compatible with LEDs.

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Engineers have developed a breakthrough technique to make the processing of nanosensors cheaper, greener and more effective by using a single drop of ethanol to replace heat processing of nanoparticle networks, allowing a wider range of materials to be used to make these sensors.

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Engineers have developed HADAR, or heat-assisted detection and ranging.

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Whether they're made from soybeans, almonds, oats, or just sourced straight from the cow, milk products must go through heat treatment to prevent harmful bacterial growth and keep them safe. But understanding how these processes affect new, plant-based milk formulations could make the beverages more pleasant to drink as well. Researchers have discovered how pasteurization and sterilization affects the look and feel of one such drink made from coconut and rice.

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An unusual discovery is now being developed as an on-demand cooling solution for high-flying military electronics.

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Heat load mitigation is critical to extending the lifetime of future fusion device. Researchers have found a way to explain the rotational temperatures measured in three different experimental fusion devices in Japan and the United States. Their model evaluates the surface interactions and electron-proton collisions of hydrogen molecules.

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Excess heat from electronic or mechanical devices is a sign or cause of inefficient performance. In many cases, embedded sensors to monitor the flow of heat could help engineers alter device behavior or designs to improve their efficiency. For the first time, researchers exploit a novel thermoelectric phenomenon to build a thin sensor that can visualize heat flow in real time. The sensor could be built deep inside devices where other kinds of sensors are impractical. It is also quick, cheap and easy to manufacture using well-established methods.

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A catalyst using a single or just a few palladium atoms removed 90% of unburned methane from natural gas engine exhaust at low temperatures in a recent study. While more research needs to be done, the advance in single atom catalysis has the potential to lower exhaust emissions of methane, one of the worst greenhouse gases that traps heat at about 25 times the rate of carbon dioxide. Researchers showed that the single-atom catalyst was able to remove methane from engine exhaust at lower temperatures, less than 350 degrees Celsius (662 degrees Fahrenheit), while maintaining reaction stability at higher temperatures.

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Putting a suite of new materials synthesis and characterization methods to the test, a team of scientists has developed 14 organic-inorganic hybrid materials, seven of which are entirely new.

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Researchers report achieving self-sustaining and long-term levitation of millimeter-sized droplets of several different liquids without any external forces. To get the droplets to levitate, they use solutocapillary convection, which occurs when a surface tension gradient is formed by nonuniform distribution of vapor molecules from the droplet at the pool surface. Further exploring the effects of various external conditions on self-sustained droplet levitation will reveal whether it can be harnessed and adapted for microbiology and biochemistry applications.

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Small-winged and lighter colored butterflies likely to be at greatest threat from climate change. The family, wing length and wing colour of tropical butterflies all influence their ability to withstand rising temperatures, say ecologists. The researchers believe this could help identify species whose survival is under threat from climate change.