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Categories: Chemistry: General, Offbeat: Earth and Climate
Published X-rays visualize how one of nature's strongest bonds breaks
(via sciencedaily.com) Original source The use of short flashes of X-ray light brings scientists one big step closer toward developing better catalysts to transform the greenhouse gas methane into a less harmful chemical. The result reveals for the first time how carbon-hydrogen bonds of alkanes break and how the catalyst works in this reaction.
Published Thermal energy stored by land masses has increased significantly
(via sciencedaily.com) Original source There are many effects of climate change. Perhaps the most broadly known is global warming, which is caused by heat building up in various parts of the Earth system, such as the atmosphere, the ocean, the cryosphere and the land. 89 percent of this excess heat is stored in the oceans, with the rest in ice and glaciers, the atmosphere and land masses (including inland water bodies). An international research team has now studied the quantity of heat stored on land, showing the distribution of land heat among the continental ground, permafrost soils, and inland water bodies. The calculations show that more than 20 times as much heat has been stored there since the 1960s, with the largest increase being in the ground.
Published You can make carbon dioxide filters with a 3D printer
(via sciencedaily.com) Original source Researchers demonstrated that it's possible to make carbon dioxide capture filters using 3D printing.
Published Desert ant increase the visibility of their nest entrances in the absence of landmarks
(via sciencedaily.com) Original source Researchers report that in the absence of visible landmarks, desert ants increase the likelihood that foraging nest mates will find their way home quickly and safely by elevating their nest entrance. Ant colonies whose nests are found deep in the Tunisian saltpan are particularly reliant on the self-made landmarks. If the mound at the nest entrance was removed, they immediately began building a new hill, unless the researchers provided artificial landmarks. This phenomenon adds yet another fascinating facet to the amazing navigation skills of these tiny desert animals.
Published A protein mines, sorts rare earths better than humans, paving way for green tech
(via sciencedaily.com) Original source Rare earth elements, like neodymium and dysprosium, are a critical component to almost all modern technologies, from smartphones to hard drives, but they are notoriously hard to separate from the Earth's crust and from one another. Scientists have discovered a new mechanism by which bacteria can select between different rare earth elements, using the ability of a bacterial protein to bind to another unit of itself, or 'dimerize,' when it is bound to certain rare earths, but prefer to remain a single unit, or 'monomer,' when bound to others.
Published First X-ray of a single atom
(via sciencedaily.com) Original source Scientists have taken the world's first X-ray SIGNAL (or SIGNATURE) of just one atom. This groundbreaking achievement could revolutionize the way scientists detect the materials.
Published A nanocrystal shines on and off indefinitely
(via sciencedaily.com) Original source Optical probes have led to numerous breakthroughs in applications like optical memory, nanopatterning, and bioimaging, but existing options have limited lifespans and will eventually 'photobleach.' New work demonstrates a promising, longer-lasting alternative: ultra-photostable avalanching nanoparticles that can turn on and off indefinitely in response to near-infrared light from simple lasers.
Published Geneticists discover hidden 'whole genome duplication' that may explain why some species survived mass extinctions
(via sciencedaily.com) Original source Geneticists have unearthed a major event in the ancient history of sturgeons and paddlefish that has significant implications for the way we understand evolution. They have pinpointed a previously hidden 'whole genome duplication' (WGD) in the common ancestor of these species, which seemingly opened the door to genetic variations that may have conferred an advantage around the time of a major mass extinction some 200 million years ago.
Published Crossing the ring: New method enables C-H activation across saturated carbocycles
(via sciencedaily.com) Original source Chemists add another powerful tool to their 'molecular editing' toolkit for crafting pharmaceuticals and other valuable compounds.
Published Hidden in plain sight: Windshield washer fluid is an unexpected emission source
(via sciencedaily.com) Original source Exhaust fumes probably come to mind when considering vehicle emissions, but they aren't the only source of pollutants released by a daily commute. Researchers report that alcohols in windshield washer fluid account for a larger fraction of real-world vehicle emissions than previous estimates have suggested. Notably, the levels of these non-fuel-derived gases will likely remain unchanged, even as more drivers transition from gas-powered to electric vehicles.
Published Robot centipedes go for a walk
(via sciencedaily.com) Original source Researchers show how their multilegged walking robot can be steered by inducing a dynamic instability. By making the couplings between segments more flexible, the robot changes from walking straight to moving in a curved path. This work can lead to more energy-efficient and reliable robotic navigation of terrain.
Published Emergence of solvated dielectrons observed for the first time
(via sciencedaily.com) Original source Scientists generate low-energy electrons using ultraviolet light.
Published Nanorobotic system presents new options for targeting fungal infections
(via sciencedaily.com) Researchers have developed a nanorobot system that targets fungal infections in the mouth.
Published Development of iron complex catalyst for selective and efficient conversion of methane to methanol
(via sciencedaily.com) Original source A new iron complex has been developed as a catalyst for the oxidation of methane to selectively convert it to methanol. This complex can efficiently oxidize methane by internally trapping methane while preventing the overoxidation of the produced methanol. Using this complex, the direct and selective conversion of methane to methanol has been successfully achieved in an aqueous solution.
Published Making the structure of 'fire ice' with nanoparticles
(via sciencedaily.com) Original source Cage structures made with nanoparticles could be a route toward making organized nanostructures with mixed materials, and researchers have shown how to achieve this through computer simulations.
Published Twisting under the stroboscope -- Controlling crystal lattices of hybrid solar cell materials with terahertz light
(via sciencedaily.com) Original source To overcome global energy challenges and fight the looming environmental crisis, researchers around the world investigate new materials for converting sunlight into electricity. Some of the most promising candidates for high-efficiency low-cost solar cell applications are based on lead halide perovskite (LHP) semiconductors. Despite record-breaking solar cell prototypes, the microscopic origin of the surprisingly excellent optoelectronic performance of this material class is still not completely understood. Now, an international team of physicists and chemists has demonstrated laser-driven control of fundamental motions of the LHP atomic lattice.
Published Snapshots of photoinjection
(via sciencedaily.com) Original source Ultrafast laser physicists from the attoworld team have gained new insights into the dynamics of electrons in solids immediately after photoinjection.
Published Weevils, long-nosed beetles, are unsung heroes of pollination
(via sciencedaily.com) Original source Some of nature's most diverse pollinators often go unnoticed, even by scientists: long-snouted beetles called weevils. A new study provides a deep dive into the more than 600 species of weevils, including ones whose entire life cycles are interwoven with a specific plant that they help pollinate.
Published Iron-rich rocks unlock new insights into Earth's planetary history
(via sciencedaily.com) Original source A new study suggests iron-rich ancient sediments may have helped cause some of the largest volcanic events in the planet's history.
Published Engineers harvest abundant clean energy from thin air, 24/7
(via sciencedaily.com) Original source A team of engineers has recently shown that nearly any material can be turned into a device that continuously harvests electricity from humidity in the air. Researchers describe the 'generic Air-gen effect'-- nearly any material can be engineered with nanopores to harvest, cost effective, scalable, interruption-free electricity. The secret lies in being able to pepper the material with nanopores less than 100 nanometers in diameter.