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Categories: Chemistry: Inorganic Chemistry, Environmental: Wildfires

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Polymers can be thought of like trains: Just as a train is composed of multiple cars, polymers are made up of multiple monomers, and the couplings between the train cars are similar to the chemical bonds that link monomers together. While polymers have myriad applications -- from drug delivery to construction materials -- their structures and functions are restricted by the chemically similar monomer building blocks they're composed of. Now, chemists have developed a new reaction to create unique monomers in a controlled way. This reaction, which uses nickel as a catalyst, ultimately enables scientists to create polymers with unique and modifiable properties for drug delivery, energy storage, microelectronics and more.

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The control of artificial double-helical structures, which are essential for the development of high-order molecular systems, remains difficult. In a new study, researchers have developed novel double-helical monometallofoldamers that exhibit controllable helicity inversion and chiral information transfer, in response to external stimuli. These monometallofoldamers can lead to novel artificial supramolecular systems for molecular information transmission, amplification, replication, and other exciting applications in various fields of technology.

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Researchers developed a way to fingerprint organofluorine compounds -- sometimes called 'forever chemicals' --which could help authorities trace them to their source when they end up in aquifers, waterways or soil.

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In 2023, roughly 60,000 firework shells exploded above Manhattan's East River as part of Macy's Fourth of July show. The resulting air pollutant levels were many times higher in the hours after the display than those seen when smoke from a Canadian wildfire had blanketed the area a month before, according to the results of a new study.

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The world is going to need a lot of weird metals in the coming years, according to chemistry professor. But he isn't talking about lithium, cobalt or even beryllium. He's interested in dysprosium, which is so hidden in the periodic table that you'd be forgiven for thinking he made it up.

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The production of more than 90 percent of all chemical products we use in our everyday lives relies on catalysts. Catalysts speed up chemical reactions, can reduce the energy required for these processes, and in some cases, reactions would not be possible at all without catalysts. Researchers developed a concept that increases the stability of noble-metal catalysts and requires less noble metal for their production.

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Physicists have discovered two new ways to improve organic semiconductors. They found a way to remove more electrons from the material than previously possible and used unexpected properties in an environment known as the non-equilibrium state, boosting its performance for use in electronic devices.

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Controlling the crystal phase of cobalt nanoparticles leads to exceptional catalytic performance in hydrogenation processes, scientists report. Produced via an innovative hydrosilane-assisted synthesis method, these phase-controlled reusable nanoparticles enable the selective hydrogenation of various compounds under mild conditions without the use of harmful gases like ammonia. These efforts could lead to more sustainable and efficient catalytic processes across many industrial fields.

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An international research team has succeeded in developing a new version of RNA building blocks with higher chemical reactivity and photosensitivity. This can significantly reduce the production time of RNA chips used in biotechnological and medical research. The chemical synthesis of these chips is now twice as fast and seven times more efficient.

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A coating of solar cells with special organic molecules could pave the way for a new generation of solar panels. This coating can increase the efficiency of monolithic tandem cells made of silicon and perovskite while lowering their cost -- because they are produced from industrial, microstructured, standard silicon wafers.

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A new study focuses on how a particular Kagome metal interacts with light to generate what are known as plasmon polaritons -- nanoscale-level linked waves of electrons and electromagnetic fields in a material, typically caused by light or other electromagnetic waves.

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Nanozymes are tiny, engineered substances that mimic the catalytic properties of natural enzymes, and they serve a variety of purposes in biomedicine, chemical engineering, and environmental applications. They are typically made from inorganic materials, including metal-based elements, which makes them unsuitable for many purposes due to their toxicity and high production costs. Organic-based nanozymes partially overcome some of these problems and have the potential for a broader range of applications, including food and agriculture, but they are still in the early stages of development. A new paper provides an overview of the current state of organic nanozymes and their future potential.

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Climate-driven shifts in California's biodiversity call for innovation and continued environmental stewardfship, says a new study. California's 30x30 Initiative and efforts to harmonize biodiversity with renewable energy are promising steps, while wildfire strategies need to further adapt.

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Researchers have synthesized a bio-inspired polymer for water purification. The polymer was designed to mimic phytochelatin, a plant protein that selectively captures and neutralizes harmful heavy metal ions. The hyperconfinement of the polymer enabled a flow-through system and effectively removed cadmium ions from contaminated water, making it safe to drink. The system was selective for heavy metals and provides a new way to remove specific contaminants from water.

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A study has made it possible to estimate experimentally the energy required to transfer protons from water to ionic liquids.

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Scientists transformed existing optoelectronic devices into ones that can control electron spin at room temperature, without a ferromagnet or magnetic field. Researchers replaced the electrodes of store-bought LEDs with a patented spin filter made from hybrid organic-inorganic halide perovskite.

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Aerosol scientists quantify the extent of light absorption by black carbon in fire clouds to better model climate impacts of extreme wildfire events.

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Engineers discovered that when the aluminum in soda cans is purified and mixed with seawater, the solution produces hydrogen -- which can power an engine or fuel cell without generating carbon emissions. The reaction can be sped up by adding caffeine.

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Researchers have developed a material that shows a remarkable ability to convert sunlight and water into clean energy.

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Researchers are proposing a new way to curb industrial emissions, by tapping into the 'atomic intelligence' of liquid metals to deliver greener and more sustainable chemical reactions.