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Categories: Chemistry: Inorganic Chemistry, Environmental: Wildfires
Published Crystals from radioactive metal actinium
(via sciencedaily.com) Original source Researchers grew crystals containing actinium and illuminated them with X-rays to learn how the radioactive metal binds with other elements. That information could help design better cancer treatments.
Published Complex impact of large wildfires on ozone layer dynamics
(via sciencedaily.com) Original source In a revelation highlighting the fragile balance of our planet's atmosphere, scientists have uncovered an unexpected link between massive wildfire events and the chemistry of the ozone layer. Using satellite data and numerical modeling, the team discovered that an enormous smoke-charged vortex nearly doubles the southern hemispheric aerosol burden in the middle stratosphere of the Earth and reorders ozone depletion at different heights. This study reveals how wildfires, such as the catastrophic 2019/20 Australian bushfires, impact the stratosphere in previously unseen ways.
Published Microbeads with adaptable fluorescent colors from visible light to near-infrared
(via sciencedaily.com) Original source Researchers have successfully developed an environmentally friendly, microspherical fluorescent material primarily made from citric acid. These microbeads emit various colors of light depending on the illuminating light and the size of the beads, which suggests a wide range of applications. Furthermore, the use of plant-derived materials allows for low-cost and energy-efficient synthesis.
Published A chemical claw machine bends and stretches when exposed to vapors
(via sciencedaily.com) Original source Scientists have developed a tiny 'claw machine' that is able to pick up and drop a marble-sized ball in response to exposure to chemical vapors. The findings point to a technique that can enable soft actuators--the parts of a machine that make it move--to perform multiple tasks without the need for additional costly materials. While existing soft actuators can be 'one-trick ponies' restricted to one type of movement, this novel composite film contorts itself in different ways depending on the vapor that it is exposed to.
Published Scientists create computer program that 'paints' the structure of molecules in the style of Piet Mondrian
(via sciencedaily.com) Original source Scientists have created a computer program that 'paints' the structure of molecules in the style of famous Dutch artist, Piet Mondrian. Researchers are opening eyes and minds to the beauty of molecular structure, as well as posing new questions about the form and function of the molecules themselves.
Published Forest carbon storage has declined across much of the Western U.S., likely due to drought and fire
(via sciencedaily.com) Original source Forests have been embraced as a natural climate solution, due to their ability to soak up carbon dioxide from the atmosphere as they grow, locking it up in their trunks, branches, leaves, and roots. But a new study confirms widespread doubts about the potential for most forests in the Western US to help curb climate change. The paper analyzed trends in carbon storage across the American West from 2005 to 2019.
Published Aperiodic approximants for relating quasicrystals and modulated structures
(via sciencedaily.com) Original source By constructing hexagonal metallic-mean approximants of the honeycomb lattice, scientists have linked incommensurately modulated structures and quasicrystals, two classes of aperiodic crystals. They found that a quasicrystal converges to a modulated honeycomb crystal on arranging tiles based on metallic means. This metallic-mean tiling pattern was also identified in polymer and colloidal systems in soft-matter self-assemblies, providing new insights into aperiodic crystals.
Published High-speed electron camera uncovers a new 'light-twisting' behavior in an ultrathin material
(via sciencedaily.com) Original source Using an instrument for ultrafast electron diffraction (MeV-UED), researchers discovered how an ultrathin material can circularly polarize light. This discovery sets up a promising approach to manipulate light for applications in optoelectronic devices.
Published BESSY II shows how solid-state batteries degrade
(via sciencedaily.com) Original source Solid-state batteries have several advantages: they can store more energy and are safer than batteries with liquid electrolytes. However, they do not last as long and their capacity decreases with each charge cycle. But it doesn't have to stay that way: Researchers are already on the trail of the causes.
Published Moving from the visible to the infrared: Developing high quality nanocrystals
(via sciencedaily.com) Original source Awarded the 2023 Nobel Prize in Chemistry, quantum dots have a wide variety of applications ranging from displays and LED lights to chemical reaction catalysis and bioimaging. These semiconductor nanocrystals are so small -- on the order of nanometers -- that their properties, such as color, are size dependent, and they start to exhibit quantum properties. This technology has been really well developed, but only in the visible spectrum, leaving untapped opportunities for technologies in both the ultraviolet and infrared regions of the electromagnetic spectrum.
Published Mining rare earth metals from electronic waste
(via sciencedaily.com) Original source A small molecule that naturally serves as a binding site for metals in enzymes also proves useful for separating certain rare earth metals from each other. In a proof of concept, the process extracts europium directly from fluorescent powder in used energy-saving lamps in much higher quantities than existing methods. The researchers are now working on expanding their approach to other rare earth metals. They are in the process of founding a start-up to put the recycling of these raw materials into practice.
Published It takes a cool microscope and antifreeze to really look at ice
(via sciencedaily.com) Original source Ice in nature is surrounded by liquid most of the time, and therefore it is key to understand how ice and liquid interact. A new study has now directly observe the precise shape of ice at the interface between ice and liquid -- by using antifreeze and a refrigerated microscope.
Published Chemistry inspired by one-pot cooking
(via sciencedaily.com) Original source Is it possible to create a new class of materials from very different substances using the 'one-pot synthesis' approach? Chemists explain how they enable the synthesis of such novel materials.
Published Visualizing short-lived intermediate compounds produced during chemical reactions
(via sciencedaily.com) Original source Immobilizing small synthetic molecules inside protein crystals proves to be a promising avenue for studying intermediate compounds formed during chemical reactions, scientists report. By integrating this method with time-resolved serial femtosecond crystallography, they successfully visualized reaction dynamics and rapid structural changes occurring within reaction centers immobilized inside protein crystals. This innovative strategy holds significant potential for the intelligent design of drugs, catalysts, and functional materials.
Published Ionic liquids: 'Don't shake it'
(via sciencedaily.com) Original source Chemists have develop innovative ionic liquid synthesis and purification technology.
Published Scientists discover way to 'grow' sub-nanometer sized transistors
(via sciencedaily.com) Original source A research team has implemented a novel method to achieve epitaxial growth of 1D metallic materials with a width of less than 1 nm. The group applied this process to develop a new structure for 2D semiconductor logic circuits. Notably, they used the 1D metals as a gate electrode of the ultra-miniaturized transistor.
Published Chemists synthesize an improved building block for medicines
(via sciencedaily.com) Original source Research could help drug developers improve the safety profiles of medications and reduce side effects.
Published Mechanism of bio-inspired control of liquid flow
(via sciencedaily.com) Original source The more we discover about the natural world, the more we find that nature is the greatest engineer. Past research implied that liquids can only be transported in fixed direction on species with specific liquid communication properties and cannot switch the transport direction. Recently, researchers have shown that an African plant controls water movement in a previously unknown way -- and this could inspire breakthroughs in a range of technologies in fluid dynamics and nature-inspired materials, including applications that require multistep and repeated reactions, such as microassays, medical diagnosis and solar desalination etc.
Published Mapping the surfaces of MXenes, atom by atom, reveals new potential for the 2D materials
(via sciencedaily.com) Original source In the decade since their discovery, the family of two-dimensional materials called MXenes has shown a great deal of promise for applications ranging from water desalination and energy storage to electromagnetic shielding and telecommunications, among others. While researchers have long speculated about the genesis of their versatility, a recent study has provided the first clear look at the surface chemical structure foundational to MXenes' capabilities.
Published Using visible light to make pharmaceutical building blocks
(via sciencedaily.com) Original source Chemists have discovered a way to use visible light to synthesize a class of compounds particularly well suited for use in pharmaceuticals. The class of compounds, called azetidines, had been previously identified as a good candidate to build therapeutic drugs, but the compounds are difficult to produce in chemical reactions. Now, a team has developed a method to produce a specific class of azetidines called monocyclic azetidines using visible light and a photocatalyst.