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Categories: Chemistry: Inorganic Chemistry, Geoscience: Earthquakes

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The term aromaticity is a basic, long-standing concept in chemistry that is well established for ring-shaped carbon compounds. Aromatic rings consisting solely of metal atoms were, however, heretofore unknown. A research team recently succeeded in isolating such a metal ring and describing it in full.

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Researchers have discovered a new way to drive chemical reactions that could generate a wide variety of azetidines -- four-membered nitrogen heterocycles that have desirable pharmaceutical properties.

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Researchers are reporting progress on the road to more efficient utilization of solar energy: They have developed an innovative light-harvesting system.

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A new study uncovers the remarkable potential of ultrafast lasers that could provide innovative solutions in 2D materials processing for many technology developers such as high-speed photodetectors, flexible electronics, biohybrids, and next-generation solar cells.

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Scientists predict from geochemical data that Iceland is entering a new volcanic era that will last for decades, possibly centuries. Under an hour's drive from the country's capital city, the ongoing eruptions pose considerable risks for economic disruption, and they leave evacuated communities uncertain of a possible return.

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A research team has developed a small optical lens, only a few millimeters in size, whose refractive behavior changes in the presence of gas. This 'intelligent' behavior of the micro-lens is enabled by the hybrid glass material from which it is made. The molecular structure of the lens consists of a three-dimensional lattice with cavities that can accommodate gas molecules, thereby affecting the optical properties of the material.

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Norcembranolide diterpenes, isolated from the soft corals of the genus Sinularia, are important compounds for the development of new drugs, owing to their diverse biological activities. However, total synthesis methods for these compounds are scarce. Now, a team of researchers has achieved the total synthesis of scabrolide F, a norcembranolide diterpene. They also revealed its non-toxic antifouling properties. This novel method can lead to the development of new drugs and antifouling agents.

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Scientists predict the existence of flat electronic bands at the Fermi level, a finding that could enable new forms of quantum computing and electronic devices.

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Using a novel non-contact approach, a research team has successfully controlled the speed and efficiency of Forster resonance energy transfer between fluorescent molecules by varying the intensity of a laser beam.

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Encapsulating copper nanoparticles within hydrophobic porous silicate crystals has been shown to significantly enhance the catalytic activity of copper-zinc oxide catalysts used in methanol synthesis via CO2 hydrogenation. The innovative encapsulation structure effectively inhibits the thermal aggregation of copper particles, leading to enhanced hydrogenation activity and increased methanol production. This breakthrough paves the way for more efficient methanol synthesis from CO2.

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Researchers have created a new class of materials called 'glassy gels' that are very hard and difficult to break despite containing more than 50% liquid. Coupled with the fact that glassy gels are simple to produce, the material holds promise for a variety of applications.

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Researchers used theoretical calculations assessing electron orbital symmetry to synthesize new molecule designed to be both transparent and colorless while absorbing near-infrared light. This compound demonstrates the first systematic approach to producing such materials and have applications in advanced electronics. This compound also shows semiconducting properties.

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A new method in spectromicroscopy significantly improves the study of chemical reactions at the nanoscale, both on surfaces and inside layered materials. Scanning X-ray microscopy (SXM) at MAXYMUS beamline of BESSY II enables the investigation of chemical species adsorbed on the top layer (surface) or intercalated within the MXene electrode (bulk) with high chemical sensitivity.

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A major earthquake 2,500 years ago caused one of the largest rivers on Earth to abruptly change course, according to a new study. The previously undocumented quake rerouted the main channel of the Ganges River in what is now densely populated Bangladesh, which remains vulnerable to big quakes.

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Current techniques for measuring nano/microplastic (N/MP) concentrations in soil require the soil organic matter content to be separated and have limited resolution for analyzing N/MPs sized <1 m. Therefore, researchers have developed a novel yet simple method to measure N/MP concentration in different soil types using spectroscopy at two wavelengths. This method does not require the soil to be separated in order to detect the N/MPs and can accurately quantify N/MPs regardless of their size.

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A gold-coated milling vessel for ball mills proved to be a real marvel: without any solvents or environmentally harmful chemicals, the team was able to use it to convert alcohols into aldehydes. The catalytic reaction takes place at the gold surface and is mechanically driven. The vessel can be reused multiple times. 'This opens up new prospects for the use of gold in catalysis and shows how traditional materials can contribute to solving modern environmental problems in an innovative way,' says Borchardt.

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A ubiquitous compound, called ester can be broken down to produce desirable alcohols and other chemicals for use across industries including pharmaceuticals and cosmetics, but the process can be costly, both financially and in terms of the environment. Researchers developed a novel photocatalyst 'N-BAP.' When irradiated with blue light, the photocatalyst reduces esters in the presence of oxalate, a negatively charged molecule found widely in nature, resulting in the desired alcohols.

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Spontaneous parametric down-conversion (SPDC), as a source of entangled photons, is of great interest for quantum physics and quantum technology, but so far it could be only implemented in solids. Researchers have demonstrated, for the first time, SPDC in a liquid crystal. The results open a path to a new generation of quantum sources: efficient and electric-field tunable.

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With their 'T-REX' method, researchers developed a glassy, amber-like polymer that can be used for long-term storage of DNA, such as entire human genomes or digital files such as photos.

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The new study provides unambiguous evidence that the inner core began to decrease its speed around 2010, moving slower than the Earth's surface.