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Categories: Chemistry: Inorganic Chemistry, Offbeat: Paleontology and Archeology
Published Mapping the surfaces of MXenes, atom by atom, reveals new potential for the 2D materials
(via sciencedaily.com) Original source In the decade since their discovery, the family of two-dimensional materials called MXenes has shown a great deal of promise for applications ranging from water desalination and energy storage to electromagnetic shielding and telecommunications, among others. While researchers have long speculated about the genesis of their versatility, a recent study has provided the first clear look at the surface chemical structure foundational to MXenes' capabilities.
Published Using visible light to make pharmaceutical building blocks
(via sciencedaily.com) Original source Chemists have discovered a way to use visible light to synthesize a class of compounds particularly well suited for use in pharmaceuticals. The class of compounds, called azetidines, had been previously identified as a good candidate to build therapeutic drugs, but the compounds are difficult to produce in chemical reactions. Now, a team has developed a method to produce a specific class of azetidines called monocyclic azetidines using visible light and a photocatalyst.
Published Nuclear spectroscopy breakthrough could rewrite the fundamental constants of nature
(via sciencedaily.com) Original source Raising the energy state of an atom's nucleus using a laser, or exciting it, would enable development of the most accurate atomic clocks ever to exist. This has been hard to do because electrons, which surround the nucleus, react easily with light, increasing the amount of light needed to reach the nucleus. By causing the electrons to bond with fluorine in a transparent crystal, UCLA physicists have finally succeeded in exciting the neutrons in a thorium atom's nucleus using a moderate amount of laser light. This accomplishment means that measurements of time, gravity and other fields that are currently performed using atomic electrons can be made with orders of magnitude higher accuracy.
Published Optoelectronics gain spin control from chiral perovskites and III-V semiconductors
(via sciencedaily.com) Original source A research effort has made advances that could enable a broader range of currently unimagined optoelectronic devices.
Published Organic material from Mars reveals the likely origin of life's building blocks
(via sciencedaily.com) Original source Two samples from Mars together deliver clear evidence of the origin of Martian organic material. The study presents solid evidence for a prediction made over a decade ago that could be key to understanding how organic molecules, the foundation of life, were first formed here on Earth.
Published Sixty-million-year-old grape seeds reveal how the death of the dinosaurs may have paved the way for grapes to spread
(via sciencedaily.com) Original source Scientists discovered the oldest fossil grapes in the Western Hemisphere, which help show how after the death of the dinosaurs, grapes spread across the world.
Published Melanin from cuttlefish ink as a sustainable biomass resource
(via sciencedaily.com) Original source Melanin is a ubiquitous compound in nature, produced by many organisms. However, its potential as a biomass resource to produce value-added chemicals and materials remains relatively unexplored. In a recent study, researchers investigated the chemical decomposition of melanin derived from cuttlefish ink and showcased its application in the synthesis of biopolymer films and particles. Their efforts will hopefully pave the way to the adoption of melanin upcycling.
Published Investigating newly discovered hydrothermal vents at depths of 3,000 meters off Svalbard
(via sciencedaily.com) Original source Hydrothermal vents can be found around the world at the junctions of drifting tectonic plates. But there are many hydrothermal fields still to be discovered. During a 2022 expedition of the MARIA S. MERIAN, the first field of hydrothermal vents on the 500-kilometer-long Knipovich Ridge off the coast of Svalbard was discovered.
Published Synthetic fuels and chemicals from CO2: Ten experiments in parallel
(via sciencedaily.com) Original source Why do just one experiment at a time when you can do ten? Researchers have developed an automated system, which allows them to research catalysts, electrodes, and reaction conditions for CO2 electrolysis up to ten times faster. The system is complemented by an open-source software for data analysis.
Published New materials: Synthetic pathway for promising nitride compounds discovered
(via sciencedaily.com) Original source Chemists have successfully synthesized Ruddlesden-Popper nitrides for the first time, opening the door to new materials with unique properties.
Published Aromatic compounds: A ring made up solely of metal atoms
(via sciencedaily.com) Original source The term aromaticity is a basic, long-standing concept in chemistry that is well established for ring-shaped carbon compounds. Aromatic rings consisting solely of metal atoms were, however, heretofore unknown. A research team recently succeeded in isolating such a metal ring and describing it in full.
Published Last surviving woolly mammoths were inbred but not doomed to extinction
(via sciencedaily.com) Original source The last population of woolly mammoths was isolated on Wrangel Island off the coast of Siberia 10,000 years ago, when sea levels rose and cut the mountainous island off from the mainland. A new genomic analysis reveals that the isolated mammoths, who lived on the island for the subsequent 6,000 years, originated from at most 8 individuals but grew to 200--300 individuals within 20 generations. The researchers report that the Wrangel Island mammoths' genomes showed signs of inbreeding and low genetic diversity but not to the extent that it can explain their ultimate (and mysterious) extinction.
Published Prehistoric 'Pompeii' discovered: Most pristine trilobite fossils ever found shake up scientific understanding of the long extinct group
(via sciencedaily.com) Original source Researchers have described some of the best-preserved three-dimensional trilobite fossils ever discovered. The fossils, which are more than 500 million years old, were collected in the High Atlas of Morocco and are being referred to by scientists as 'Pompeii' trilobites due to their remarkable preservation in ash.
Published Scientists use computational modeling to guide a difficult chemical synthesis
(via sciencedaily.com) Original source Researchers have discovered a new way to drive chemical reactions that could generate a wide variety of azetidines -- four-membered nitrogen heterocycles that have desirable pharmaceutical properties.
Published Researchers find genetic stability in a long-term Panamanian hybrid zone of manakin birds
(via sciencedaily.com) Original source We often think of species as separate and distinct, but sometimes they can interbreed and create hybrids. When this happens consistently in a specific area, it forms what's known as a hybrid zone. These zones can be highly dynamic or remarkably stable, and studying them can reveal key insights into how species boundaries evolve -- or sometimes blur. Researchers now describe a hybrid zone between two manakin species in Panama that has overall remained relatively stable over the past 30 years.
Published Solar technology: Innovative light-harvesting system works very efficiently
(via sciencedaily.com) Original source Researchers are reporting progress on the road to more efficient utilization of solar energy: They have developed an innovative light-harvesting system.
Published Almonds, pottery, wood help date famed Kyrenia shipwreck
(via sciencedaily.com) Original source Researchers have identified the likeliest timeline of the famous Hellenistic-era Kyrenia shipwreck, discovered and recovered off the north coast of Cyprus in the 1960s.
Published Shocked quartz reveals evidence of historical cosmic airburst
(via sciencedaily.com) Original source Researchers continue to expand the case for the Younger Dryas Impact hypothesis. The idea proposes that a fragmented comet smashed into the Earth's atmosphere 12,800 years ago, causing a widespread climatic shift that, among other things, led to the abrupt reversal of the Earth's warming trend and into an anomalous near-glacial period called the Younger Dryas.
Published A new study highlights potential of ultrafast laser processing for next-gen devices
(via sciencedaily.com) Original source A new study uncovers the remarkable potential of ultrafast lasers that could provide innovative solutions in 2D materials processing for many technology developers such as high-speed photodetectors, flexible electronics, biohybrids, and next-generation solar cells.
Published An optical lens that senses gas
(via sciencedaily.com) Original source A research team has developed a small optical lens, only a few millimeters in size, whose refractive behavior changes in the presence of gas. This 'intelligent' behavior of the micro-lens is enabled by the hybrid glass material from which it is made. The molecular structure of the lens consists of a three-dimensional lattice with cavities that can accommodate gas molecules, thereby affecting the optical properties of the material.