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Categories: Chemistry: Inorganic Chemistry, Offbeat: Paleontology and Archeology
Published Diamonds are a chip's best friend
(via sciencedaily.com) Original source New technologies aim to produce high-purity synthetic crystals that become excellent semiconductors when doped with impurities as electron donors or acceptors of other elements. Researchers have now determined the magnitude of the spin-orbit interaction in acceptor-bound excitons in a semiconductor. They broke through the energy resolution limit of conventional luminescence measurements by directly observing the fine structure of bound excitons in boron-doped blue diamond, using optical absorption.
Published Researchers use Hawk supercomputer and lean into imperfection to improve solar cell efficiency
(via sciencedaily.com) Original source Solar energy is one of the most promising, widely adopted renewable energy sources, but the solar cells that convert light into electricity remains a challenge. Scientists have turned to the High-Performance Computing Center Stuttgart to understand how strategically designing imperfections in the system could lead to more efficient energy conversion.
Published Imaging grain boundaries that impede lithium-ion migration in solid-state batteries
(via sciencedaily.com) Original source A research team has developed a new technique to image grain boundaries obstructing lithium-ion migration in solid-state batteries -- a promising type of next-generation battery.
Published AI-driven lab speeds catalysis research
(via sciencedaily.com) Original source Researchers have developed a 'self-driving' lab that uses artificial intelligence (AI) and automated systems to provide in-depth analyses of catalytic reactions used in chemical research and manufacturing. The new tool, called Fast-Cat, can provide more information in five days than is possible in six months of conventional testing.
Published A new theoretical development clarifies water's electronic structure
(via sciencedaily.com) Original source Scientists have decoded the electronic structure of water, opening up new perspectives for technological and environmental applications.
Published The mutual neutralization of hydronium and hydroxide
(via sciencedaily.com) Original source Researchers have been able to directly visualize the neutral products of the mutual neutralization of hydronium and hydroxide, and report three different product channels: two channels were attributed to a predominant electron-transfer mechanism, and a smaller channel was associated with proton transfer. The two-beam collision experiment is an important step toward understanding the quantum dynamics of this fundamental reaction.
Published Chemists synthesize unique anticancer molecules using novel approach
(via sciencedaily.com) Original source Nearly 30 years ago, scientists discovered a unique class of anticancer molecules in a family of bryozoans, a phylum of marine invertebrates found in tropical waters. The chemical structures of these molecules, which consist of a dense, highly complex knot of oxidized rings and nitrogen atoms, has attracted the interest of organic chemists worldwide, who aimed to recreate these structures from scratch in the laboratory. However, despite considerable effort, it has remained an elusive task. Until now, that is. A team of chemists has succeeded in synthesizing eight of the compounds for the first time using an approach that combines inventive chemical strategy with the latest technology in small molecule structure determination.
Published A new vibrant blue pottery pigment with less cobalt
(via sciencedaily.com) Original source Whether ultramarine, cerulean, Egyptian or cobalt, blue pigments have colored artworks for centuries. Now, seemingly out of the blue, scientists have discovered a new blue pigment that uses less cobalt but still maintains a brilliant shine. Though something like this might only happen once in a blue moon, the cobalt-doped barium aluminosilicate colorant withstands the high temperatures found in a kiln and provides a bright color to glazed tiles.
Published Graphene research: Numerous products, no acute dangers found by study
(via sciencedaily.com) Original source Graphene is an enormously promising material. It consists of a single layer of carbon atoms arranged in a honeycomb pattern and has extraordinary properties: exceptional mechanical strength, flexibility, transparency and outstanding thermal and electrical conductivity. If the already two-dimensional material is spatially restricted even more, for example into a narrow ribbon, controllable quantum effects can be created. This could enable a wide range of applications, from vehicle construction and energy storage to quantum computing.
Published High resolution techniques reveal clues in 3.5 billion-year-old biomass
(via sciencedaily.com) Original source To learn about the first organisms on our planet, researchers have to analyze the rocks of the early Earth. These can only be found in a few places on the surface of the Earth. The Pilbara Craton in Western Australia is one of these rare sites: there are rocks there that are around 3.5 billion years old containing traces of the microorganisms that lived at that time. A research team has now found new clues about the formation and composition of this ancient biomass, providing insights into the earliest ecosystems on Earth.
Published Utah's Bonneville Salt Flats has long been in flux
(via sciencedaily.com) Original source It has been long assumed that Utah's Bonneville Salt Flats was formed as its ancient namesake lake dried up 13,000 years ago. But new research has gutted that narrative, determining these crusts did not form until several thousand years after Lake Bonneville disappeared, which could have important implications for managing this feature that has been shrinking for decades to the dismay of the racing community and others who revere the saline pan 100 miles west of Salt Lake City. Relying on radiocarbon analysis of pollen found in salt cores, the study concludes the salt began accumulating between 5,400 and 3,500 years ago, demonstrating how this geological feature is not a permanent fixture on the landscape.
Published Butterfly and moth genomes mostly unchanged despite 250 million years of evolution
(via sciencedaily.com) Original source Comparison of over 200 high-quality butterfly and moth genomes reveals key insights into their biology, evolution and diversification over the last 250 million years, as well as clues for conservation.
Published An awkward family reunion: Sea monsters are our cousins
(via sciencedaily.com) Original source The sea lamprey, a 500-million-year-old animal with a sharp-toothed suction cup for a mouth, is the thing of nightmares. A new study discovered that the hindbrain -- the part of the brain controlling vital functions like blood pressure and heart rate -- of both sea lampreys and humans is built using an extraordinarily similar molecular and genetic toolkit.
Published An environmentally friendly way to turn seafood waste into value-added products
(via sciencedaily.com) Original source Reduce, reuse, recycle, and repurpose: These are all ways we can live more sustainably. One tricky aspect of recycling, though, is that sometimes the recycling process is chemically intensive, and this is the case for recycling one of the world's most abundant materials -- chitin. Researchers have tackled this problem and found a way to sustainably recover chitin from seafood waste.
Published Revolutionary breakthrough in solar energy: Most efficient QD solar cells
(via sciencedaily.com) Original source A research team has unveiled a novel ligand exchange technique that enables the synthesis of organic cation-based perovskite quantum dots (PQDs), ensuring exceptional stability while suppressing internal defects in the photoactive layer of solar cells.
Published Did neanderthals use glue? Researchers find evidence that sticks
(via sciencedaily.com) Original source Neanderthals created stone tools held together by a multi-component adhesive, a team of scientists has discovered. Its findings, which are the earliest evidence of a complex adhesive in Europe, suggest these predecessors to modern humans had a higher level of cognition and cultural development than previously thought.
Published It's the spin that makes the difference
(via sciencedaily.com) Original source Biomolecules such as amino acids and sugars occur in two mirror-image forms -- in all living organisms, however, only one is ever found. Why this is the case is still unclear. Researchers have now found evidence that the interplay between electric and magnetic fields could be at the origin of this phenomenon.
Published Physicists develop more efficient solar cell
(via sciencedaily.com) Original source Physicists have used complex computer simulations to develop a new design for significantly more efficient solar cells than previously available. A thin layer of organic material, known as tetracene, is responsible for the increase in efficiency.
Published Accelerating the discovery of single-molecule magnets with deep learning
(via sciencedaily.com) Original source Single-molecule magnets (SMMs) are exciting materials. In a recent breakthrough, researchers have used deep learning to predict SMMs from 20,000 metal complexes. The predictions were made solely based on the crystal structures of these metal complexes, thus eliminating the need for time-consuming experiments and complex simulations. As a result, this method is expected to accelerate the development of functional materials, especially for high-density memory and quantum computing devices.
Published Plastic recycling with a protein anchor
(via sciencedaily.com) Original source Polystyrene is a widespread plastic that is essentially not recyclable when mixed with other materials and is not biodegradable. A research team has now introduced a biohybrid catalyst that oxidizes polystyrene microparticles to facilitate their subsequent degradation. The catalyst consists of a specially constructed 'anchor peptide' that adheres to polystyrene surfaces and a cobalt complex that oxidizes polystyrene.