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Categories: Chemistry: Inorganic Chemistry, Chemistry: Organic Chemistry
Published Moving from the visible to the infrared: Developing high quality nanocrystals
(via sciencedaily.com) Original source Awarded the 2023 Nobel Prize in Chemistry, quantum dots have a wide variety of applications ranging from displays and LED lights to chemical reaction catalysis and bioimaging. These semiconductor nanocrystals are so small -- on the order of nanometers -- that their properties, such as color, are size dependent, and they start to exhibit quantum properties. This technology has been really well developed, but only in the visible spectrum, leaving untapped opportunities for technologies in both the ultraviolet and infrared regions of the electromagnetic spectrum.
Published Mining rare earth metals from electronic waste
(via sciencedaily.com) Original source A small molecule that naturally serves as a binding site for metals in enzymes also proves useful for separating certain rare earth metals from each other. In a proof of concept, the process extracts europium directly from fluorescent powder in used energy-saving lamps in much higher quantities than existing methods. The researchers are now working on expanding their approach to other rare earth metals. They are in the process of founding a start-up to put the recycling of these raw materials into practice.
Published It takes a cool microscope and antifreeze to really look at ice
(via sciencedaily.com) Original source Ice in nature is surrounded by liquid most of the time, and therefore it is key to understand how ice and liquid interact. A new study has now directly observe the precise shape of ice at the interface between ice and liquid -- by using antifreeze and a refrigerated microscope.
Published Chemistry inspired by one-pot cooking
(via sciencedaily.com) Original source Is it possible to create a new class of materials from very different substances using the 'one-pot synthesis' approach? Chemists explain how they enable the synthesis of such novel materials.
Published Hexagonal perovskite oxides: Electrolytes for next-generation protonic ceramic fuel cells
(via sciencedaily.com) Original source Researchers have identified hexagonal perovskite-related oxides as materials with exceptionally high proton conductivity and thermal stability. Their unique crystal structure and large number of oxygen vacancies enable full hydration and high proton diffusion, making these materials ideal candidates as electrolytes for next-generation protonic ceramic fuel cells that can operate at intermediate temperatures without degradation.
Published Visualizing short-lived intermediate compounds produced during chemical reactions
(via sciencedaily.com) Original source Immobilizing small synthetic molecules inside protein crystals proves to be a promising avenue for studying intermediate compounds formed during chemical reactions, scientists report. By integrating this method with time-resolved serial femtosecond crystallography, they successfully visualized reaction dynamics and rapid structural changes occurring within reaction centers immobilized inside protein crystals. This innovative strategy holds significant potential for the intelligent design of drugs, catalysts, and functional materials.
Published Ionic liquids: 'Don't shake it'
(via sciencedaily.com) Original source Chemists have develop innovative ionic liquid synthesis and purification technology.
Published New organic molecule shatters phosphorescence efficiency records and paves way for rare metal-free applications
(via sciencedaily.com) Original source A team has discovered that the new organic molecule thienyl diketone exhibits high-efficiency phosphorescence, achieving a rate over ten times faster than traditional materials. This breakthrough provides new guidelines for developing rare metal-free organic phosphorescent materials, promising advancements in applications like organic EL displays, lighting, and cancer diagnostics.
Published Do genes-in-pieces code for proteins that fold in pieces?
(via sciencedaily.com) Original source A new study offers new insights into the evolution of foldable proteins.
Published Scientists discover way to 'grow' sub-nanometer sized transistors
(via sciencedaily.com) Original source A research team has implemented a novel method to achieve epitaxial growth of 1D metallic materials with a width of less than 1 nm. The group applied this process to develop a new structure for 2D semiconductor logic circuits. Notably, they used the 1D metals as a gate electrode of the ultra-miniaturized transistor.
Published Chemists synthesize an improved building block for medicines
(via sciencedaily.com) Original source Research could help drug developers improve the safety profiles of medications and reduce side effects.
Published Mechanism of bio-inspired control of liquid flow
(via sciencedaily.com) Original source The more we discover about the natural world, the more we find that nature is the greatest engineer. Past research implied that liquids can only be transported in fixed direction on species with specific liquid communication properties and cannot switch the transport direction. Recently, researchers have shown that an African plant controls water movement in a previously unknown way -- and this could inspire breakthroughs in a range of technologies in fluid dynamics and nature-inspired materials, including applications that require multistep and repeated reactions, such as microassays, medical diagnosis and solar desalination etc.
Published Mapping the surfaces of MXenes, atom by atom, reveals new potential for the 2D materials
(via sciencedaily.com) Original source In the decade since their discovery, the family of two-dimensional materials called MXenes has shown a great deal of promise for applications ranging from water desalination and energy storage to electromagnetic shielding and telecommunications, among others. While researchers have long speculated about the genesis of their versatility, a recent study has provided the first clear look at the surface chemical structure foundational to MXenes' capabilities.
Published Using visible light to make pharmaceutical building blocks
(via sciencedaily.com) Original source Chemists have discovered a way to use visible light to synthesize a class of compounds particularly well suited for use in pharmaceuticals. The class of compounds, called azetidines, had been previously identified as a good candidate to build therapeutic drugs, but the compounds are difficult to produce in chemical reactions. Now, a team has developed a method to produce a specific class of azetidines called monocyclic azetidines using visible light and a photocatalyst.
Published Nuclear spectroscopy breakthrough could rewrite the fundamental constants of nature
(via sciencedaily.com) Original source Raising the energy state of an atom's nucleus using a laser, or exciting it, would enable development of the most accurate atomic clocks ever to exist. This has been hard to do because electrons, which surround the nucleus, react easily with light, increasing the amount of light needed to reach the nucleus. By causing the electrons to bond with fluorine in a transparent crystal, UCLA physicists have finally succeeded in exciting the neutrons in a thorium atom's nucleus using a moderate amount of laser light. This accomplishment means that measurements of time, gravity and other fields that are currently performed using atomic electrons can be made with orders of magnitude higher accuracy.
Published Optoelectronics gain spin control from chiral perovskites and III-V semiconductors
(via sciencedaily.com) Original source A research effort has made advances that could enable a broader range of currently unimagined optoelectronic devices.
Published Novel spectroscopy technique sheds light on NOx reduction
(via sciencedaily.com) Original source The process that can convert pollution into benign by-products is called selective catalytic reduction, or SCR. Until now, it has been unclear how this reaction actually occurs, and contradictions have long existed between reaction models within the literature. Catalysis researchers used a technology called modulation excitation spectroscopy, or MES, to finally identify the correct pathway.
Published Melanin from cuttlefish ink as a sustainable biomass resource
(via sciencedaily.com) Original source Melanin is a ubiquitous compound in nature, produced by many organisms. However, its potential as a biomass resource to produce value-added chemicals and materials remains relatively unexplored. In a recent study, researchers investigated the chemical decomposition of melanin derived from cuttlefish ink and showcased its application in the synthesis of biopolymer films and particles. Their efforts will hopefully pave the way to the adoption of melanin upcycling.
Published Synthetic fuels and chemicals from CO2: Ten experiments in parallel
(via sciencedaily.com) Original source Why do just one experiment at a time when you can do ten? Researchers have developed an automated system, which allows them to research catalysts, electrodes, and reaction conditions for CO2 electrolysis up to ten times faster. The system is complemented by an open-source software for data analysis.
Published No more stressing out over structural formulas
(via sciencedaily.com) Original source Structural formulas are a source of dread for many students, but they're an essential tool in biology lessons. A study has now shown that the stress levels of students working with chemical formulas are significantly reduced if they are given simple tips on how to deal with these formulas.