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Categories: Chemistry: Organic Chemistry, Environmental: Water
Published Light stimulates a new twist for synthetic chemistry
(via sciencedaily.com) Original source Molecules that are induced by light to rotate bulky groups around central bonds could be developed into photo-activated bioactive systems, molecular switches, and more.
Published Want fewer microplastics in your tap water? Try boiling it first
(via sciencedaily.com) Original source Nano- and microplastics are seemingly everywhere -- water, soil and the air. While many creative strategies have been attempted to get rid of these plastic bits, one unexpectedly effective solution for cleaning up drinking water, specifically, might be as simple as brewing a cup of tea or coffee. Boiling and filtering calcium-containing tap water could help remove nearly 90% of the nano- and microplastics present.
Published Nanocarrier with escape reflex
(via sciencedaily.com) Original source Protein-based drugs must be transported into cells in a way that prevents their immediate degradation. A new approach is intended to ensure that they remain intact only in certain cells, such as cancer cells. A Japanese research team has introduced a nanocarrier that can 'escape' from endosomes before its cargo is destroyed there. This ability to escape is only triggered within the endosomes of certain tumor cells.
Published Walleye struggle with changes to timing of spring thaw
(via sciencedaily.com) Original source Walleye are one of the most sought-after species in freshwater sportfishing, a delicacy on Midwestern menus and a critically important part of the culture of many Indigenous communities. They are also struggling to survive in the warming waters of the Midwestern United States and Canada. According to a new study, part of the problem is that walleye are creatures of habit, and the seasons -- especially winter -- are changing so fast that this iconic species of freshwater fish can't keep up.
Published New disease testing component facilitates lower-cost diagnostics
(via sciencedaily.com) Original source Biomedical researchers have developed a new, less expensive way to detect nuclease digestion -- one of the critical steps in many nucleic acid sensing applications, such as those used to identify COVID-19 and other infectious diseases.
Published Low-Temperature Plasma used to remove E. coli from hydroponically grown crops
(via sciencedaily.com) Original source In a new study, a team sterilized a hydroponic nutrient solution using low-temperature plasma generated from electricity and the oxygen in the atmosphere. This new sterilization technique may allow farmers to grow crops without the use of chemical pesticides, representing an important advance in agricultural technology for sustainable crop production.
Published Scientists propose new method for tracking elusive origins of CO2 emissions from streams
(via sciencedaily.com) Original source A team of researchers that specializes in accounting for the carbon dioxide release by streams, rivers and lakes recently demonstrated that the chemical process known as 'carbonate buffering' can account for the majority of emissions in highly alkaline waters. Furthermore, carbonate buffering distorts the most commonly used method of tracking the origins of CO2 in streams. The research proposes a better method for tracking the origin of riverine CO2 emissions.
Published AI-driven lab speeds catalysis research
(via sciencedaily.com) Original source Researchers have developed a 'self-driving' lab that uses artificial intelligence (AI) and automated systems to provide in-depth analyses of catalytic reactions used in chemical research and manufacturing. The new tool, called Fast-Cat, can provide more information in five days than is possible in six months of conventional testing.
Published Cutting-edge 'protein lawnmower' created
(via sciencedaily.com) Original source Scientists have designed the first synthetic protein-based motor which harnesses biological reactions to fuel and propel itself. 'Imagine if a Roomba could be powered only by the dirt it picks up,' says one of the authors of the study. The motor uses the digestive enzyme trypsin to cut the peptides and convert them into the energy it needs to propel itself.
Published Scientists assemble a richer picture of the plight and resilience of the foothill yellow-legged frog
(via sciencedaily.com) Original source Up to only a few inches in length, with a lemon-hued belly, the foothill yellow-legged frog may seem unassuming. But its range once stretched from central Oregon to Baja California. In 2023, it was listed under the federal Endangered Species Act. Its rapidly decreasing range is due in part to a fungal pathogen called Batrachochytrium dendrobatidis, or Bd, that has devastated amphibians around the world.
Published The mutual neutralization of hydronium and hydroxide
(via sciencedaily.com) Original source Researchers have been able to directly visualize the neutral products of the mutual neutralization of hydronium and hydroxide, and report three different product channels: two channels were attributed to a predominant electron-transfer mechanism, and a smaller channel was associated with proton transfer. The two-beam collision experiment is an important step toward understanding the quantum dynamics of this fundamental reaction.
Published Wetlands, parks and even botanical gardens among the best ways to cool cities during heatwaves
(via sciencedaily.com) Original source Botanical gardens are not just beautiful -- they can cool the city air by 5 C during heatwaves, according to the most comprehensive review of its kind. Parks and wetlands have a similar effect.
Published Streams connected to groundwater show improved detoxification and microbial diversity
(via sciencedaily.com) Original source Streams with ample connections to shallow groundwater flow-paths have greater microbial diversity and are more effective at preventing toxic forms of metals -- often products of upstream mining -- from entering and being transported downstream.
Published Chemists synthesize unique anticancer molecules using novel approach
(via sciencedaily.com) Original source Nearly 30 years ago, scientists discovered a unique class of anticancer molecules in a family of bryozoans, a phylum of marine invertebrates found in tropical waters. The chemical structures of these molecules, which consist of a dense, highly complex knot of oxidized rings and nitrogen atoms, has attracted the interest of organic chemists worldwide, who aimed to recreate these structures from scratch in the laboratory. However, despite considerable effort, it has remained an elusive task. Until now, that is. A team of chemists has succeeded in synthesizing eight of the compounds for the first time using an approach that combines inventive chemical strategy with the latest technology in small molecule structure determination.
Published Air pollution hides increases in rainfall
(via sciencedaily.com) Original source In a new study, researchers broke down how human-induced greenhouse gas and aerosol emissions influence rainfall in the United States. Greenhouse gas emissions increase rainfall, while aerosols have a long-term drying effect as well as short-term impacts that vary with the seasons. As aerosols decrease, their long-term drying effect will likely diminish, causing rainfall averages and extremes to rapidly increase.
Published Biggest Holocene volcano eruption found by seabed survey
(via sciencedaily.com) Original source A detailed survey of the volcanic underwater deposits around the Kikai caldera in Japan clarified the deposition mechanisms as well as the event's magnitude. As a result, the research team found that the event 7,300 years ago was the largest volcanic eruption in the Holocene by far.
Published Utah's Bonneville Salt Flats has long been in flux
(via sciencedaily.com) Original source It has been long assumed that Utah's Bonneville Salt Flats was formed as its ancient namesake lake dried up 13,000 years ago. But new research has gutted that narrative, determining these crusts did not form until several thousand years after Lake Bonneville disappeared, which could have important implications for managing this feature that has been shrinking for decades to the dismay of the racing community and others who revere the saline pan 100 miles west of Salt Lake City. Relying on radiocarbon analysis of pollen found in salt cores, the study concludes the salt began accumulating between 5,400 and 3,500 years ago, demonstrating how this geological feature is not a permanent fixture on the landscape.
Published New detection method aims to warn of landslide tsunamis
(via sciencedaily.com) Original source Researchers have devised a way to remotely detect large landslides within minutes of occurrence and to quickly determine whether they are close to open water and present a tsunami hazard.
Published New cloud model could help with climate research
(via sciencedaily.com) Original source When clouds meet clear skies, cloud droplets evaporate as they mix with dry air. A new study has succeeded in capturing what happens in a model. Ultimately, this could lead to more accurate climate modeling in the future.
Published Why are fish getting smaller as waters warm? It's not their gills
(via sciencedaily.com) Original source A collaborative team of scientists recently found that there is no physiological evidence supporting a leading theory -- which involves the surface area of fish gills -- as to why many fish species are 'shrinking' as waters grow warmer due to climate change. Known as the Gill Oxygen Limitation (GOL) theory, it has been proposed as the universal mechanism explaining fish size and has been used in some predictions of future global fisheries yields. However, the researchers conducted a series of long-term experiments on brook trout and found that, though increased temperatures do lead to significantly decreased body size, gill surface area did not explain the change.