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Categories: Chemistry: Organic Chemistry, Environmental: Water

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When it comes to making fuel from plants, the first step has always been the hardest -- breaking down the plant matter. A new study finds that introducing a simple, renewable chemical to the pretreatment step can finally make next-generation biofuel production both cost-effective and carbon neutral.

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Carboxylic acid dianions (fumarate, maleate and succinate) play a role in coordination chemistry and to some extent also in the biochemistry of body cells. A team has now analyzed their electronic structures using RIXS in combination with DFT simulations. The results provide information not only on electronic structures but also on the relative stability of these molecules which can influence an industry's choice of carboxylate dianions, optimizing both the stability and geometry of coordination polymers.

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New study suggests that temperature can influence the microbial competition in rivers.

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New research reveals that denser, and more sheltered, kelp forests can withstand serious stressors amid warming ocean temperatures.

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A new study has found similarities between long-term climatic changes in South Australia and temperate agricultural areas in Argentina -- highlighting similarities across these Southern Hemisphere countries. As temperature records tumble, and the threat of bushfires and dry conditions looms large, researchers renew the urgency of calls to make more concerted efforts to prepare for climate extremes in South Australia.

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Lithium-sulfur batteries have exceptional theoretical capacity and performance in combination with an element in abundant supply. But the intricate reaction mechanism, particularly during discharge, has been challenging to solve. Researchers have identified the key pathways to a complex sulfur reduction reaction that leads to energy loss and reduced battery life span. The study's findings establish the whole reaction network for the first time and offer insight into electrocatalyst design for improved batteries.

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In hydrogen fuel cells, electrolyte membranes frequently undergo deformation and develop cracks during operation. A research team has recently introduced a fatigue-resistant polymer electrolyte membrane for hydrogen fuel cells, employing an interpenetrating network of Nafion (a plastic electrolyte) and perfluoropolyether (a rubbery polymer). This innovation will not only improve fuel cell vehicles but also promises advancements in diverse technologies beyond transportation, spanning applications from drones to desalination filters and backup power sources.

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There was an increase in the number of unprovoked shark attacks worldwide and an uptick in fatalities in 2023 compared to the previous year. A scientific database of global shark attacks, confirmed 69 unprovoked bites in 2023. Although this is higher than the most recent five-year average of 63 attacks, the data remain consistent with long-term trends.

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Switching to ammonia as a marine fuel, with the goal of decarbonization, can instead create entirely new problems. This is shown in a study where researchers carried out life cycle analyses for batteries and for three electrofuels including ammonia. Eutrophication and acidification are some of the environmental problems that can be traced to the use of ammonia -- as well as emissions of laughing gas, which is a very potent greenhouse gas.

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Engineers have developed an ultra-sensitive sensor made with graphene that can detect extraordinarily low concentrations of lead ions in water. The device achieves a record limit of detection of lead down to the femtomolar range, which is one million times more sensitive than previous technologies.

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A research team develops edge-to-edge assembly technique for 2D nanosheets.

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A new study provides the first evidence that the Arctic's frozen soil is the dominant force shaping Earth's northernmost rivers, confining them to smaller areas and shallower valleys than rivers to the south. But as climate change weakens Arctic permafrost, the researchers calculate that every 1 degree Celsius of global warming could release as much carbon as 35 million cars emit in a year as polar waterways expand and churn up the thawing soil.

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New research demonstrates how glycerol carbonate, a biosourced industrial additive, can be produced in record time using CO2 and a by-product of the cooking oil recycling industry. The process relies on a hybrid approach combining fundamental physical organic chemistry and applied flow process technology. Two industrial wastes are thus converted into glycerol carbonate, a biosourced rising star with high added-value.

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A research findings show that different AOM lineages employ different regulatory strategies for ammonia or urea utilization, thereby minimizing direct competition with one another and allowing for coexistence.

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Millions of tons of plastic waste enter the oceans each year. The sun's ultraviolet light and ocean turbulence break down these plastics into invisible nanoparticles that threaten marine ecosystems. In a new study, engineers have presented clear images of nanoplastics in ocean water off the coasts of China, South Korea and the United States, and in the Gulf of Mexico. These tiny plastic particles, which originated from such consumer products as water bottles, food packaging and clothing, were found to have surprising diversity in shape and chemical composition.

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Trees are struggling to sequester heat-trapping carbon dioxide (CO2) in warmer, drier climates, meaning that they may no longer serve as a solution for offsetting humanity's carbon footprint as the planet continues to warm, according to a new study.

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A team of researchers has achieved a major breakthrough in genome editing technology. They've developed a cutting-edge method that combines the power of designer-recombinases with programmable DNA-binding domains to create precise and adaptable genome editing tools.

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Green roofs have become increasingly popular thanks to their benefits related to climate adaptation, mitigation, and urban biodiversity management. But, in the U.S., green roofs are typically planted with non-native plants in sterile soils, and their effectiveness declines over time. A new study finds that managing green roof soil microbes boosts healthy urban soil development, which is a methodology that could be applied to support climate resilience in cities.

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As sea otters recolonize a California estuary, they are restoring its degraded geology by keeping populations of overgrazing marsh crabs in check, a new study shows. The crabs' appetite for plant roots, and their tunneling behavior had caused many of the estuary's marshes and creekbanks to erode and collapse in the otters' absence. Today, erosion has slowed by up to 90% in areas with large otter populations and marshes and streambeds are restabilizing.

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Scientists have succeeded in cultivating and characterizing tomato varieties with higher water use efficiency without compromising yield. The researchers, employing CRISPR genetic editing technology, were able to grow tomatoes that consume less water while preserving yield, quality, and taste.