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Categories: Chemistry: Organic Chemistry, Geoscience: Landslides

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Cutting-edge research converted waste carbon dioxide into a potential precursor for chemicals and carbon-free fuel.

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Carboxylic acid dianions (fumarate, maleate and succinate) play a role in coordination chemistry and to some extent also in the biochemistry of body cells. A team has now analyzed their electronic structures using RIXS in combination with DFT simulations. The results provide information not only on electronic structures but also on the relative stability of these molecules which can influence an industry's choice of carboxylate dianions, optimizing both the stability and geometry of coordination polymers.

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Lithium-sulfur batteries have exceptional theoretical capacity and performance in combination with an element in abundant supply. But the intricate reaction mechanism, particularly during discharge, has been challenging to solve. Researchers have identified the key pathways to a complex sulfur reduction reaction that leads to energy loss and reduced battery life span. The study's findings establish the whole reaction network for the first time and offer insight into electrocatalyst design for improved batteries.

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In hydrogen fuel cells, electrolyte membranes frequently undergo deformation and develop cracks during operation. A research team has recently introduced a fatigue-resistant polymer electrolyte membrane for hydrogen fuel cells, employing an interpenetrating network of Nafion (a plastic electrolyte) and perfluoropolyether (a rubbery polymer). This innovation will not only improve fuel cell vehicles but also promises advancements in diverse technologies beyond transportation, spanning applications from drones to desalination filters and backup power sources.

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Engineers have developed an ultra-sensitive sensor made with graphene that can detect extraordinarily low concentrations of lead ions in water. The device achieves a record limit of detection of lead down to the femtomolar range, which is one million times more sensitive than previous technologies.

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A research team develops edge-to-edge assembly technique for 2D nanosheets.

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New research demonstrates how glycerol carbonate, a biosourced industrial additive, can be produced in record time using CO2 and a by-product of the cooking oil recycling industry. The process relies on a hybrid approach combining fundamental physical organic chemistry and applied flow process technology. Two industrial wastes are thus converted into glycerol carbonate, a biosourced rising star with high added-value.

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A team of researchers has achieved a major breakthrough in genome editing technology. They've developed a cutting-edge method that combines the power of designer-recombinases with programmable DNA-binding domains to create precise and adaptable genome editing tools.

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Nanoclusters (NCs) of transition metals like cobalt or nickel have widespread applications in drug delivery and water purification, with smaller NCs exhibiting improved functionalities. Downsizing NCs is, however, usually challenging. Now, scientists have demonstrated functional NC formation with atomic-scale precision. They successfully grew cobalt NCs on flat copper surfaces using molecular arrays as traps. This breakthrough paves the way for advancements like single-atom catalysis and spintronics miniaturization.

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Global warming continues to pose a threat to human society and the ecological systems, and carbon dioxide accounts for the largest proportion of the greenhouse gases that dominate climate warming. To combat climate change and move towards the goal of carbon neutrality, researchers have developed a durable, highly selective and energy-efficient carbon dioxide (CO2) electroreduction system that can convert CO2 into ethylene for industrial purposes to provide an effective solution for reducing CO2 emissions.

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A newly evolved enzyme could one day make silicone compounds biodegradable.

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Two research groups design a plasma (an ionized gas) reactor maintained by microwaves that makes it possible to decontaminate waters with high concentrations of dye.

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Reactive oxygen species (ROS), though generally regarded as toxic byproducts of biological processes, serve many important functions in plants. However, the precise mechanism that plants use to regulate the production of ROS remains elusive. In a recent study, researchers clarified how an important ROS-generating enzyme is activated, revealing mechanisms likely conserved across all land plants. Their findings could pave the way for breakthroughs in agricultural and environmental remediation tools.

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Researchers have developed a new, more environmentally friendly way to create conductive inks for use in organic electronics such as solar cells, artificial neurons, and soft sensors. The findings pave the way for future sustainable technology.

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A research team has developed a novel catalyst for the high-efficiency and stable production of high-purity green hydrogen.

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A new study shows that the physics principle of 'nucleation' can perform complex calculations that rival a simple neural network. The work may suggest avenues for new ways to think about computation using the principles of physics.

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Researchers have developed a framework that uses machine learning to accelerate the search for new proton-conducting materials, that could potentially improve the efficiency of hydrogen fuel cells.

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A team has introduced a strategy for converting carbon-nitrogen atom pairs in a frequently used ring-shaped compound into carbon-carbon atom pairs. The method has potential in the quest for active ingredients for new drugs, for example.

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Organic semiconductors are materials that find applications in various electronic devices. Exciton binding energy is an important attribute that influences the behavior of these materials. Now, researchers have employed advanced spectroscopic techniques to accurately determine these energies for various organic semiconductor materials, with a high precision of 0.1 electron volts. Their study reveals unexpected correlations that are poised to shape the future of organic optoelectronics, influence design principles, and find potential applications in bio-related materials.

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In the switch to 'greener' energy sources, the demand for rechargeable lithium-ion batteries is surging. However, their cathodes typically contain cobalt -- a metal whose extraction has high environmental and societal costs. Now, researchers in report evaluating an earth-abundant, carbon-based cathode material that could replace cobalt and other scarce and toxic metals without sacrificing lithium-ion battery performance.