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Categories: Anthropology: General, Chemistry: Organic Chemistry
Published Chemical synthesis: New strategy for skeletal editing on pyridines
(via sciencedaily.com) Original source A team has introduced a strategy for converting carbon-nitrogen atom pairs in a frequently used ring-shaped compound into carbon-carbon atom pairs. The method has potential in the quest for active ingredients for new drugs, for example.
Published Lighting the path: Exploring exciton binding energies in organic semiconductors
(via sciencedaily.com) Original source Organic semiconductors are materials that find applications in various electronic devices. Exciton binding energy is an important attribute that influences the behavior of these materials. Now, researchers have employed advanced spectroscopic techniques to accurately determine these energies for various organic semiconductor materials, with a high precision of 0.1 electron volts. Their study reveals unexpected correlations that are poised to shape the future of organic optoelectronics, influence design principles, and find potential applications in bio-related materials.
Published Despite intensive scientific analyses, this centaur head remains a mystery
(via sciencedaily.com) Original source For almost 200 years, archaeologists have been puzzled by a mysterious brown stain on the ancient Greek Parthenon temple in Greece. Now, researchers have conducted new scientific analyses, and their verdict is clear: The mystery remains.
Published Next-generation batteries could go organic, cobalt-free for long-lasting power
(via sciencedaily.com) Original source In the switch to 'greener' energy sources, the demand for rechargeable lithium-ion batteries is surging. However, their cathodes typically contain cobalt -- a metal whose extraction has high environmental and societal costs. Now, researchers in report evaluating an earth-abundant, carbon-based cathode material that could replace cobalt and other scarce and toxic metals without sacrificing lithium-ion battery performance.
Published Cobalt-free batteries could power cars of the future
(via sciencedaily.com) Original source A new battery material could offer a more sustainable way to power electric cars. The lithium-ion battery includes a cathode based on organic materials, instead of cobalt or nickel.
Published Glowing COVID-19 diagnostic test prototype produces results in one minute
(via sciencedaily.com) Original source Cold, flu and COVID-19 season brings that now-familiar ritual: swab, wait, look at the result. But what if, instead of taking 15 minutes or more, a test could quickly determine whether you have COVID-19 with a glowing chemical? In a new study, researchers describe a potential COVID-19 test inspired by bioluminescence. Using a molecule found in crustaceans, they have developed a rapid approach that detects SARS-CoV-2 protein comparably to one used in vaccine research.
Published Woolly mammoth movements tied to earliest Alaska hunting camps
(via sciencedaily.com) Original source Researchers have linked the travels of a 14,000-year-old woolly mammoth with the oldest known human settlements in Alaska, providing clues about the relationship between the iconic species and some of the earliest people to travel across the Bering Land Bridge. Isotopic data, along with DNA from other mammoths at the site and archaeological evidence, indicates that early Alaskans likely structured their settlements to overlap with areas where mammoths congregated. Those findings, highlighted in the new issue of the journal Science Advances, provide evidence that mammoths and early hunter-gatherers shared habitat in the region. The long-term predictable presence of woolly mammoths would have attracted humans to the area.
Published Study reveals a reaction at the heart of many renewable energy technologies
(via sciencedaily.com) Original source Chemists have mapped how proton-coupled electron transfers happen at the surface of an electrode. Their results could help researchers design more efficient fuel cells, batteries, or other energy technologies.
Published Cryo-microscopy reveals nano-sized copy machine implicated in origin of life
(via sciencedaily.com) Original source RNA is thought to have sparked the origin of life by self-copying. Researchers have now revealed the atomic structure of an 'RNA copy machine' through cryo-EM. This breakthrough sheds light on a primordial RNA world and fuels advancements in RNA nanotechnology and medicine.
Published The power of pause: Controlled deposition for effective and long-lasting organic devices
(via sciencedaily.com) Original source In organic optoelectronic devices, the control of molecular deposition on thin films is important for optimal surface arrangement and device performance. In a recent study, researchers developed a new method for achieving stable deposition on thin films effectively. They also developed a tool to track real-time potential changes on the surface. These findings are expected to aid the improvement of organic devices, such as organic light-emitting diodes, in terms of efficacy and durability.
Published Core-shell 'chemical looping' boosts efficiency of greener approach to ethylene production
(via sciencedaily.com) Original source Oxidative coupling of methane (OCM) is now one step closer to leaving the lab and entering the real world. Researchers have developed an OCM catalyst that exceeds 30 percent when it comes to the production of ethylene.
Published New catalytic technique creates key component of incontinence drug in less time
(via sciencedaily.com) Original source Researchers have developed a unique catalyst that promises to revolutionize drug synthesis. It overcomes a common problem associated with the production of drugs from ketones. Using their catalyst, the researchers synthesized a key component of the commonly used incontinence drug oxybutynin. Their results underscore the potential of the catalyst to improve drug discovery and development.
Published Capturing greenhouse gases with the help of light
(via sciencedaily.com) Original source Researchers use light-reactive molecules to influence the acidity of a liquid and thereby capture of carbon dioxide. They have developed a special mixture of different solvents to ensure that the light-reactive molecules remain stable over a long period of time. Conventional carbon capture technologies are driven by temperature or pressure differences and require a lot of energy. This is no longer necessary with the new light-based process.
Published Spying on a shape-shifting protein
(via sciencedaily.com) Original source Researchers are using crystallography to gain a better understanding of how proteins shapeshift. The knowledge can provide valuable insight into stopping and treating diseases.
Published The first assessment of toxic heavy metal pollution in the Southern Hemisphere over the last 2,000 years
(via sciencedaily.com) Original source Human activity, from burning fossil fuels and fireplaces to the contaminated dust produced by mining, alters Earth's atmosphere in countless ways. Records of these impacts over time are preserved in everlasting polar ice that serves as a sort of time capsule, allowing scientists and historians to link Earth's history with that of human societies. In a new study, ice cores from Antartica show that lead and other toxic heavy metals linked to mining activities polluted the Southern Hemisphere as early as the 13th century.
Published Catalytic combo converts CO2 to solid carbon nanofibers
(via sciencedaily.com) Original source Scientists have developed a way to convert carbon dioxide (CO2), a potent greenhouse gas, into carbon nanofibers, materials with a wide range of unique properties and many potential long-term uses. Their strategy uses tandem electrochemical and thermochemical reactions run at relatively low temperatures and ambient pressure and could successfully lock carbon away to offset or even achieve negative carbon emissions.
Published Ancient cities provide key datasets for urban planning, policy and predictions in the Anthropocene
(via sciencedaily.com) Original source A new study shows how state-of-the-art methods and perspectives from archaeology, history, and palaeoecology are shedding new light on 5,500 years of urban life.
Published Prehistoric person with Turner syndrome identified from ancient DNA
(via sciencedaily.com) Original source Researchers have developed a new technique to measure the number of chromosomes in ancient genomes more precisely, using it to identify the first prehistoric person with mosaic Turner syndrome (characterized by one X chromosome instead of two [XX]), who lived about 2500 years ago.
Published Making an important industrial synthesis more environmentally friendly
(via sciencedaily.com) Original source Researchers have resolved a problem that has limited the environmental sustainability of peracid synthesis. By judicious choice of the solvent and light input, approximately room-temperature autoxidation of aldehydes proceeds in a manner that results in industrially useful peracids or carboxylic acids. This work is an important advance in green chemistry that will help minimize the carbon footprint of the chemical industry.
Published Researchers step closer to mimicking nature's mastery of chemistry
(via sciencedaily.com) Original source In nature, organic molecules are either left- or right-handed, but synthesizing molecules with a specific 'handedness' in a lab is hard to do. Make a drug or enzyme with the wrong 'handedness,' and it just won't work. Now chemists are getting closer to mimicking nature's chemical efficiency through computational modeling and physical experimentation.