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Categories: Anthropology: Cultures, Chemistry: Organic Chemistry

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Use of the greenhouse gas CO2 as a chemical raw material would not only reduce emissions, but also the consumption of fossil feedstocks. A novel metal-free organic framework could make it possible to electrocatalytically produce ethylene, a primary chemical raw material, from CO2. Nitrogen atoms with a particular electron configuration play a critical role for the catalyst.

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A new study found evidence that Indigenous groups in the Pacific Northwest were intentionally harvesting edible camas bulbs at optimal stages of the plant's maturation as far back as 3,500 years ago.

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The analysis of fat traces in over one hundred pottery vessels reveals deep changes in food consumption and preparation by communities living in central Germany between the Early Neolithic and the Late Bronze Age, as well as in their relation with innovations in pottery styles and decorations. In a groundbreaking study, researchers identified a generalized inclusion of dairy products in prehistoric diets, a preference in consuming pork with the arrival of communities from the Eurasian Steppe, and the importance of dairy products in funeral rites. Central Germany was a key region for the emergence of great prehistoric cultures, such as the Linear Pottery Culture, the Corded Ware Culture, the Bell Beaker populations and the Unetice Culture, one of the first state societies in Europe.

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By converting their data into sounds, scientists discovered how hydrogen bonds contribute to the lightning-fast gyrations that transform a string of amino acids into a functional, folded protein. Their report offers an unprecedented view of the sequence of hydrogen-bonding events that occur when a protein morphs from an unfolded to a folded state.

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Scientists have taken a step closer to replicating nature's processes of self-assembly. The study describes the synthetic construction of a tiny, self-assembled crystal known as a 'pyrochlore,' which bears unique optical properties. The advance provides a steppingstone to the eventual construction of sophisticated, self-assembling devices at the nanoscale -- roughly the size of a single virus.

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The study's findings show mergansers arrived in the New Zealand region at least seven million years ago from the Northern Hemisphere, in a separate colonisation event to that which led to the Brazilian merganser.

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Investigating ways to create high-performance steel, a research team used theoretical calculations on 120 combinations of 12 alloy elements, such as aluminum and titanium, with carbon and nitrogen, while also systematically clarifying the bonding mechanism.

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Using DNA origami, researchers have built a diamond lattice with a periodicity of hundreds of nanometers -- a new approach for manufacturing semiconductors for visible light.

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The patterns of dispersal of early humans across continents and islands are hotly debated, but researchers have found that Pleistocene hunter-gatherers settled in Cyprus thousands of years earlier than previously thought. In examining the timing of the first human occupation of Cyprus, research found that large islands in the Mediterranean Sea were attractive and favorable destinations for palaeolithic peoples. These findings refute previous studies that suggested Mediterranean islands would have been unreachable and inhospitable for Pleistocene hunter-gatherer societies.

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C-H activation-based method should speed drug molecule design and diversification.

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A team of chemists has achieved a significant breakthrough in the field of chemical synthesis, developing a novel method for manipulating carbon-hydrogen bonds. This groundbreaking discovery provides new insights into the molecular interactions of positively charged carbon atoms. By selectively targeting a specific C--H bond, they open doors to synthetic pathways that were previously closed -- with potential applications in medicine.

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Vanilla, the most widely used flavoring compound in confectionaries and cosmetics, gets its sweet flavor and aroma from the chemical compound -- 'vanillin'. However, the large-scale production of natural vanillin is impeded by the lack of microbial processes and enzymes which can commercially generate vanillin. Now, researchers have genetically engineered a novel enzyme which can convert ferulic acid from plant waste into vanillin in a one-step sustainable process.

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The optimal design of a novel zeolite catalyst enables tandem reaction that turns greenhouse gases into value-added chemicals, report scientists. By tuning the separation between different active sites on the catalyst, they achieved the stepwise conversion of methane into methanol and then to hydrocarbons at mild conditions. These findings will help reduce energy costs and greenhouse gas emissions across various industrial fields.

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Semiconductors are the foundation of all modern electronics. Now, researchers have developed a new method where organic semiconductors can become more conductive with the help of air as a dopant. The study is a significant step towards future cheap and sustainable organic semiconductors.

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Researchers who contributed to the development of record-breaking solar cells a few years ago, expanded their invention. The self-assembled monolayers can now be applied not only in inverted but also in regular structure perovskite solar cells.

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A battery made from zinc and lignin that can be used over 8000 times. This has been developed with a vision to provide a cheap and sustainable battery solution for countries where access to electricity is limited.

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Polystyrene is made from styrene building blocks and is the most widely used plastic in terms of volume, for example in packaging. Unlike PET, which can now be produced and recycled using biotechnological methods, the production of polystyrene has so far been a purely chemical process. The plastic can't be broken down by biotechnological means, either. Researchers are looking for ways to rectify this: An international team decoded a bacterial enzyme that plays a key role in styrene degradation. This paves the way for biotechnological application.

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A method has been discovered to treat water heavily contaminated with unhealthful forever chemicals, known by chemists as PFAS or poly- and per-fluoroalkyl substances. It involves treating heavily contaminated water with ultraviolet (UV) light, sulfite, and a process called electrochemical oxidation. It breaks up strong fluorine-to-carbon bonds in the PFAS compounds and other concentrated organic compounds in heavily polluted water. The reaction also occurs at room temperature without a need for additional heat or high pressure. This method is expected to be useful in cleanups of PFAS pollution from decades of fire suppressant foam use at military facilities.

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Perovskites are among the most researched topics in materials science. Recently, a research team has solved an age-old challenge to synthesize all-organic two-dimensional perovskites, extending the field into the exciting realm of 2D materials. This breakthrough opens up a new field of 2D all-organic perovskites, which holds promise for both fundamental science and potential applications.

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The global chemical industry is a major fossil fuel consumer and climate change contributor; however, new research has identified how the sector could clean up its green credentials by getting dirty.