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Categories: Chemistry: General, Chemistry: Organic Chemistry
Published Quantum chemistry: Molecules caught tunneling
(via sciencedaily.com) Quantum effects can play an important role in chemical reactions. Physicists have now observed a quantum mechanical tunneling reaction in experiments. The observation can also be described exactly in theory. The scientists provide an important reference for this fundamental effect in chemistry. It is the slowest reaction with charged particles ever observed.
Published New study could help pinpoint hidden helium gas fields -- and avert a global supply crisis
(via sciencedaily.com) Helium -- essential for many medical and industrial processes -- is in critically short supply worldwide. Production is also associated with significant carbon emissions, contributing to climate change. This study provides a new concept in gas field formation to explain why, in rare places, helium accumulates naturally in high concentrations just beneath the Earth's surface. The findings could help locate new reservoirs of carbon-free helium -- and potentially also hydrogen.
Published Sustainable process for the production of vanillin from lignin makes further progress
(via sciencedaily.com) The demand for vanillin vastly outstrips the natural resources of this flavoring agent. A chemical process is thus used to produce the required large quantities of vanillin from petroleum, which is far less expensive than obtaining the substance from fermented genuine vanilla pods. Another alternative is to make vanillin from lignin, a waste product of the wood pulping industry. A team has now managed to further enhance their method of electrochemical production of vanillin from lignin in that they employ a 'green' oxidation method for this purpose.
Published Scientists synthesize cerium mineral which holds promise for biomedical research
(via sciencedaily.com) Geoscientists have developed a cheap and environmentally friendly method for the synthesis of cerianite, a rare earth mineral which holds promise for the treatment of diseases associated with inflammation, including cancer.
Published Degrading modified proteins could treat Alzheimer's, other 'undruggable' diseases
(via sciencedaily.com) Certain diseases, including Alzheimer's, are currently considered 'undruggable' because traditional small molecule drugs can't interfere with the proteins responsible for the illnesses. But a new technique that specifically targets and breaks apart certain proteins -- rather than just interfering with them -- may offer a pathway toward treatment. Researchers have now designed a compound that targets and breaks down a post-translationally modified protein closely associated with Alzheimer's disease.
Published New purification method could make protein drugs cheaper
(via sciencedaily.com) Original source Engineers devised a way to purify protein drugs during manufacturing. Their approach, which uses nanoparticles to rapidly crystallize proteins, could help make protein drugs more affordable and accessible, especially in developing countries.
Published New hydrogel stem cell treatment repairs injured brain tissue in mice
(via sciencedaily.com) A new hybrid hydrogel that safely delivers stem cells to brain injury sites in mice has been developed. This solves a major challenge -- keeping stem cells alive for long enough to evolve into the cells required to create new tissue after insertion into a damaged part of the body.
Published New superacid converts harmful compounds into sustainable chemicals
(via sciencedaily.com) Researchers have succeeded in producing very special catalysts, known as 'Lewis superacids', which can be used to break strong chemical bonds and speed up reactions. The production of these substances has, until now, proven extremely difficult. The chemists' discovery enables non-biodegradable fluorinated hydrocarbons, similar to Teflon, and possibly even climate-damaging greenhouse gases, such as sulphur hexafluoride, to be converted back into sustainable chemicals.
Published Chaos on the nanometer scale
(via sciencedaily.com) Chaotic behavior is typically known from large systems: for example, from weather, from asteroids in space that are simultaneously attracted by several large celestial bodies, or from swinging pendulums that are coupled together. On the atomic scale, however, one does normally not encounter chaos -- other effects predominate. Now scientists have been able to detect clear indications of chaos on the nanometer scale -- in chemical reactions on tiny rhodium crystals.
Published New material may offer key to solving quantum computing issue
(via sciencedaily.com) A new form of heterostructure of layered two-dimensional (2D) materials may enable quantum computing to overcome key barriers to its widespread application, according to an international team of researchers.
Published New method creates material that could create the next generation of solar cells
(via sciencedaily.com) Perovskites, a family of materials with unique electric properties, show promise for use in a variety fields, including next-generation solar cells. A team of scientists has now created a new process to fabricate large perovskite devices that is more cost- and time-effective than previously possible and that they said may accelerate future materials discovery.
Published Fastest laser camera films combustion in real time
(via sciencedaily.com) A research team has developed one of the world's fastest single-shot laser cameras, which is at least a thousand times faster than today's most modern equipment for combustion diagnostics. The discovery has enormous significance for studying the lightning-fast combustion of hydrocarbons.
Published Research captures and separates important toxic air pollutant
(via sciencedaily.com) A series of new stable, porous materials that capture and separate benzene have been developed.
Published Making engineered cells dance to ultrasound
(via sciencedaily.com) A team has developed a method for selectively manipulating genetically engineered cells with ultrasound.
Published Electrodes grown in the brain -- paving the way for future therapies for neurological disorders
(via sciencedaily.com) The boundaries between biology and technology are becoming blurred. Researchers have now successfully grown electrodes in living tissue using the body's molecules as triggers. The result paves the way for the formation of fully integrated electronic circuits in living organisms.
Published Plastic upcycling to close the carbon cycle
(via sciencedaily.com) Original source A new method to convert waste plastic to fuel and raw materials promises to help close the carbon cycle at mild temperature and with high yield.
Published Novel air filter captures wide variety of pollutants
(via sciencedaily.com) Original source An air filter made out of corn protein instead of petroleum products can concurrently capture small particulates as well as toxic chemicals like formaldehyde that current air filters can't. The research could lead to better air purifiers, particularly in regions of the world that suffer from very poor air quality. The more environmentally friendly air filter was able to simultaneously capture 99.5% of small particulate matter, similar to commercial HEPA filters, and 87% of formaldehyde, which is higher than specially designed air filters for those types of toxics.
Published Theory can sort order from chaos in complex quantum systems
(via sciencedaily.com) Theoretical chemists have developed a theory that can predict the threshold at which quantum dynamics switches from 'orderly' to 'random,' as shown through research using large-scale computations on photosynthesis models.
Published A human interactome to prioritize drug discovery
(via sciencedaily.com) Researchers create a network of interacting proteins -- or interactome -- to aid drug discovery.
Published A molecular machine's secret weapon exposed
(via sciencedaily.com) RNAs can wreak havoc on cells if they aren't removed at the right time. Dis3L2 is a molecular 'machine' that untangles and chews up RNAs, but scientists have been unable to explain how. Biochemists have now pieced together the answer. By shape-shifting, the machine unsheathes a lethal wedge that pries open and chews up RNA molecules, a behavior previously unseen.