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Categories: Chemistry: General, Chemistry: Organic Chemistry

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A research team has developed a novel catalyst for the high-efficiency and stable production of high-purity green hydrogen.

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A new paper describes a significant leap forward in assembling polyhedral nanoparticles. The researchers introduce and demonstrate the power of a novel synthetic strategy that expands possibilities in metamaterial design. These are the unusual materials that underpin 'invisibility cloaks' and ultrahigh-speed optical computing systems.

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A new study shows that the physics principle of 'nucleation' can perform complex calculations that rival a simple neural network. The work may suggest avenues for new ways to think about computation using the principles of physics.

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Researchers have developed a framework that uses machine learning to accelerate the search for new proton-conducting materials, that could potentially improve the efficiency of hydrogen fuel cells.

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A team has introduced a strategy for converting carbon-nitrogen atom pairs in a frequently used ring-shaped compound into carbon-carbon atom pairs. The method has potential in the quest for active ingredients for new drugs, for example.

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Organic semiconductors are materials that find applications in various electronic devices. Exciton binding energy is an important attribute that influences the behavior of these materials. Now, researchers have employed advanced spectroscopic techniques to accurately determine these energies for various organic semiconductor materials, with a high precision of 0.1 electron volts. Their study reveals unexpected correlations that are poised to shape the future of organic optoelectronics, influence design principles, and find potential applications in bio-related materials.

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In the switch to 'greener' energy sources, the demand for rechargeable lithium-ion batteries is surging. However, their cathodes typically contain cobalt -- a metal whose extraction has high environmental and societal costs. Now, researchers in report evaluating an earth-abundant, carbon-based cathode material that could replace cobalt and other scarce and toxic metals without sacrificing lithium-ion battery performance.

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Researchers have developed a material to remove urea from water and potentially convert it into hydrogen gas. By building these materials of nickel and cobalt atoms with carefully tailored electronic structures, the group has unlocked the potential to enable these transition metal oxides and hydroxides to selectively oxidize urea in an electrochemical reaction. The team's findings could help use urea in waste streams to efficiently produce hydrogen fuel through the electrolysis process, and could be used to sequester urea from water, maintaining the long-term sustainability of ecological systems, and revolutionizing the water-energy nexus.

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A new battery material could offer a more sustainable way to power electric cars. The lithium-ion battery includes a cathode based on organic materials, instead of cobalt or nickel.

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Researchers have synthesized the first 2D heavy fermion. The material, a layered intermetallic crystal composed of cerium, silicon, and iodine (CeSiI), has electrons that are 1000x heavier and is a new platform to explore quantum phenomena.

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Researchers have created a new way to detect 'forever chemical' pollution in water, via a luminescent sensor.

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Cold, flu and COVID-19 season brings that now-familiar ritual: swab, wait, look at the result. But what if, instead of taking 15 minutes or more, a test could quickly determine whether you have COVID-19 with a glowing chemical? In a new study, researchers describe a potential COVID-19 test inspired by bioluminescence. Using a molecule found in crustaceans, they have developed a rapid approach that detects SARS-CoV-2 protein comparably to one used in vaccine research.

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Fake plants are moving into the 21st century! Researchers developed literal 'power plants' -- tiny, leaf-shaped generators that create electricity from a blowing breeze or falling raindrops. The team tested the energy harvesters by incorporating them into artificial plants.

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Chemists have mapped how proton-coupled electron transfers happen at the surface of an electrode. Their results could help researchers design more efficient fuel cells, batteries, or other energy technologies.

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'Soft robots,' medical devices and implants, and next-generation drug delivery methods could soon be guided with magnetism -- thanks to a metal-free magnetic gel developed by researchers. Carbon-based, magnetic molecules are chemically bonded to the molecular network of a gel, creating a flexible, long-lived magnet for soft robotics.

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Researchers have helped minimize the cost of an important class of chemical transformations: converting nitriles into primary amines. Their experimental protocol uses a cheap nickel catalyst instead of an expensive noble metal, is convenient to conduct, and works for a broad range of starting materials. This work is an important advance in sustainable chemistry that might help lower the cost of producing nylon and many other everyday products.

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RNA is thought to have sparked the origin of life by self-copying. Researchers have now revealed the atomic structure of an 'RNA copy machine' through cryo-EM. This breakthrough sheds light on a primordial RNA world and fuels advancements in RNA nanotechnology and medicine.

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Textbook models will need to be re-drawn after a team of researchers found that water molecules at the surface of salt water are organised differently than previously thought.

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In organic optoelectronic devices, the control of molecular deposition on thin films is important for optimal surface arrangement and device performance. In a recent study, researchers developed a new method for achieving stable deposition on thin films effectively. They also developed a tool to track real-time potential changes on the surface. These findings are expected to aid the improvement of organic devices, such as organic light-emitting diodes, in terms of efficacy and durability.

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Oxidative coupling of methane (OCM) is now one step closer to leaving the lab and entering the real world. Researchers have developed an OCM catalyst that exceeds 30 percent when it comes to the production of ethylene.