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Categories: Chemistry: General, Chemistry: Organic Chemistry

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Gold (Au)-based electrocatalysts used for hydrogen production via water electrolysis exhibit high chemical stability but low hydrogen evolution reaction (HER) activity. Alloying them with nickel (Ni) can improve their HER activity. A recent study investigated the HER activity and surface properties of AuNi alloy prepared on single crystal Au surfaces, revealing the atomic structural changes and surface sites responsible for enhanced HER activity of AuNi/Au catalyst during electrolysis.

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A new study suggests that Cytochromes P450 (CYP450s) enzymes can sense and respond to stimuli, acting like soft robots in living systems.

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A water purification system separates out salt and other unnecessary particles with an electrified version of dialysis. Successfully applied to wastewater with planned expansion into rivers and seas, the method saves money and saps 90% less energy than its counterparts.

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Scientists detect a new carbon compound in space for the first time. Known as methyl cation (pronounced cat-eye-on) (CH3+), the molecule is important because it aids the formation of more complex carbon-based molecules. Methyl cation was detected in a young star system, with a protoplanetary disk, known as d203-506, which is located about 1,350 light-years away in the Orion Nebula.

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CoSn(OH)6 (CSO) is an effective oxygen evolution reaction (OER) catalyst, necessary for developing next-generation lithium -- air batteries. However, current methods of synthesizing CSO are complicated and slow. Recently, an international research team synthesized CSO in a single step within 20 minutes using solution plasma to generate CSO nanocrystals with excellent OER catalytic properties. Their findings could boost the manufacturing of high energy density batteries.

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Chemists discovered a new way to make polymers stronger: introduce a few weaker bonds into the material. Working with polyacrylate elastomers, they could increase the materials' resistance to tearing up to tenfold by using a weaker type of crosslinker to join some of the polymer building blocks.

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To unveil the previously elusive behavior and stability of complex metal compounds found in aqueous solutions called 'POMs', researchers have created a speciation atlas. This achievement has the potential to drive new discoveries and advancements in fields like catalysis, medicine, and beyond.

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Specially designed gardens could reduce the amount of a toxic chemical associated with tires entering our waterways by more than 90 per cent, new research shows.

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A gel that combines both stiffness and toughness is a step forward in the bid to create biodegradable implants for joint injuries, according to new research. Mimicking articular cartilage, found in our knee and hip joints, is challenging. This cartilage is key to smooth joint movement, and damage to it can cause pain, reduce function, and lead to arthritis. One potential solution is to implant artificial scaffolds made of proteins that help the cartilage regenerate itself as the scaffold biodegrades. How well the cartilage regenerates is linked to how well a scaffold can mimic the biological properties of cartilage, and to date, researchers have struggled to combine the seemingly incompatible properties of stiffness and toughness. Now, new research outlines a method to marry these properties in a biodegradable gel.

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Collaborators have created 'living-like' bioactive interior architecture designed to one day protect us from hidden airborne threats. This publication establishes that the lab's biomaterial manufacturing process is compatible with the leading-edge cell-free engineering that gives the bioactive sites their life-like properties.

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Researchers have demonstrated how carbon dioxide can be captured from industrial processes -- or even directly from the air -- and transformed into clean, sustainable fuels using just the energy from the Sun.

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Genome Architecture Mapping captures complex, multi-way interactions in the genome. This is different than the workhorse technique of 3D genomics, which sees mostly two-way contacts, finds a new study.

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Researchers are exploring the different ways of harvesting materials from water.

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Although passenger vehicle catalytic converters have been mandatory for over 30 years, there is still plenty of room for improvement. For instance, they only work correctly when the engine is sufficiently hot, which is not always the case, especially with hybrid vehicles. Researchers have now developed an improved catalyst that can properly purify exhaust gases even at room temperature.

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A new process enables printing of nanometer-scale quartz glass structures directly onto semiconductor chips. A hybrid organic-inorganic polymer resin is used as feedstock material for 3D printing of silicon dioxide. Since the process works without sintering, the required temperatures are significantly lower. Simultaneously, increased resolution enables visible-light nanophotonics.

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Perfect noncaloric replacements for sugar and high fructose corn syrup just don't exist yet. For example, some alternatives have a lingering sweet aftertaste and lack a sugar-like mouthfeel, leaving some consumers unsatisfied. Now, researchers propose adding blends of nutritionally important mineral salts to make noncaloric sweeteners seem more like the real thing. Taste-testers indicated that these blends gave zero- and low-calorie drinks a better flavor.

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A cutting-edge experiment has revealed the quantum dynamics of one of nature's most crucial processes.

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An innovative, decade-long experiment in the foothills of California's Sierra Nevada mountains shows carbon stocks buried deep underground are vulnerable to climate change. The findings have implications for mitigating global warming through the natural carbon sinks provided by soil and forests which capture 25% of all carbon emissions.

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Scientists develop positive electrode material using an organic redox polymer based on phenothiazine. Aluminium-ion batteries containing this material stored an unprecedented 167 milliampere hours per gram, outperforming batteries using graphite as electrode material. Aluminium-ion batteries are considered a promising alternative to conventional batteries that use scarce raw materials such as lithium.

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Scientists investigate the promising properties of a common, Earth-abundant salt.