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Categories: Chemistry: Organic Chemistry, Paleontology: Fossils
Published Shedding light on the chemical enigma of sulfur trioxide in the atmosphere
(via sciencedaily.com) Original source Researchers discovered that sulfur trioxide can form products other than sulfuric acid in the atmosphere by interacting with organic and inorganic acids. These previously uncharacterized acid sulfuric anhydride products are almost certainly key contributors to atmospheric new particle formation and a way to efficiently incorporate carboxylic acids into atmospheric nanoparticles. Better prediction of aerosol formation can help curb air pollution and reduce uncertainties concerning climate change.
Published Producing novel liquid crystals by stacking antiaromatic units
(via sciencedaily.com) Original source In a recent study, researchers developed modified norcorrole molecules whose side chains favored the formation of columnar -stacking structures. Using these compounds, they produced liquid crystals with high electrical conductivity and thermotropic properties. Their findings open up new design avenues for materials useful in electronics, sensing, optics, and biomedicine.
Published Unlocking complex sulfur molecules: Novel approach for synthesis of functionalized benzenethiol equivalents
(via sciencedaily.com) Original source Organosulfur skeletons are crucial in many fields, including pharmaceuticals and electronics. Synthesizing organosulfur skeletons requires o-bromobenzenethiols. However, conventional methods face challenges due to quick oxidation and formation of highly reactive intermediates. Researchers have now developed a new method for synthesizing o-bromobenzenethiols from aryne intermediates via bromothiolation. This method can pave the way for the synthesis of new organosulfur compounds with applications in diverse fields.
Published Ancient people hunted extinct elephants at Tagua Tagua Lake in Chile 12,000 years ago
(via sciencedaily.com) Original source Thousands of years ago, early hunter-gatherers returned regularly to Tagua Tagua Lake in Chile to hunt ancient elephants and take advantage of other local resources, according to a new study.
Published 3,500-year-old Mycenaean armor was suitable for extended battle
(via sciencedaily.com) Original source A 3,500-year-old suit of Mycenaean armour may have been used in battle -- and not just for ceremonial purposes as previously thought -- new research reveals.
Published Researchers design new metal-free porous framework materials
(via sciencedaily.com) Original source Researchers have used computational design methods to develop non-metal organic porous framework materials, with potential applications in areas such as catalysis, water capture or hydrogen storage.
Published Scientists develop new battery-free lactic acid sensor
(via sciencedaily.com) Original source Scientists have created a new type of chemosensor (demonstrated for lactic acid sensing) which functions with electricity but without the need for reference electrodes or battery power.
Published Ethylene from CO2: Building-kit catalyst
(via sciencedaily.com) Original source Use of the greenhouse gas CO2 as a chemical raw material would not only reduce emissions, but also the consumption of fossil feedstocks. A novel metal-free organic framework could make it possible to electrocatalytically produce ethylene, a primary chemical raw material, from CO2. Nitrogen atoms with a particular electron configuration play a critical role for the catalyst.
Published Researchers discover hidden step in dinosaur feather evolution
(via sciencedaily.com) Original source Scientists discover 'zoned development' in dinosaur skin, with zones of reptile-style scales and zones of bird-like skin with feathers. A new dinosaur skin fossil has been found to be composed of silica -- the same as glass.
Published By listening, scientists learn how a protein folds
(via sciencedaily.com) Original source By converting their data into sounds, scientists discovered how hydrogen bonds contribute to the lightning-fast gyrations that transform a string of amino acids into a functional, folded protein. Their report offers an unprecedented view of the sequence of hydrogen-bonding events that occur when a protein morphs from an unfolded to a folded state.
Published Blueprints of self-assembly
(via sciencedaily.com) Original source Scientists have taken a step closer to replicating nature's processes of self-assembly. The study describes the synthetic construction of a tiny, self-assembled crystal known as a 'pyrochlore,' which bears unique optical properties. The advance provides a steppingstone to the eventual construction of sophisticated, self-assembling devices at the nanoscale -- roughly the size of a single virus.
Published Evolutionary history of extinct duck revealed
(via sciencedaily.com) Original source The study's findings show mergansers arrived in the New Zealand region at least seven million years ago from the Northern Hemisphere, in a separate colonisation event to that which led to the Brazilian merganser.
Published Seeking stronger steel, systematic look at 120 combinations of alloy elements provides clues
(via sciencedaily.com) Original source Investigating ways to create high-performance steel, a research team used theoretical calculations on 120 combinations of 12 alloy elements, such as aluminum and titanium, with carbon and nitrogen, while also systematically clarifying the bonding mechanism.
Published Diverse headgear in hoofed mammals evolved from common ancestor
(via sciencedaily.com) Original source From the small ossicones on a giraffe to the gigantic antlers of a male moose -- which can grow as wide as a car -- the headgear of ruminant hooved mammals is extremely diverse, and new research suggests that despite the physical differences, fundamental aspects of these bony adaptations likely evolved from a common ancestor.
Published Diamond glitter: A play of colors with artificial DNA crystals
(via sciencedaily.com) Original source Using DNA origami, researchers have built a diamond lattice with a periodicity of hundreds of nanometers -- a new approach for manufacturing semiconductors for visible light.
Published Ancient arachnid from coal forests of America stands out for its spiny legs
(via sciencedaily.com) Original source The spiny legged 308-million-year-old arachnid Douglassarachne acanthopoda was discovered the famous Mazon Creek locality.
Published Chemists develop new method for making gamma chiral centers on simple carboxylic acids
(via sciencedaily.com) Original source C-H activation-based method should speed drug molecule design and diversification.
Published Breaking bonds to form bonds: Rethinking the Chemistry of Cations
(via sciencedaily.com) Original source A team of chemists has achieved a significant breakthrough in the field of chemical synthesis, developing a novel method for manipulating carbon-hydrogen bonds. This groundbreaking discovery provides new insights into the molecular interactions of positively charged carbon atoms. By selectively targeting a specific C--H bond, they open doors to synthetic pathways that were previously closed -- with potential applications in medicine.
Published How did sabre-toothed tigers acquire their long upper canine teeth?
(via sciencedaily.com) Original source In a groundbreaking study an international team of scientists has investigated the evolutionary patterns behind the development of sabre teeth, with some unexpected results along the way.
Published Bioengineered enzyme creates natural vanillin from plants in one step
(via sciencedaily.com) Original source Vanilla, the most widely used flavoring compound in confectionaries and cosmetics, gets its sweet flavor and aroma from the chemical compound -- 'vanillin'. However, the large-scale production of natural vanillin is impeded by the lack of microbial processes and enzymes which can commercially generate vanillin. Now, researchers have genetically engineered a novel enzyme which can convert ferulic acid from plant waste into vanillin in a one-step sustainable process.