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Categories: Chemistry: Organic Chemistry, Paleontology: Climate

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Polymers can be thought of like trains: Just as a train is composed of multiple cars, polymers are made up of multiple monomers, and the couplings between the train cars are similar to the chemical bonds that link monomers together. While polymers have myriad applications -- from drug delivery to construction materials -- their structures and functions are restricted by the chemically similar monomer building blocks they're composed of. Now, chemists have developed a new reaction to create unique monomers in a controlled way. This reaction, which uses nickel as a catalyst, ultimately enables scientists to create polymers with unique and modifiable properties for drug delivery, energy storage, microelectronics and more.

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The control of artificial double-helical structures, which are essential for the development of high-order molecular systems, remains difficult. In a new study, researchers have developed novel double-helical monometallofoldamers that exhibit controllable helicity inversion and chiral information transfer, in response to external stimuli. These monometallofoldamers can lead to novel artificial supramolecular systems for molecular information transmission, amplification, replication, and other exciting applications in various fields of technology.

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Researchers developed a way to fingerprint organofluorine compounds -- sometimes called 'forever chemicals' --which could help authorities trace them to their source when they end up in aquifers, waterways or soil.

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Researchers found that how well light-converting molecules stack together in a solid is important for how well they convert light into electric current. A rigid molecule that stacked well showed excellent electricity generation in an organic solar cell and photocatalyst, easily outperforming a similar flexible molecule that did not stack well. This new way of improving the design of molecules could be used to pioneer the next generation of light-converting devices.

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Markings on a stone pillar at a 12,000 year-old archaeological site in Turkey likely represent the world's oldest solar calendar, created as a memorial to a devastating comet strike, experts suggest.

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The first continent-wide mapping study of plant life across Antarctica reveals growth in previously uncharted areas and is set to inform conservation measures across the region. The satellite survey of mosses, lichens and algae across the continent will form a baseline for monitoring how Antarctica's vegetation responds to climate change.

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Seeds, twigs, and insect parts found under two miles of ice confirm Greenland's ice sheet melted in the recent past, the first direct evidence that the center -- not just the edges -- of the two-mile-deep ice melted away in the recent geological past. The new research indicates that the giant ice sheet is more fragile than scientists had realized until the last few years -- and reveals increased risk of sea-level catastrophe in a warmer future.

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A research team developed artificial intelligence technology that could find ways to improve researchers' understanding of the chemical reactions involved in ammonia production and other complex chemical reactions.

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The rising earth beneath the Antarctic Ice Sheet will likely become a major factor in future sea level rise, a new study suggests.

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An international research team has succeeded in developing a new version of RNA building blocks with higher chemical reactivity and photosensitivity. This can significantly reduce the production time of RNA chips used in biotechnological and medical research. The chemical synthesis of these chips is now twice as fast and seven times more efficient.

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Clues to future sea level rise have been revealed by the first detailed maps of the underside of a floating ice shelf in Antarctica. An international research team deployed an unmanned submersible beneath the Dotson Ice Shelf in West Antarctica.

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Using powerful new visualization technologies, researchers have captured the first 3-D images of the structure of a key muscle receptor, providing new insights on how muscles develop across the animal kingdom and setting the stage for possible future treatments for muscular disorders.

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Lung diseases kill millions of people around the world each year. Treatment options are limited, and animal models for studying these illnesses and experimental medications are inadequate. Now, researchers describe their success in creating a mucus-based bioink for 3D printing lung tissue. This advance could one day help study and treat chronic lung conditions.

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Scientists have revealed that injury dressings found in first-aid kits can reliably be used to identify shark species involved in bite incidents by deploying medical gauze to gather DNA samples from aquatic equipment, such as surfboards.

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A research group has developed a new method that further improves the existing CRISPR/Cas technologies: it allows a more precise and seamless introduction of tags into proteins at the gene level. This technology could significantly improve research on proteins in living organisms and opens up new possibilities for medical research.

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Nanozymes are tiny, engineered substances that mimic the catalytic properties of natural enzymes, and they serve a variety of purposes in biomedicine, chemical engineering, and environmental applications. They are typically made from inorganic materials, including metal-based elements, which makes them unsuitable for many purposes due to their toxicity and high production costs. Organic-based nanozymes partially overcome some of these problems and have the potential for a broader range of applications, including food and agriculture, but they are still in the early stages of development. A new paper provides an overview of the current state of organic nanozymes and their future potential.

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Researchers have achieved a significant breakthrough that could lead to better -- and greener -- agricultural chemicals and everyday products. Using a process that combines natural enzymes and light, the team developed an eco-friendly way to precisely mix fluorine, an important additive, into chemicals called olefins -- hydrocarbons used in a vast array of products, from detergents to fuels to medicines. This groundbreaking method offers an efficient new strategy for creating high-value chemicals with potential applications in agrochemicals, pharmaceuticals, renewable fuels, and more.

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A study has made it possible to estimate experimentally the energy required to transfer protons from water to ionic liquids.

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Scientists transformed existing optoelectronic devices into ones that can control electron spin at room temperature, without a ferromagnet or magnetic field. Researchers replaced the electrodes of store-bought LEDs with a patented spin filter made from hybrid organic-inorganic halide perovskite.

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Non-reciprocal interactions allow the design of more efficient molecular systems. Scientists now propose a mechanism on how energy barriers in complex systems can be overcome. These findings can help to engineer molecular machines and to understand the self-organization of active matter.