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Categories: Chemistry: Organic Chemistry, Offbeat: Earth and Climate

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Under certain conditions, some algae are able to produce hydrogen -- a much sought-after green energy source. Its production takes place in the unique catalytic center of the unicellular algae and is only possible if certain cofactors of the relevant proteins are present. Researchers have identified how such a cofactor, the so-called hydrogen cluster, is assembled. Specifically, they describe the previously unexplained role of the enzyme HydF, which is involved in the final steps of assembly.

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A technical achievement marks a significant advance in the burgeoning field of observing individual molecules without the aid of fluorescent labels. While these labels are useful in many applications, they alter molecules in ways that can obscure how they naturally interact with one another. The new label-free method makes the molecules so easy to detect, it is almost as if they had labels.

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Engineers have helped design a new method to make hydrogen gas from water using only solar power and agricultural waste such as manure or husks. The method reduces the energy needed to extract hydrogen from water by 600%, creating new opportunities for sustainable, climate-friendly chemical production.

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A whaler's forgotten aerial photos from 1937 have given researchers the most detailed picture of the ice evolution in East Antarctica to date. The results show that the ice has remained stable and even grown slightly over almost a century, though scientists observe early signs of weakening. The research offers new insights that enhance predictions of ice changes and sea level rise.

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New research has determined the spatial structure of various processes of a novel gene-editing tool called 'prime editor.' Functional analysis based on these structures also revealed how a 'prime editor' could achieve reverse transcription, synthesizing DNA from RNA, without 'cutting' both strands of the double helix. Clarifying these molecular mechanisms contributes greatly to designing gene-editing tools accurate enough for gene therapy treatments.

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Advances in electrochromic coatings may bring us closer to environmentally friendly ways to keep inside spaces cool. Like eyeglasses that darken to provide sun protection, the optical properties of these transparent films can be tuned with electricity to block out solar heat and light. Now, researchers report demonstrating a new electrochromic film design based on metal-organic frameworks (MOFs) that quickly and reliably switch from transparent to glare-diminishing green to thermal-insulating red.

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Researchers have demonstrated the ability to engineer materials that are both stiff and capable of insulating against heat. This combination of properties is extremely unusual and holds promise for a range of applications, such as the development of new thermal insulation coatings for electronic devices.

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Orchid plants nurture their seedlings via an underground fungal network, new research has revealed.

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As a newly developed perovskite with a large amount of intrinsic oxygen vacancies, BaSc0.8W0.2O2.8 achieves high proton conduction at low and intermediate temperatures, report scientists. By the donor doping of large W6+, this material can take up more water to increase its proton concentration, as well as reduce the proton trapping through electrostatic repulsion between the dopant and proton. These findings could pave the way to the rational design of novel perovskites for protonic ceramic fuel cells (PCFCs) and electrolysis cells (PCECs).

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Most native species avoid more urbanized areas of Los Angeles, but slugs and snails may actually prefer these environments, according to a new study.

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Corals play an essential role in ocean ecosystems, and like many organisms, they are under threat from climate change and other human activities. To better protect coral, it's first necessary to understand them, in particular their reproductive life cycle, which only happens once a year. For the first time, researchers have produced a model for coral spawning, based on various environmental factors. They achieved this by tapping an often overlooked source of aquatic knowledge, an aquarium.

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The African turquoise killifish lives in ephemeral ponds in Zimbabwe and Mozambique. To survive the annual dry season, the fish's embryos enter a state of extreme suspended animation or 'diapause' for approximately 8 months. Now, researchers have uncovered the mechanisms that enabled the killifish to evolve this extreme survival state.

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Entomologists have solved the 250-year-old origin puzzle of the most prevalent indoor urban pest insect on the planet: the German cockroach. The team's research findings, representing the genomic analyses of over 280 specimens from 17 countries and six continents, show that this species evolved some 2,100 years ago from an outdoor-living species in Asia.

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Researchers have outlined a way to manipulate water molecules to make CO2R more efficient, with the ultimate goal of creating a clean energy loop. Through their new method, the team was able to perform CO2R with nearly 100% efficiency under mildly acidic conditions, using either gold or zinc as catalysts.

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Researchers have developed a new technique to view living mammalian cells. The team used a powerful laser, called a soft X-ray free electron laser, to emit ultrafast pulses of illumination at the speed of femtoseconds, or quadrillionths of a second. With this they could capture images of carbon-based structures in living cells for the first time, before the soft X-ray radiation damaged them.

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Researchers discovered that sulfur trioxide can form products other than sulfuric acid in the atmosphere by interacting with organic and inorganic acids. These previously uncharacterized acid sulfuric anhydride products are almost certainly key contributors to atmospheric new particle formation and a way to efficiently incorporate carboxylic acids into atmospheric nanoparticles. Better prediction of aerosol formation can help curb air pollution and reduce uncertainties concerning climate change.

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In a recent study, researchers developed modified norcorrole molecules whose side chains favored the formation of columnar -stacking structures. Using these compounds, they produced liquid crystals with high electrical conductivity and thermotropic properties. Their findings open up new design avenues for materials useful in electronics, sensing, optics, and biomedicine.

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Organosulfur skeletons are crucial in many fields, including pharmaceuticals and electronics. Synthesizing organosulfur skeletons requires o-bromobenzenethiols. However, conventional methods face challenges due to quick oxidation and formation of highly reactive intermediates. Researchers have now developed a new method for synthesizing o-bromobenzenethiols from aryne intermediates via bromothiolation. This method can pave the way for the synthesis of new organosulfur compounds with applications in diverse fields.

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Members of the vertebrate group including anglerfishes are unique in possessing a characteristic known as sexual parasitism, in which males temporarily attach or permanently fuse with females to mate. Now, researchers show that sexual parasitism arose during a time of major global warming and rapid transition for anglerfishes from the ocean floor to the deep, open sea.

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A new study demonstrates that kangaroos, wallabies and other Australian marsupials fear humans far more than any other predator.