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Categories: Chemistry: Organic Chemistry, Offbeat: Earth and Climate
Published Enhancing electron transfer for highly efficient upconversion OLEDs
(via sciencedaily.com) Original source Electron transfer is enhanced by minimal energetic driving force at the organic-semiconductor interface in upconversion (UC) organic light emitting diodes (OLEDs), resulting in efficient blue UC-OLEDs with low extremely turn-on voltage, scientists show. Their findings deepen the understanding of electron transfer mechanisms in organic optoelectronic devices and can lead to the development of efficient new optoelectronics without energy loss.
Published Scientists condition crocodiles to avoid killer cane toads
(via sciencedaily.com) Original source Scientists have trialled a new way to protect freshwater crocodiles from deadly invasive cane toads spreading across northern Australia.
Published Chemists synthesize plant-derived molecules that hold potential as pharmaceuticals
(via sciencedaily.com) Original source Chemists developed a way to synthesize complex molecules called oligocyclotryptamines, originally found in plants, which could hold potential as antibiotics, analgesics, or anticancer drugs.
Published Halogen bonding for selective electrochemical separation, path to sustainable chemical processing demonstrated
(via sciencedaily.com) Original source A team has reported the first demonstration of selective electrochemical separation driven by halogen bonding. This was achieved by engineering a polymer that modulates the charge density on a halogen atom when electricity is applied. The polymer then attracts only certain targets -- such as halides, oxyanions, and even organic molecules -- from organic solutions, a feature that has important implications for pharmaceuticals and chemical synthesis processes.
Published Reduce, reuse, 're-fly-cle'
(via sciencedaily.com) Original source Black soldier flies are now commercially used to consume organic waste -- but genetic modifications proposed by bioscientists could see the insects digesting a wider variety of refuse, while also creating raw ingredients for industry.
Published Why carbon nanotubes fluoresce when they bind to certain molecules
(via sciencedaily.com) Original source Nanotubes can serve as biosensors. They change their fluorescence when they bind to certain molecules. Until now, it was unclear why. Researchers have gained new insights into the cause of the fluorescence.
Published Researchers find unexpectedly large methane source in overlooked landscape
(via sciencedaily.com) Original source Researchers reported that upland landscapes were releasing some of the highest methane emissions yet documented among northern terrestrial ecosystems. The research was sparked when a potent greenhouse gas began ballooning under lawns in Fairbanks.
Published Pioneering plasma-catalytic process for CO2 hydrogenation to methanol under ambient conditions
(via sciencedaily.com) Original source A research team reports a pioneering plasma-catalytic process for the hydrogenation of CO2 to methanol at room temperature and atmospheric pressure. This breakthrough addresses the limitations of traditional thermal catalysis, which often requires high temperatures and pressures, resulting in low CO2 conversion and methanol yield.
Published Effective new catalyst brings hope for cleaner energy, wastewater treatment, and green chemistry
(via sciencedaily.com) Original source A catalyst that significantly enhances ammonia conversion could improve wastewater treatment, green chemical and hydrogen production.
Published Chemists develop new sustainable reaction for creating unique molecular building blocks
(via sciencedaily.com) Original source Polymers can be thought of like trains: Just as a train is composed of multiple cars, polymers are made up of multiple monomers, and the couplings between the train cars are similar to the chemical bonds that link monomers together. While polymers have myriad applications -- from drug delivery to construction materials -- their structures and functions are restricted by the chemically similar monomer building blocks they're composed of. Now, chemists have developed a new reaction to create unique monomers in a controlled way. This reaction, which uses nickel as a catalyst, ultimately enables scientists to create polymers with unique and modifiable properties for drug delivery, energy storage, microelectronics and more.
Published Breakthrough in molecular control: New bioinspired double helix with switchable chirality
(via sciencedaily.com) Original source The control of artificial double-helical structures, which are essential for the development of high-order molecular systems, remains difficult. In a new study, researchers have developed novel double-helical monometallofoldamers that exhibit controllable helicity inversion and chiral information transfer, in response to external stimuli. These monometallofoldamers can lead to novel artificial supramolecular systems for molecular information transmission, amplification, replication, and other exciting applications in various fields of technology.
Published Individuals vary in how air pollution impacts their mood
(via sciencedaily.com) Original source Affective sensitivity to air pollution (ASAP) describes the extent to which affect, or mood, fluctuates in accordance with daily changes in air pollution, which can vary between individuals, according to a new study.
Published Forever chemical pollution can now be tracked
(via sciencedaily.com) Original source Researchers developed a way to fingerprint organofluorine compounds -- sometimes called 'forever chemicals' --which could help authorities trace them to their source when they end up in aquifers, waterways or soil.
Published When mammoths roamed Vancouver Island
(via sciencedaily.com) Original source Mammoths, the massive pre-historic ice age cousins of the modern-day elephant, have always been understood to have inhabited parts of British Columbia, but the question of when has always been a bit woolly. Now, a new study has given scientists the clearest picture yet when the giant mammals roamed Vancouver Island.
Published Fishing is causing frightened fish to flee when they should flirt
(via sciencedaily.com) Original source Populations of squaretail grouper face an uncertain future as new research shows fishing that targets their spawning sites is causing males to be repeatedly scared away from their territories during their short mating meet-ups. By fleeing for safety, individuals are losing valuable time to catch the eye and court female fish.
Published Stacking molecules like plates improves organic solar device performance
(via sciencedaily.com) Original source Researchers found that how well light-converting molecules stack together in a solid is important for how well they convert light into electric current. A rigid molecule that stacked well showed excellent electricity generation in an organic solar cell and photocatalyst, easily outperforming a similar flexible molecule that did not stack well. This new way of improving the design of molecules could be used to pioneer the next generation of light-converting devices.
Published Carvings at ancient monument may be world's oldest calendars
(via sciencedaily.com) Original source Markings on a stone pillar at a 12,000 year-old archaeological site in Turkey likely represent the world's oldest solar calendar, created as a memorial to a devastating comet strike, experts suggest.
Published Engineers develop general, high-speed technology to model, explain catalytic reactions
(via sciencedaily.com) Original source A research team developed artificial intelligence technology that could find ways to improve researchers' understanding of the chemical reactions involved in ammonia production and other complex chemical reactions.
Published The next generation of RNA chips
(via sciencedaily.com) Original source An international research team has succeeded in developing a new version of RNA building blocks with higher chemical reactivity and photosensitivity. This can significantly reduce the production time of RNA chips used in biotechnological and medical research. The chemical synthesis of these chips is now twice as fast and seven times more efficient.
Published Smell reports reveal the need to expand urban air quality monitoring, say researchers
(via sciencedaily.com) Original source Researchers have uncovered surprising insights into the Vancouver region's 'smellscape' using data from the Smell Vancouver app. Analyzing 549 reports from one year of app data, they discovered that 'rotten' and 'chemical' odours dominated, making up about 65 per cent of submissions. These unpleasant smells were linked to self-reported health issues like headaches and anxiety, leading some residents to change their behaviours, like closing windows even in stifling-hot weather.