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Categories: Chemistry: Organic Chemistry, Offbeat: Paleontology and Archeology
Published Breaking bonds to form bonds: Rethinking the Chemistry of Cations
(via sciencedaily.com) Original source A team of chemists has achieved a significant breakthrough in the field of chemical synthesis, developing a novel method for manipulating carbon-hydrogen bonds. This groundbreaking discovery provides new insights into the molecular interactions of positively charged carbon atoms. By selectively targeting a specific C--H bond, they open doors to synthetic pathways that were previously closed -- with potential applications in medicine.
Published How did sabre-toothed tigers acquire their long upper canine teeth?
(via sciencedaily.com) Original source In a groundbreaking study an international team of scientists has investigated the evolutionary patterns behind the development of sabre teeth, with some unexpected results along the way.
Published Bioengineered enzyme creates natural vanillin from plants in one step
(via sciencedaily.com) Original source Vanilla, the most widely used flavoring compound in confectionaries and cosmetics, gets its sweet flavor and aroma from the chemical compound -- 'vanillin'. However, the large-scale production of natural vanillin is impeded by the lack of microbial processes and enzymes which can commercially generate vanillin. Now, researchers have genetically engineered a novel enzyme which can convert ferulic acid from plant waste into vanillin in a one-step sustainable process.
Published A novel multifunctional catalyst turns methane into valuable hydrocarbons
(via sciencedaily.com) Original source The optimal design of a novel zeolite catalyst enables tandem reaction that turns greenhouse gases into value-added chemicals, report scientists. By tuning the separation between different active sites on the catalyst, they achieved the stepwise conversion of methane into methanol and then to hydrocarbons at mild conditions. These findings will help reduce energy costs and greenhouse gas emissions across various industrial fields.
Published Iconic baobabs: The origin and long-distance travels of upside down trees
(via sciencedaily.com) Original source The research cracks the code on the iconic baobab tree's origin story, revealing their surprising origins in Madagascar and incredible long-distance dispersals to Africa and Australia. The study unveils how baobabs developed unique pollination mechanisms -- some attracting hawkmoths, others lemurs, and even bats -- showcasing remarkable evolutionary adaptations. The research sheds light on how climate change has shaped the baobab's distribution and diversification over millions of years, offering valuable insights for understanding plant responses to future environmental shifts.
Published First 'warm-blooded' dinosaurs may have emerged 180 million years ago
(via sciencedaily.com) Original source The ability to regulate body temperature, a trait all mammals and birds have today, may have evolved among some dinosaurs early in the Jurassic period about 180 million years ago. The new study looked at the spread of dinosaurs across different climates on Earth throughout the Mesozoic Era (the dinosaur era lasting from 230 to 66 million years ago), drawing on 1,000 fossils, climate models and the geography of the period, and dinosaurs' evolutionary trees.
Published Next-generation sustainable electronics are doped with air
(via sciencedaily.com) Original source Semiconductors are the foundation of all modern electronics. Now, researchers have developed a new method where organic semiconductors can become more conductive with the help of air as a dopant. The study is a significant step towards future cheap and sustainable organic semiconductors.
Published Promising new development in solar cell technology
(via sciencedaily.com) Original source Researchers who contributed to the development of record-breaking solar cells a few years ago, expanded their invention. The self-assembled monolayers can now be applied not only in inverted but also in regular structure perovskite solar cells.
Published Eco-friendly and affordable battery for low-income countries
(via sciencedaily.com) Original source A battery made from zinc and lignin that can be used over 8000 times. This has been developed with a vision to provide a cheap and sustainable battery solution for countries where access to electricity is limited.
Published How to make ubiquitous plastics biodegradable
(via sciencedaily.com) Original source Polystyrene is made from styrene building blocks and is the most widely used plastic in terms of volume, for example in packaging. Unlike PET, which can now be produced and recycled using biotechnological methods, the production of polystyrene has so far been a purely chemical process. The plastic can't be broken down by biotechnological means, either. Researchers are looking for ways to rectify this: An international team decoded a bacterial enzyme that plays a key role in styrene degradation. This paves the way for biotechnological application.
Published New 'forever chemical' cleanup strategy discovered
(via sciencedaily.com) Original source A method has been discovered to treat water heavily contaminated with unhealthful forever chemicals, known by chemists as PFAS or poly- and per-fluoroalkyl substances. It involves treating heavily contaminated water with ultraviolet (UV) light, sulfite, and a process called electrochemical oxidation. It breaks up strong fluorine-to-carbon bonds in the PFAS compounds and other concentrated organic compounds in heavily polluted water. The reaction also occurs at room temperature without a need for additional heat or high pressure. This method is expected to be useful in cleanups of PFAS pollution from decades of fire suppressant foam use at military facilities.
Published 2D all-organic perovskites: potential use in 2D electronics
(via sciencedaily.com) Original source Perovskites are among the most researched topics in materials science. Recently, a research team has solved an age-old challenge to synthesize all-organic two-dimensional perovskites, extending the field into the exciting realm of 2D materials. This breakthrough opens up a new field of 2D all-organic perovskites, which holds promise for both fundamental science and potential applications.
Published Getting dirty to clean up the chemical industry's environmental impact
(via sciencedaily.com) Original source The global chemical industry is a major fossil fuel consumer and climate change contributor; however, new research has identified how the sector could clean up its green credentials by getting dirty.
Published An epigenome editing toolkit to dissect the mechanisms of gene regulation
(via sciencedaily.com) Original source A recent study led to the development of a powerful epigenetic editing technology. The system unlocks the ability to precisely program chromatin modifications at any specific position in the genome, to understand their causal role in transcription regulation. This innovative approach will help to investigate the role of chromatin modifications in many biological processes, and to program desired gene activity responses, which may prove useful in disease settings.
Published Chemists produce new-to-nature enzyme containing boron
(via sciencedaily.com) Original source Chemists created an enzyme with boronic acid at its reactive center. This approach can produce more selective reactions with boron, and allows the use of directed evolution to improve its catalytic power.
Published Why is breaking down plant material for biofuels so slow?
(via sciencedaily.com) Original source Tracking individual enzymes during the breakdown of cellulose for biofuel production has revealed how several roadblocks slow this process when using plant material that might otherwise go to waste. The research may lead to new ways to improve the breakdown process and make the non-edible parts of plants and other plant waste, such as forestry residue, a more competitive source of biofuels.
Published 'Better than graphene' material development may improve implantable technology
(via sciencedaily.com) Original source Move over, graphene. There's a new, improved two-dimensional material in the lab. Borophene, the atomically thin version of boron first synthesized in 2015, is more conductive, thinner, lighter, stronger and more flexible than graphene, the 2D version of carbon. Now, researchers have made the material potentially more useful by imparting chirality -- or handedness -- on it, which could make for advanced sensors and implantable medical devices.
Published Caterbot? Robatapillar? It crawls with ease through loops and bends
(via sciencedaily.com) Original source Engineers created a catapillar-shaped robot that splits into segments and reassembles, hauls cargo, and crawls through twisting courses.
Published High-pressure spectroscopy: Why 3,000 bars are needed to take a comprehensive look at a protein
(via sciencedaily.com) Original source Why 3,000 bars are needed to take a comprehensive look at a protein: Researchers present a new high-pressure spectroscopy method to unravel the properties of proteins' native structures.
Published Did a magnetic field collapse trigger the emergence of animals?
(via sciencedaily.com) Original source Researchers uncovered compelling evidence that Earth's magnetic field was in a highly unusual state when the macroscopic animals of the Ediacaran Period -- 635 to 541 million years ago -- diversified and thrived. Their study raises the question of whether these fluctuations in Earth's ancient magnetic field led to shifts in oxygen levels that may have been crucial to the proliferation of life forms millions of years ago.