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Categories: Chemistry: Organic Chemistry, Offbeat: Paleontology and Archeology

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Carboxylic acid dianions (fumarate, maleate and succinate) play a role in coordination chemistry and to some extent also in the biochemistry of body cells. A team has now analyzed their electronic structures using RIXS in combination with DFT simulations. The results provide information not only on electronic structures but also on the relative stability of these molecules which can influence an industry's choice of carboxylate dianions, optimizing both the stability and geometry of coordination polymers.

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The rivers of Australia, which once flowed across its now dry interior, used to host a range of bizarre animals -- including a sleek predatory lobe-finned fish with large fangs and bony scales. The newly described fossil fish discovered in remote fossil fields west of Alice Springs has been named Harajicadectes zhumini by palaeontologists.

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Lithium-sulfur batteries have exceptional theoretical capacity and performance in combination with an element in abundant supply. But the intricate reaction mechanism, particularly during discharge, has been challenging to solve. Researchers have identified the key pathways to a complex sulfur reduction reaction that leads to energy loss and reduced battery life span. The study's findings establish the whole reaction network for the first time and offer insight into electrocatalyst design for improved batteries.

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In hydrogen fuel cells, electrolyte membranes frequently undergo deformation and develop cracks during operation. A research team has recently introduced a fatigue-resistant polymer electrolyte membrane for hydrogen fuel cells, employing an interpenetrating network of Nafion (a plastic electrolyte) and perfluoropolyether (a rubbery polymer). This innovation will not only improve fuel cell vehicles but also promises advancements in diverse technologies beyond transportation, spanning applications from drones to desalination filters and backup power sources.

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Engineers have developed an ultra-sensitive sensor made with graphene that can detect extraordinarily low concentrations of lead ions in water. The device achieves a record limit of detection of lead down to the femtomolar range, which is one million times more sensitive than previous technologies.

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A research team develops edge-to-edge assembly technique for 2D nanosheets.

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In the fossil record, trees typically are preserved with only their trunks. They don't usually include any leaves to show what their canopies and overall forms may have looked like. In a new study, researchers describe fossilized trees from New Brunswick, Canada with a surprising and unique three-dimensional crown shape.

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New research demonstrates how glycerol carbonate, a biosourced industrial additive, can be produced in record time using CO2 and a by-product of the cooking oil recycling industry. The process relies on a hybrid approach combining fundamental physical organic chemistry and applied flow process technology. Two industrial wastes are thus converted into glycerol carbonate, a biosourced rising star with high added-value.

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A team of researchers has achieved a major breakthrough in genome editing technology. They've developed a cutting-edge method that combines the power of designer-recombinases with programmable DNA-binding domains to create precise and adaptable genome editing tools.

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Nanoclusters (NCs) of transition metals like cobalt or nickel have widespread applications in drug delivery and water purification, with smaller NCs exhibiting improved functionalities. Downsizing NCs is, however, usually challenging. Now, scientists have demonstrated functional NC formation with atomic-scale precision. They successfully grew cobalt NCs on flat copper surfaces using molecular arrays as traps. This breakthrough paves the way for advancements like single-atom catalysis and spintronics miniaturization.

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The first analysis results now confirm that the grave in Tiarp is one of the oldest stone burial chambers in Sweden. The researchers noted that some parts of the people buried in the grave are missing, such as skulls and thigh bones, posing intriguing questions for archaeologists.

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Global warming continues to pose a threat to human society and the ecological systems, and carbon dioxide accounts for the largest proportion of the greenhouse gases that dominate climate warming. To combat climate change and move towards the goal of carbon neutrality, researchers have developed a durable, highly selective and energy-efficient carbon dioxide (CO2) electroreduction system that can convert CO2 into ethylene for industrial purposes to provide an effective solution for reducing CO2 emissions.

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A newly evolved enzyme could one day make silicone compounds biodegradable.

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DNA from ancient feces can offer archaeologists new clues about the life and health of Japanese people who lived thousands of years ago, according to a new study.

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Two research groups design a plasma (an ionized gas) reactor maintained by microwaves that makes it possible to decontaminate waters with high concentrations of dye.

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Microorganisms were the first forms of life on our planet. The clues are written in 3.5 billion-year-old rocks by geochemical and morphological traces, such as chemical compounds or structures that these organisms left behind. However, it is still not clear when and where life originated on Earth and when a diversity of species developed in these early microbial communities. Evidence is scarce and often disputed. Now, researchers have uncovered key findings about the earliest forms of life. In rock samples from South Africa, they found evidence dating to around 3.42 billion years ago of an unprecedentedly diverse carbon cycle involving various microorganisms. This research shows that complex microbial communities already existed in the ecosystems during the Palaeoarchaean period.

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Reactive oxygen species (ROS), though generally regarded as toxic byproducts of biological processes, serve many important functions in plants. However, the precise mechanism that plants use to regulate the production of ROS remains elusive. In a recent study, researchers clarified how an important ROS-generating enzyme is activated, revealing mechanisms likely conserved across all land plants. Their findings could pave the way for breakthroughs in agricultural and environmental remediation tools.

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Inspired by a 1725 fire engine that pumped water at larger distances and higher speeds than previously possible, authors analyzed the pressure chamber's Windkessel effect to capture the physics behind this widely used, enduring technology. They compared the initial state of the chamber, the rate at which bucket brigades could pour water in (volumetric inflow), the length of time pressure builds, and the effects on output flow rate. Next, the authors plan to examine the physiological Windkessel involved in the heart-aorta system.

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Researchers have developed a new, more environmentally friendly way to create conductive inks for use in organic electronics such as solar cells, artificial neurons, and soft sensors. The findings pave the way for future sustainable technology.

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Gliding winged-reptiles were amongst the ancient crocodile residents of the Mendip Hills in Somerset, England, researchers at the have revealed.