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Categories: Chemistry: Inorganic Chemistry, Chemistry: Thermodynamics

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Researchers have developed a material to remove urea from water and potentially convert it into hydrogen gas. By building these materials of nickel and cobalt atoms with carefully tailored electronic structures, the group has unlocked the potential to enable these transition metal oxides and hydroxides to selectively oxidize urea in an electrochemical reaction. The team's findings could help use urea in waste streams to efficiently produce hydrogen fuel through the electrolysis process, and could be used to sequester urea from water, maintaining the long-term sustainability of ecological systems, and revolutionizing the water-energy nexus.

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Researchers have synthesized the first 2D heavy fermion. The material, a layered intermetallic crystal composed of cerium, silicon, and iodine (CeSiI), has electrons that are 1000x heavier and is a new platform to explore quantum phenomena.

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A team has developed a new measurement method that, for the first time, accurately detects tiny temperature differences in the range of 100 microkelvin in the thermal Hall effect. Previously, these temperature differences could not be measured quantitatively due to thermal noise. Using the well-known terbium titanate as an example, the team demonstrated that the method delivers highly reliable results. The thermal Hall effect provides information about coherent multi-particle states in quantum materials, based on their interaction with lattice vibrations (phonons).

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Researchers have created a new way to detect 'forever chemical' pollution in water, via a luminescent sensor.

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Scientists have made an insight into superlubricity, where surfaces experience extremely low levels of friction. This could benefit future technologies by reducing energy lost to friction by moving parts.

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Chemists have mapped how proton-coupled electron transfers happen at the surface of an electrode. Their results could help researchers design more efficient fuel cells, batteries, or other energy technologies.

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'Soft robots,' medical devices and implants, and next-generation drug delivery methods could soon be guided with magnetism -- thanks to a metal-free magnetic gel developed by researchers. Carbon-based, magnetic molecules are chemically bonded to the molecular network of a gel, creating a flexible, long-lived magnet for soft robotics.

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Researchers have helped minimize the cost of an important class of chemical transformations: converting nitriles into primary amines. Their experimental protocol uses a cheap nickel catalyst instead of an expensive noble metal, is convenient to conduct, and works for a broad range of starting materials. This work is an important advance in sustainable chemistry that might help lower the cost of producing nylon and many other everyday products.

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Researchers have improved the efficiency of heat-to-electricity conversion in gallium arsenide semiconductor microstructures. By judicious spatial alignment of electrons within a two-dimensional electron gas system with multiple subbands, one can substantially enhance the power factor compared with previous iterations of analogous systems. This work is an important advance in modern thermoelectric technology and will benefit the global integration of the Internet of Things.

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The rules of statistical physics address the uncertainty about the state of a system that arises when that system interacts with its environment. But they've long missed another kind. In a new paper, researchers argue that uncertainty in the thermodynamic parameters themselves -- built into equations that govern the energetic behavior of the system -- may also influence the outcome of an experiment.

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Oxidative coupling of methane (OCM) is now one step closer to leaving the lab and entering the real world. Researchers have developed an OCM catalyst that exceeds 30 percent when it comes to the production of ethylene.

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Researchers have developed a unique catalyst that promises to revolutionize drug synthesis. It overcomes a common problem associated with the production of drugs from ketones. Using their catalyst, the researchers synthesized a key component of the commonly used incontinence drug oxybutynin. Their results underscore the potential of the catalyst to improve drug discovery and development.

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A combination of cooling technologies and techniques could reduce the temperature and energy needs of Riyadh, Saudi Arabia.

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In an experiment that could help the development of new spintronics devices with low energy consumption, researchers have used heat and magnetic fields to create transformations between spin textures -- magnetic vortices and antivortices known as skyrmions and antiskyrmions -- in a single crystal thin plate device. Importantly, they achieved this at room temperature.

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Researchers use light-reactive molecules to influence the acidity of a liquid and thereby capture of carbon dioxide. They have developed a special mixture of different solvents to ensure that the light-reactive molecules remain stable over a long period of time. Conventional carbon capture technologies are driven by temperature or pressure differences and require a lot of energy. This is no longer necessary with the new light-based process.

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Researchers are using crystallography to gain a better understanding of how proteins shapeshift. The knowledge can provide valuable insight into stopping and treating diseases.

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An insight into preventing perovskite semiconductors from degrading quickly could help enable solar cells estimated to be two to four times cheaper than today's thin-film solar panels.

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The world is filled with a myriad of sounds and vibrations -- the gentle tones of a piano drifting down the hall, the relaxing purr of a cat laying on your chest, the annoying hum of the office lights. Imagine being able to selectively tune out noises of a certain frequency. Researchers have now synthesized polymer networks with two distinct architectures and crosslink points capable of dynamically exchanging polymer strands to understand how the network connectivity and bond exchange mechanisms govern the overall damping behavior of the network. The incorporation of dynamic bonds into the polymer network demonstrates excellent damping of sound and vibrations at well-defined frequencies.

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In a new study, environmentally benign inverse-perovskites with high energy conversion efficiency have been reported by scientists with potential for practical application as thermoelectric materials (TEMs). Addressing the limitations typically faced with TEMs, such as insufficient energy conversion efficiency and environmental toxicity due to heavy elements, the new TEMs provide a suitable alternative to TEMs based on toxic elements with better thermoelectric properties than conventional eco-friendly TEMs.

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The water electrolysis method, a promising avenue for hydrogen production, relies on substantial freshwater consumption, thereby limiting the regions available with water resources required for water electrolysis . Researchers have developed highly durable electrodes without precious metals to enable direct hydrogen production from seawater.