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Categories: Chemistry: Inorganic Chemistry, Chemistry: Thermodynamics

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A newly developed molecular catalyst specifically tailored for mechanochemical reaction conditions enables high-efficiency transformations at near room temperature.

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Fluorescence is a fascinating natural phenomenon. It is based on the fact that certain materials can absorb light of a certain wavelength and then emit light of a different wavelength. Fluorescent materials play an important role in our everyday lives, for example in modern screens. Due to the high demand for applications, science is constantly striving to produce new and easily accessible molecules with high fluorescence efficiency.

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Researchers have developed and demonstrated an efficient and scalable technique that allows them to manufacture soft polymer materials in a dozen different structures, or 'morphologies,' from ribbons and nanoscale sheets to rods and branched particles. The technique allows users to finely tune the morphology of the materials at the micro- and nano-scale.

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A micro-architected material made from tiny knots proves tougher and more durable than unknotted counterparts.

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It's a tough job, but someone's got to do it. In this case, the 'job' is the breakdown of lignin, the structural biopolymer that gives stems, bark and branches their signature woodiness. One of the most abundant terrestrial polymers on Earth, lignin surrounds valuable plant fibers and other molecules that could be converted into biofuels and other commodity chemicals -- if we could only get past that rigid plant cell wall.

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A new biosensor offers scientists the first dynamic glimpses of manganese, an elusive metal ion that is essential for life.

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Scientists report the safe synthesis of hydrogen peroxide (H2O2), an oxidizing agent used in multiple industries including semiconductors, using a new rhodium-based catalyst. The catalyst is based on natural enzymes found in extremophile microorganisms, and the reaction meets three chemical ideals for H2O2 production: safe, use of a single vessel, and direct synthesis.

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Scientists have devised a way of fabricating a complex structure, previously found only in nature, to open up new ways for manipulating and controlling light.

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A further development in atomic force microscopy now makes it possible to simultaneously image the height profile of nanometer-fine structures as well as the electric current and the frictional force at solid-liquid interfaces. A team has succeeded in analyzing electrocatalytically active materials and gaining insights that will help optimize catalysts. The method is also potentially suitable for studying processes on battery electrodes, in photocatalysis or on active biomaterials.

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A new analysis supports the idea that photons colliding with heavy ions create a fluid of 'strongly interacting' particles. The results indicate that photon-heavy ion collisions can create a strongly interacting fluid that responds to the initial collision geometry and that these collisions can form a quark-gluon plasma. These findings will help guide future experiments at the planned Electron-Ion Collider.

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New study finds obstacles can trap rolling microparticles in fluid. Through simulations and experiments, physicists attribute the trapping effect to stagnant pockets of fluid, created by hydrodynamics. Random motions of the molecules within the fluid then 'kick' the microroller into a stagnant pocket, effectively trapping it.

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Researchers report the creation of a superconducting material at both a temperature and pressure low enough for practical applications. In a new paper, the researchers describe a nitrogen-doped lutetium hydride that exhibits superconductivity at 69 degrees Fahrenheit and 10 kilobars (145,000 pounds per square inch, or psi) of pressure.

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Researchers are using glow-in-the-dark materials to enhance and improve rapid COVID-19 home tests.

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Researchers have developed a new 'camera' that sees the local disorder in materials. Its key feature is a variable shutter speed: because the disordered atomic clusters are moving, when the team used a slow shutter, the dynamic disorder blurred out, but when they used a fast shutter, they could see it. The method uses neutrons to measure atomic positions with a shutter speed of around one picosecond, a trillion times faster than normal camera shutters.

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Development of all-solid-state batteries is crucial to achieve carbon neutrality. However, their high surface resistance causes these batteries to have low output, limiting their applications. To this end, researchers have employed a novel technique to investigate and modulate electric double layer dynamics at the solid/solid electrolyte interface. The researchers demonstrate unprecedented control of response speed by over two orders of magnitude, a major steppingstone towards realization of commercial all-solid-state batteries.

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The ability to distinguish two chiral enantiomers is an essential analytical capability for chemical industries including pharmaceutical companies, flavor/odor engineering and forensic science. A new wave of chiral optical methods have shown significant improvements in chiral sensitivity, compared to their predecessors, leading to potential analytical advantages for chiral discrimination.

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Researchers have developed a dual-purpose catalyst that purifies herbicide-tainted water while also producing hydrogen.

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Researchers have developed an inexpensive method for fabricating multi-walled carbon nanotubes (MWNTs) on a plastic film. The proposed method is simple, can be applied under ambient conditions, reuses MWNTs, and produces flexible wires of tunable resistances without requiring additional steps. It eliminates several drawbacks of current fabrication methods, making it useful for large-scale manufacturing of carbon wiring for flexible all-carbon devices.

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Researchers have developed a prototype for coral-reef-friendly sunscreens by using polymerization to create large molecules that still block UV radiation but are too big to penetrate our skin, coral, and algae. The polymeric UV filter was more effective at preventing sunburn in mice than existing sunscreens.

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Quantum effects can play an important role in chemical reactions. Physicists have now observed a quantum mechanical tunneling reaction in experiments. The observation can also be described exactly in theory. The scientists provide an important reference for this fundamental effect in chemistry. It is the slowest reaction with charged particles ever observed.