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Categories: Chemistry: Organic Chemistry, Chemistry: Thermodynamics
Published Chemists synthesize plant-derived molecules that hold potential as pharmaceuticals
(via sciencedaily.com) Original source Chemists developed a way to synthesize complex molecules called oligocyclotryptamines, originally found in plants, which could hold potential as antibiotics, analgesics, or anticancer drugs.
Published Halogen bonding for selective electrochemical separation, path to sustainable chemical processing demonstrated
(via sciencedaily.com) Original source A team has reported the first demonstration of selective electrochemical separation driven by halogen bonding. This was achieved by engineering a polymer that modulates the charge density on a halogen atom when electricity is applied. The polymer then attracts only certain targets -- such as halides, oxyanions, and even organic molecules -- from organic solutions, a feature that has important implications for pharmaceuticals and chemical synthesis processes.
Published Why carbon nanotubes fluoresce when they bind to certain molecules
(via sciencedaily.com) Original source Nanotubes can serve as biosensors. They change their fluorescence when they bind to certain molecules. Until now, it was unclear why. Researchers have gained new insights into the cause of the fluorescence.
Published New mechanism to cool buildings while saving energy
(via sciencedaily.com) Original source The movement of radiant heat -- felt when a hot surface warms our bodies and homes -- between buildings and their surroundings at ground level makes buildings with less skyward-facing surfaces harder to cool. A research team has demonstrated a new passive cooling technology that coats walls and windows with materials that can better manage heat movement between buildings and their surroundings at ground level. Findings could reduce the reliance on air conditioning and provide a more environmentally friendly, low-cost and scalable option for low-income communities with limited or no access to cooling and heating systems.
Published Pioneering plasma-catalytic process for CO2 hydrogenation to methanol under ambient conditions
(via sciencedaily.com) Original source A research team reports a pioneering plasma-catalytic process for the hydrogenation of CO2 to methanol at room temperature and atmospheric pressure. This breakthrough addresses the limitations of traditional thermal catalysis, which often requires high temperatures and pressures, resulting in low CO2 conversion and methanol yield.
Published New technology uses light to engrave erasable 3D images
(via sciencedaily.com) Original source Researchers invented a technique that uses a specialized light projector and a photosensitive chemical additive to imprint two- and three-dimensional images inside any polymer. The light-based engraving remains in the polymer until heat or light are applied, which erases the image and makes it ready to use again. The technology is intended for any situation where having detailed, precise visual data in a compact and easily customizable format could be critical, such as planning surgeries and developing architectural designs.
Published Effective new catalyst brings hope for cleaner energy, wastewater treatment, and green chemistry
(via sciencedaily.com) Original source A catalyst that significantly enhances ammonia conversion could improve wastewater treatment, green chemical and hydrogen production.
Published Chemists develop new sustainable reaction for creating unique molecular building blocks
(via sciencedaily.com) Original source Polymers can be thought of like trains: Just as a train is composed of multiple cars, polymers are made up of multiple monomers, and the couplings between the train cars are similar to the chemical bonds that link monomers together. While polymers have myriad applications -- from drug delivery to construction materials -- their structures and functions are restricted by the chemically similar monomer building blocks they're composed of. Now, chemists have developed a new reaction to create unique monomers in a controlled way. This reaction, which uses nickel as a catalyst, ultimately enables scientists to create polymers with unique and modifiable properties for drug delivery, energy storage, microelectronics and more.
Published Breakthrough in molecular control: New bioinspired double helix with switchable chirality
(via sciencedaily.com) Original source The control of artificial double-helical structures, which are essential for the development of high-order molecular systems, remains difficult. In a new study, researchers have developed novel double-helical monometallofoldamers that exhibit controllable helicity inversion and chiral information transfer, in response to external stimuli. These monometallofoldamers can lead to novel artificial supramolecular systems for molecular information transmission, amplification, replication, and other exciting applications in various fields of technology.
Published Forever chemical pollution can now be tracked
(via sciencedaily.com) Original source Researchers developed a way to fingerprint organofluorine compounds -- sometimes called 'forever chemicals' --which could help authorities trace them to their source when they end up in aquifers, waterways or soil.
Published Stacking molecules like plates improves organic solar device performance
(via sciencedaily.com) Original source Researchers found that how well light-converting molecules stack together in a solid is important for how well they convert light into electric current. A rigid molecule that stacked well showed excellent electricity generation in an organic solar cell and photocatalyst, easily outperforming a similar flexible molecule that did not stack well. This new way of improving the design of molecules could be used to pioneer the next generation of light-converting devices.
Published Researchers solve long-standing challenge for piezoelectric materials
(via sciencedaily.com) Original source Heat and pressure can deteriorate the properties of piezoelectric materials that make state-of-the-art ultrasound and sonar technologies possible -- and fixing that damage has historically required disassembling devices and exposing the materials to even higher temperatures. Now researchers have developed a technique to restore those properties at room temperature, making it easier to repair these devices -- and paving the way for new ultrasound technologies.
Published Heating for fusion: Why toast plasma when you can microwave it!
(via sciencedaily.com) Original source Can plasma be sufficiently heated inside a tokamak using only microwaves? New research suggests it can! Eliminating the central ohmic heating coil normally used in tokamaks will free up much-needed space for a more compact, efficient spherical tokamak.
Published Engineers develop general, high-speed technology to model, explain catalytic reactions
(via sciencedaily.com) Original source A research team developed artificial intelligence technology that could find ways to improve researchers' understanding of the chemical reactions involved in ammonia production and other complex chemical reactions.
Published Revolutionary loop heat pipe transports 10 kW of waste heat -- No electricity required
(via sciencedaily.com) Original source Researchers have unveiled a new loop heat pipe capable of transporting up to 10 kW of heat without using electric power. The loop heat pipe's design aims to contribute to energy savings and carbon neutrality in various fields, including waste heat recovery, solar heat utilization, electric vehicle thermal management, and data center cooling.
Published The next generation of RNA chips
(via sciencedaily.com) Original source An international research team has succeeded in developing a new version of RNA building blocks with higher chemical reactivity and photosensitivity. This can significantly reduce the production time of RNA chips used in biotechnological and medical research. The chemical synthesis of these chips is now twice as fast and seven times more efficient.
Published Unraveling a key junction underlying muscle contraction
(via sciencedaily.com) Original source Using powerful new visualization technologies, researchers have captured the first 3-D images of the structure of a key muscle receptor, providing new insights on how muscles develop across the animal kingdom and setting the stage for possible future treatments for muscular disorders.
Published Mucus-based bio-ink could be used to print and grow lung tissue
(via sciencedaily.com) Original source Lung diseases kill millions of people around the world each year. Treatment options are limited, and animal models for studying these illnesses and experimental medications are inadequate. Now, researchers describe their success in creating a mucus-based bioink for 3D printing lung tissue. This advance could one day help study and treat chronic lung conditions.
Published Injury dressings in first-aid kits provide a new technique to reveal shark species after bite incidents
(via sciencedaily.com) Original source Scientists have revealed that injury dressings found in first-aid kits can reliably be used to identify shark species involved in bite incidents by deploying medical gauze to gather DNA samples from aquatic equipment, such as surfboards.
Published Precise genetics: New CRISPR method enables efficient DNA modification
(via sciencedaily.com) Original source A research group has developed a new method that further improves the existing CRISPR/Cas technologies: it allows a more precise and seamless introduction of tags into proteins at the gene level. This technology could significantly improve research on proteins in living organisms and opens up new possibilities for medical research.