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Categories: Chemistry: General, Energy: Alternative Fuels

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In the atmosphere, gaseous sulfuric acid can form particles that influence the physical properties of clouds. Thus, the formation of sulfuric acid in the gas phase directly affects the radiative forcing and Earth's climate. In addition to the known formation from sulfur dioxide, researchers have now been able to demonstrate through experiments that there is another formation pathway that has been speculated about for decades. Sulfuric acid in the atmosphere can also be formed directly by the oxidation of organic sulfur compounds. This new production pathway can be responsible for up to half of the gaseous sulfuric acid formation over the oceans and is thus of high importance for climate projections -- especially over the oceans of the Southern Hemisphere.

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Molecular photoswitches that can both convert and store energy could be used to make solar energy harvesting more efficient. A team of researchers has used a quantum computing method to find a particularly efficient molecular structure for this purpose. Their procedure was based on a dataset of more than 400,000 molecules, which they screened to find the optimum molecular structure for solar energy storage materials.

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Researchers have developed a miniature battery that could be used to power tiny devices integrated into human tissues. The design uses an ionic gradient across a chain of droplets -- inspired by how electric eels generate electricity. The device was able to regulate the biological activity of human neurons. This could open the way to the development of tiny bio-integrated devices, with a range of applications in biology and medicine.

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Iron--sulfur (Fe--S) proteins, essential to all life forms, are difficult to synthesise due to the complicated molecular machinery involved and sensitivity of Fe--S clusters to oxygen. In a new study, a team of researchers devised an innovative protocol for synthesising mature Fe--S proteins, by bringing together a recombinant sulfur assimilation (SUF) system and an oxygen-scavenging system, thereby, paving the way for new technologies and a better understanding of the evolution of life.

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An organometallic capsule that can reversibly assemble and disassemble in response to chemical stimuli was recently developed by chemists. Comprising ferrocene-based bent amphiphiles, this new capsule can act as a host for various types of guest molecules, such as electron acceptors and dyes. Thanks to the controllable release of its cargo, the capsule would find applications in catalysis, medicine, and biotechnology.

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Methylcyclohexane is very promising as a hydrogen carrier that can safely and efficiently transport and store hydrogen. However, the dehydrogenation process using catalysts has issues due to its durability and large energy loss. Recently, researchers have succeeded in using solid oxide fuel cells to generate electricity directly from methylcyclohexane and recover toluene for reuse. This research is expected to not only reduce energy requirements but also explore new chemical synthesis by fuel cells.

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Could blending of crushed rock with arable soil lower global temperatures? Researchers study global warming events from 40 and 56 million years ago to find answers.

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A team of researchers is designing novel systems to capture water vapor in the air and turn it into liquid. They have developed sponges or membranes with a large surface area that continually capture moisture from their surrounding environment.

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Mathematical modeling can show how to safely blend hydrogen with natural gas for transport in existing pipeline systems. A secure and reliable transition to hydrogen is one of the proposed solutions for the shift to a net-zero-carbon economy.

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In the ongoing quest for more efficient solar cells, the most current published record for tandem perovskite solar cells is 32.5 percent. In a new paper, researchers report on the improvements in silicon-perovskite tandem cells that have made this possible.

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The world needs greener ways to make chemicals. In a new study, researchers demonstrate one potential path toward this goal by adapting hydrogen fuel cell technologies.

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In an experiment on how turbulent boundary layers respond to acceleration in the flow around them, aerospace engineers at the observed an unexpected internal boundary layer.

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A new analysis reveals that soft technology, the processes to design and deploy a solar energy system, contributed far less to the total cost declines of solar installations than previously estimated. Their quantitative model shows that driving down solar energy costs in the future will likely require either improving soft technology or reducing system dependencies on soft technology features.

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Expensive noble metals often play a vital role in illuminating screens or converting solar energy into fuels. Now, chemists have succeeded in replacing these rare elements with a significantly cheaper metal. In terms of their properties, the new materials are very similar to those used in the past.

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Gold (Au)-based electrocatalysts used for hydrogen production via water electrolysis exhibit high chemical stability but low hydrogen evolution reaction (HER) activity. Alloying them with nickel (Ni) can improve their HER activity. A recent study investigated the HER activity and surface properties of AuNi alloy prepared on single crystal Au surfaces, revealing the atomic structural changes and surface sites responsible for enhanced HER activity of AuNi/Au catalyst during electrolysis.

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A research team recently developed a stable artificial photocatalytic system that is more efficient than natural photosynthesis. The new system mimics a natural chloroplast to convert carbon dioxide in water into methane, a valuable fuel, very efficiently using light. This is a promising discovery, which could contribute to the goal of carbon neutrality.

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Earth is rapidly warming and scientists are developing a variety of approaches to reduce the effects of climate change. An astronomer has proposed a novel approach -- a solar shield to reduce the amount of sunlight hitting Earth, combined with a tethered, captured asteroid as a counterweight. Engineering studies using this approach could start now to create a workable design that could mitigate climate change within decades.

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Researchers are making progress on the design of a solar battery made from an abundant, non-toxic and easily synthesized material composed of 2D carbon nitride.

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Heat load mitigation is critical to extending the lifetime of future fusion device. Researchers have found a way to explain the rotational temperatures measured in three different experimental fusion devices in Japan and the United States. Their model evaluates the surface interactions and electron-proton collisions of hydrogen molecules.

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Chemists have demonstrated that water remediation can be powered in part -- and perhaps even exclusively -- by renewable energy sources.