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Categories: Chemistry: General, Energy: Batteries

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Perovskite solar cells are considered the strongest contender to replace silicon solar cells. While they achieve high power conversion energy, they also suffer from lead leakage and perovskite degradation due to moisture. Now scientists leverage the technique of interfacial passivation, where lead ions are bound by crown ether B18C6, obtaining 21.7% power conversion energy. The crown ether also resists degradation due to moisture for 300 hours at room temperature and 85% humidity.

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Recycling facilities collect glass and mercury from thrown away fluorescent bulbs, but discarded lighting could also supply rare-earth metals for reuse. The 17 metals referred to as rare earths aren't all widely available and aren't easily extracted with existing recycling methods. Now, researchers have found a simpler way to collect slightly magnetic particles that contain rare-earth metals from spent fluorescent bulbs.

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Chemists fill a major gap in origin-of-life theories.

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Researchers have developed a microporous covalent organic framework with dense donor-acceptor lattices and engineered linkages for the efficient and clean production of hydrogen peroxide through the photosynthesis process with water and air.

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Molecules that are induced by light to rotate bulky groups around central bonds could be developed into photo-activated bioactive systems, molecular switches, and more.

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Biomedical researchers have developed a new, less expensive way to detect nuclease digestion -- one of the critical steps in many nucleic acid sensing applications, such as those used to identify COVID-19 and other infectious diseases.

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In a new study, a team sterilized a hydroponic nutrient solution using low-temperature plasma generated from electricity and the oxygen in the atmosphere. This new sterilization technique may allow farmers to grow crops without the use of chemical pesticides, representing an important advance in agricultural technology for sustainable crop production.

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A research team has developed a new technique to image grain boundaries obstructing lithium-ion migration in solid-state batteries -- a promising type of next-generation battery.

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Researchers have developed a 'self-driving' lab that uses artificial intelligence (AI) and automated systems to provide in-depth analyses of catalytic reactions used in chemical research and manufacturing. The new tool, called Fast-Cat, can provide more information in five days than is possible in six months of conventional testing.

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Black carbon is up to 25 times more hazardous to human health than other airborne particles of a similar size. Standard sensors are expensive and burdensome, resulting in sparse coverage in regions infamous for poor air quality, such as the greater Salt Lake City area. A University of Utah-led study found that a portable, more affordable sensor recorded black carbon concentrations as accurately as the most widely used instrument for monitoring black carbon in real time. The portable sensor could help expand an accurate observation network to establish disease risk and create effective public health policies.

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Scientists have decoded the electronic structure of water, opening up new perspectives for technological and environmental applications.

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Researchers have been able to directly visualize the neutral products of the mutual neutralization of hydronium and hydroxide, and report three different product channels: two channels were attributed to a predominant electron-transfer mechanism, and a smaller channel was associated with proton transfer. The two-beam collision experiment is an important step toward understanding the quantum dynamics of this fundamental reaction.

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A collaborative research team develops an absorbent multifunctional nanofiber adhesive hemostat based on a protein biomaterial.

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Researchers are revisiting old building practices -- the use of by-products and cast-offs -- as a way to improve building materials and sustainability of the trade. A technique known as rammed earth construction uses materials that are alternatives to cement and are often more readily available in the environment. One such alternative is wood fly ash, a by-product of pulp mills and coal-fired power plants.

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Nearly 30 years ago, scientists discovered a unique class of anticancer molecules in a family of bryozoans, a phylum of marine invertebrates found in tropical waters. The chemical structures of these molecules, which consist of a dense, highly complex knot of oxidized rings and nitrogen atoms, has attracted the interest of organic chemists worldwide, who aimed to recreate these structures from scratch in the laboratory. However, despite considerable effort, it has remained an elusive task. Until now, that is. A team of chemists has succeeded in synthesizing eight of the compounds for the first time using an approach that combines inventive chemical strategy with the latest technology in small molecule structure determination.

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Whether ultramarine, cerulean, Egyptian or cobalt, blue pigments have colored artworks for centuries. Now, seemingly out of the blue, scientists have discovered a new blue pigment that uses less cobalt but still maintains a brilliant shine. Though something like this might only happen once in a blue moon, the cobalt-doped barium aluminosilicate colorant withstands the high temperatures found in a kiln and provides a bright color to glazed tiles.

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Graphene is an enormously promising material. It consists of a single layer of carbon atoms arranged in a honeycomb pattern and has extraordinary properties: exceptional mechanical strength, flexibility, transparency and outstanding thermal and electrical conductivity. If the already two-dimensional material is spatially restricted even more, for example into a narrow ribbon, controllable quantum effects can be created. This could enable a wide range of applications, from vehicle construction and energy storage to quantum computing.

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A global team of researchers has invented recyclable 'water batteries' that won't catch fire or explode. The team use water to replace organic electrolytes -- which enable the flow of electric current between the positive and negative terminals -- meaning their batteries can't start a fire or blow up -- unlike their lithium-ion counterparts.

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Reduce, reuse, recycle, and repurpose: These are all ways we can live more sustainably. One tricky aspect of recycling, though, is that sometimes the recycling process is chemically intensive, and this is the case for recycling one of the world's most abundant materials -- chitin. Researchers have tackled this problem and found a way to sustainably recover chitin from seafood waste.

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A research team has unveiled a novel ligand exchange technique that enables the synthesis of organic cation-based perovskite quantum dots (PQDs), ensuring exceptional stability while suppressing internal defects in the photoactive layer of solar cells.