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Categories: Chemistry: Inorganic Chemistry, Energy: Nuclear
Published Scientists unveil fire-safe fuel
(via sciencedaily.com) Original source Chemical engineers have designed a fuel that ignites only with the application of electric current. Since it doesn't react to flames and cannot start accidental fires during storage or transport, it is a 'safe' liquid fuel.
Published Capturing CO2 with electricity: A microbial enzyme inspires electrochemistry
(via sciencedaily.com) Original source Humanity continuously emits greenhouse gases and thereby worsens global warming. Increasing research efforts go into developing strategies to convert these gases, such as carbon dioxide (CO2), into valuable products. CO2 accumulates dramatically over the years and is chemically very stable, thus challenging to transform. Yet, for billions of years, some microbes have actively captured CO2 using highly efficient enzymes. Scientists have now isolated one of these enzymes. When the enzyme was electronically branched on an electrode, they observed the conversion of CO2 to formate with perfect efficiency. This phenomenon will inspire new CO2-fixation systems because of its remarkable directionality and rates.
Published Accelerating sustainable semiconductors with 'multielement ink'
(via sciencedaily.com) Original source Scientists have demonstrated 'multielement ink' -- the first 'high-entropy' semiconductor that can be processed at low-temperature or room temperature. The new material could enable cost-effective and energy-efficient semiconductor manufacturing.
Published Milestone for novel atomic clock
(via sciencedaily.com) Original source An international research team has taken a decisive step toward a new generation of atomic clocks. The researchers have created a much more precise pulse generator based on the element scandium, which enables an accuracy of one second in 300 billion years -- that is about a thousand times more precise than the current standard atomic clock based on caesium.
Published Separating molecules requires lots of energy. This new, heat-resistant membrane could change that
(via sciencedaily.com) Original source A research team has created a new, heat-resistant membrane that can withstand harsh environments -- high temperatures, high pressure and complex chemical solvents -- associated with industrial separation processes. It could eventually be used as a less energy intensive alternative to distillation and other industrial processes that separate molecules that ultimately serve as ingredients in medicine, chemicals and other products.
Published How organic solar cells could become significantly more efficient
(via sciencedaily.com) Original source The sun sends enormous amounts of energy to the earth. Nevertheless, some of it is lost in solar cells. This is an obstacle in the use of organic solar cells, especially for those viable in innovative applications. A key factor in increasing their performance: Improved transport of the solar energy stored within the material. Now a research group has shown that certain organic dyes can help build virtual highways for the energy.
Published Crystallization as the driving force
(via sciencedaily.com) Scientists have successfully developed nanomaterials using a so-called bottom-up approach. They exploit the fact that crystals often grow in a specific direction during crystallization. These resulting nanostructures, which appear as 'worm-like and decorated rods,' could be used in various technological applications.
Published Copper-based catalysts efficiently turn carbon dioxide into methane
(via sciencedaily.com) Copper-based catalysts developed by materials scientists help speed up the rate of carbon dioxide-to-methane conversion.
Published Unraveling the mysteries of glassy liquids
(via sciencedaily.com) Original source A collaborative study builds a novel theory to explain the puzzling collective behavior of glass-forming liquids at low temperatures, a phenomenon with widespread implications in fields like material science and biology.
Published Scaling up the power of nanotechnology
(via sciencedaily.com) Researchers created a proof of concept of a nanocapsule -- a microscopic container -- capable of delivering a specific 'payload' to a targeted location. While beyond the scope of this study, the discovery could one day impact how drugs, nutrients and other types of chemical compounds are delivered within humans or plants.
Published New recycling method fights plastic waste
(via sciencedaily.com) Almost 80% of plastic in the waste stream ends up in landfills or accumulates in the environment. Scientists have now developed a technology that converts a conventionally unrecyclable mixture of plastic waste into useful chemicals, presenting a new strategy in the toolkit to combat global plastic waste.
Published One-atom-thick ribbons could improve batteries, solar cells and sensors
(via sciencedaily.com) Researchers created nanoribbons made of phosphorus and tiny amounts of arsenic, which they found were able to conduct electricity at temperatures above -140 degrees Celsius, while retaining the highly useful properties of the phosphorus-only ribbons.
Published Making contact: Researchers wire up individual graphene nanoribbons
(via sciencedaily.com) Researchers have developed a method of 'wiring up' graphene nanoribbons (GNRs), a class of one-dimensional materials that are of interest in the scaling of microelectronic devices. Using a direct-write scanning tunneling microscopy (STM) based process, the nanometer-scale metal contacts were fabricated on individual GNRs and could control the electronic character of the GNRs. The researchers say that this is the first demonstration of making metal contacts to specific GNRs with certainty and that those contacts induce device functionality needed for transistor function.
Published Researchers make sand that flows uphill
(via sciencedaily.com) Engineering researchers have discovered that sand can actually flow uphill. A corresponding video shows what happens when torque and an attractive force is applied to each grain -- the grains flow uphill, up walls, and up and down stairs.
Published Novel organic light-emitting diode with ultralow turn-on voltage for blue emission
(via sciencedaily.com) An upconversion organic light-emitting diode (OLED) based on a typical blue-fluorescence emitter achieves emission at an ultralow turn-on voltage of 1.47 V. The technology circumvents the traditional high voltage requirement for blue OLEDs, leading to potential advancements in commercial smartphone and large screen displays.
Published Imaging the smallest atoms provides insights into an enzyme's unusual biochemistry
(via sciencedaily.com) A team has used neutron crystallography to image all of the atoms in a radical intermediate of a copper amine oxidase enzyme. They disclosed previously unknown details, such as precise conformational changes, that help to explain the enzyme's biochemistry. This work might help researchers engineer enzymes that facilitate unusual chemistry or are highly efficient at room temperature that are useful in chemical industry.
Published New recipes for origin of life may point way to distant, inhabited planets
(via sciencedaily.com) Original source Life on a faraway planet -- if it's out there -- might not look anything like life on Earth. But there are only so many chemical ingredients in the universe's pantry, and only so many ways to mix them. Scientists have now exploited those limitations to write a cookbook of hundreds of chemical recipes with the potential to give rise to life. Their ingredient list could focus the search for life elsewhere in the universe by pointing out the most likely conditions -- planetary versions of mixing techniques, oven temperatures and baking times -- for the recipes to come together.
Published Precisely arranging nanoparticles
(via sciencedaily.com) In the incredibly small world of molecules, the elementary building blocks -- the atoms -- join together in a very regular pattern. In contrast, in the macroscopic world with its larger particles, there is much greater disorder when particles connect. A research team has now succeeded in achieving the same precise arrangement of atoms shown in molecules, but using nanometer-sized particles, known as 'plasmonic molecules' -- combinations of nanoscale metallic structures that have unique properties.
Published Novel ligands for transition-metal catalysis of photoreactions
(via sciencedaily.com) Transition metals exchange electrons with supporting ligands to form complexes that facilitate reaction catalysis in several industries, like pharmaceutical production. Both the metal center and the ligand moiety have pivotal roles in enabling catalysis. While numerous transition metal-catalyzed photoreactions have been developed, only a few new ligands have been reported. Researchers from Chiba University have now developed novel ligands to create transition metal complexes, defining new reaction capabilities.
Published Engineers grow full wafers of high-performing 2D semiconductor that integrates with state-of-the-art chips
(via sciencedaily.com) Researchers have grown a high-performing 2D semiconductor to a full-size, industrial-scale wafer. In addition, the semiconductor material, indium selenide (InSe), can be deposited at temperatures low enough to integrate with a silicon chip.