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Categories: Chemistry: Organic Chemistry, Energy: Fossil Fuels

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Organosulfur skeletons are crucial in many fields, including pharmaceuticals and electronics. Synthesizing organosulfur skeletons requires o-bromobenzenethiols. However, conventional methods face challenges due to quick oxidation and formation of highly reactive intermediates. Researchers have now developed a new method for synthesizing o-bromobenzenethiols from aryne intermediates via bromothiolation. This method can pave the way for the synthesis of new organosulfur compounds with applications in diverse fields.

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Researchers have used computational design methods to develop non-metal organic porous framework materials, with potential applications in areas such as catalysis, water capture or hydrogen storage.

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Scientists have created a new type of chemosensor (demonstrated for lactic acid sensing) which functions with electricity but without the need for reference electrodes or battery power.

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Use of the greenhouse gas CO2 as a chemical raw material would not only reduce emissions, but also the consumption of fossil feedstocks. A novel metal-free organic framework could make it possible to electrocatalytically produce ethylene, a primary chemical raw material, from CO2. Nitrogen atoms with a particular electron configuration play a critical role for the catalyst.

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By converting their data into sounds, scientists discovered how hydrogen bonds contribute to the lightning-fast gyrations that transform a string of amino acids into a functional, folded protein. Their report offers an unprecedented view of the sequence of hydrogen-bonding events that occur when a protein morphs from an unfolded to a folded state.

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A team of geologists analyzed 3,500 samples taken in and around coal mines in Utah and Colorado. Their findings open the possibility that these mines could see a secondary resource stream in the form of rare earth metals used in renewable energy and numerous other high-tech applications.

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Scientists have taken a step closer to replicating nature's processes of self-assembly. The study describes the synthetic construction of a tiny, self-assembled crystal known as a 'pyrochlore,' which bears unique optical properties. The advance provides a steppingstone to the eventual construction of sophisticated, self-assembling devices at the nanoscale -- roughly the size of a single virus.

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Investigating ways to create high-performance steel, a research team used theoretical calculations on 120 combinations of 12 alloy elements, such as aluminum and titanium, with carbon and nitrogen, while also systematically clarifying the bonding mechanism.

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Using DNA origami, researchers have built a diamond lattice with a periodicity of hundreds of nanometers -- a new approach for manufacturing semiconductors for visible light.

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C-H activation-based method should speed drug molecule design and diversification.

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A team of chemists has achieved a significant breakthrough in the field of chemical synthesis, developing a novel method for manipulating carbon-hydrogen bonds. This groundbreaking discovery provides new insights into the molecular interactions of positively charged carbon atoms. By selectively targeting a specific C--H bond, they open doors to synthetic pathways that were previously closed -- with potential applications in medicine.

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Vanilla, the most widely used flavoring compound in confectionaries and cosmetics, gets its sweet flavor and aroma from the chemical compound -- 'vanillin'. However, the large-scale production of natural vanillin is impeded by the lack of microbial processes and enzymes which can commercially generate vanillin. Now, researchers have genetically engineered a novel enzyme which can convert ferulic acid from plant waste into vanillin in a one-step sustainable process.

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The optimal design of a novel zeolite catalyst enables tandem reaction that turns greenhouse gases into value-added chemicals, report scientists. By tuning the separation between different active sites on the catalyst, they achieved the stepwise conversion of methane into methanol and then to hydrocarbons at mild conditions. These findings will help reduce energy costs and greenhouse gas emissions across various industrial fields.

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By studying how bubbles form in a drop of biodiesel, researchers can help future engines get the most energy out of the fuel.

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Semiconductors are the foundation of all modern electronics. Now, researchers have developed a new method where organic semiconductors can become more conductive with the help of air as a dopant. The study is a significant step towards future cheap and sustainable organic semiconductors.

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Researchers who contributed to the development of record-breaking solar cells a few years ago, expanded their invention. The self-assembled monolayers can now be applied not only in inverted but also in regular structure perovskite solar cells.

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A battery made from zinc and lignin that can be used over 8000 times. This has been developed with a vision to provide a cheap and sustainable battery solution for countries where access to electricity is limited.

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Polystyrene is made from styrene building blocks and is the most widely used plastic in terms of volume, for example in packaging. Unlike PET, which can now be produced and recycled using biotechnological methods, the production of polystyrene has so far been a purely chemical process. The plastic can't be broken down by biotechnological means, either. Researchers are looking for ways to rectify this: An international team decoded a bacterial enzyme that plays a key role in styrene degradation. This paves the way for biotechnological application.

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Coal phase-out is necessary to solve climate change, but can have negative impacts on workers and local communities dependent on coal for their livelihoods. Researchers have studied government plans for coal phase-out around the world and discovered that more than half of such plans include monetary compensation to affected parties. This planned compensation globally amounts to USD 200 billion, but it excludes China and India, the two largest users of coal that currently do not have phase-out plans. The study shows that if China and India decide to phase out coal as fast as needed to reach the Paris climate targets and pay similar compensation, it would cost upwards of USD 2 trillion.

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A method has been discovered to treat water heavily contaminated with unhealthful forever chemicals, known by chemists as PFAS or poly- and per-fluoroalkyl substances. It involves treating heavily contaminated water with ultraviolet (UV) light, sulfite, and a process called electrochemical oxidation. It breaks up strong fluorine-to-carbon bonds in the PFAS compounds and other concentrated organic compounds in heavily polluted water. The reaction also occurs at room temperature without a need for additional heat or high pressure. This method is expected to be useful in cleanups of PFAS pollution from decades of fire suppressant foam use at military facilities.