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Categories: Chemistry: Organic Chemistry, Energy: Fossil Fuels
Published Not only in information technology: Restart also works in chemical simulations
(via sciencedaily.com) Original source Scientists have discovered that a known practice in information technology can also be applied to chemistry. Researchers found that to enhance the sampling in chemical simulations, all you need to do is stop and restart.
Published Key advance for capturing carbon from the air
(via sciencedaily.com) Original source A chemical element so visually striking that it was named for a goddess shows a 'Goldilocks' level of reactivity -- neither too much nor too little -- that makes it a strong candidate as a carbon scrubbing tool.
Published Towards A Better Way of Releasing Hydrogen Stored in Hydrogen Boride Sheets
(via sciencedaily.com) Original source Hydrogen stored in hydrogen boride sheets can be efficiently released electrochemically, report scientists. Through a series of experiments, they demonstrated that dispersing these sheets in an organic solvent and applying a small voltage is enough to release all the stored hydrogen efficiently. These findings suggest hydrogen boride sheets could soon become a safe and convenient way to store and transport hydrogen, which is a cleaner and more sustainable fuel.
Published Illuminating the invisible: Detecting proteins linked to diseases
(via sciencedaily.com) Original source Engineers have pioneered a new way to visualize the smallest protein clusters, skirting the physical limitations of light-powered microscopes and opening new avenues for detecting the proteins implicated in diseases like Alzheimer's and testing new treatments.
Published Greenhouse gas repurposed
(via sciencedaily.com) Original source Cutting-edge research converted waste carbon dioxide into a potential precursor for chemicals and carbon-free fuel.
Published Inexpensive, carbon-neutral biofuels are finally possible
(via sciencedaily.com) Original source When it comes to making fuel from plants, the first step has always been the hardest -- breaking down the plant matter. A new study finds that introducing a simple, renewable chemical to the pretreatment step can finally make next-generation biofuel production both cost-effective and carbon neutral.
Published BESSY II: Molecular orbitals determine stability
(via sciencedaily.com) Original source Carboxylic acid dianions (fumarate, maleate and succinate) play a role in coordination chemistry and to some extent also in the biochemistry of body cells. A team has now analyzed their electronic structures using RIXS in combination with DFT simulations. The results provide information not only on electronic structures but also on the relative stability of these molecules which can influence an industry's choice of carboxylate dianions, optimizing both the stability and geometry of coordination polymers.
Published Japan's electric vehicle transition by 2035 may be insufficient to combat the climate crisis, but there are solutions
(via sciencedaily.com) Original source Researchers report that Japan's policy of banning the sale of new gas vehicles by 2035 may be insufficient to reduce the country's CO2 emissions. The team's analysis showed that to effectively reach their climate goals, Japan must also implement policies that extend vehicle lifetime, implement more renewable energy into its energy sector, and decarbonize the manufacturing process of vehicles.
Published Chemists decipher reaction process that could improve lithium-sulfur batteries
(via sciencedaily.com) Original source Lithium-sulfur batteries have exceptional theoretical capacity and performance in combination with an element in abundant supply. But the intricate reaction mechanism, particularly during discharge, has been challenging to solve. Researchers have identified the key pathways to a complex sulfur reduction reaction that leads to energy loss and reduced battery life span. The study's findings establish the whole reaction network for the first time and offer insight into electrocatalyst design for improved batteries.
Published Improving fuel cell durability with fatigue-resistant membranes
(via sciencedaily.com) Original source In hydrogen fuel cells, electrolyte membranes frequently undergo deformation and develop cracks during operation. A research team has recently introduced a fatigue-resistant polymer electrolyte membrane for hydrogen fuel cells, employing an interpenetrating network of Nafion (a plastic electrolyte) and perfluoropolyether (a rubbery polymer). This innovation will not only improve fuel cell vehicles but also promises advancements in diverse technologies beyond transportation, spanning applications from drones to desalination filters and backup power sources.
Published Ammonia attracts the shipping industry, but researchers warn of its risks
(via sciencedaily.com) Original source Switching to ammonia as a marine fuel, with the goal of decarbonization, can instead create entirely new problems. This is shown in a study where researchers carried out life cycle analyses for batteries and for three electrofuels including ammonia. Eutrophication and acidification are some of the environmental problems that can be traced to the use of ammonia -- as well as emissions of laughing gas, which is a very potent greenhouse gas.
Published Ultra-sensitive lead detector could significantly improve water quality monitoring
(via sciencedaily.com) Original source Engineers have developed an ultra-sensitive sensor made with graphene that can detect extraordinarily low concentrations of lead ions in water. The device achieves a record limit of detection of lead down to the femtomolar range, which is one million times more sensitive than previous technologies.
Published Edge-to-edge assembly technique for 2D nanosheets
(via sciencedaily.com) Original source A research team develops edge-to-edge assembly technique for 2D nanosheets.
Published Intensifying the production of high-value compounds from industrial waste
(via sciencedaily.com) Original source New research demonstrates how glycerol carbonate, a biosourced industrial additive, can be produced in record time using CO2 and a by-product of the cooking oil recycling industry. The process relies on a hybrid approach combining fundamental physical organic chemistry and applied flow process technology. Two industrial wastes are thus converted into glycerol carbonate, a biosourced rising star with high added-value.
Published Groundbreaking genome editing tools unlock new possibilities for precision medicine
(via sciencedaily.com) Original source A team of researchers has achieved a major breakthrough in genome editing technology. They've developed a cutting-edge method that combines the power of designer-recombinases with programmable DNA-binding domains to create precise and adaptable genome editing tools.
Published Small yet mighty: Showcasing precision nanocluster formation with molecular traps
(via sciencedaily.com) Original source Nanoclusters (NCs) of transition metals like cobalt or nickel have widespread applications in drug delivery and water purification, with smaller NCs exhibiting improved functionalities. Downsizing NCs is, however, usually challenging. Now, scientists have demonstrated functional NC formation with atomic-scale precision. They successfully grew cobalt NCs on flat copper surfaces using molecular arrays as traps. This breakthrough paves the way for advancements like single-atom catalysis and spintronics miniaturization.
Published High-efficiency carbon dioxide electroreduction system reduces our carbon footprint and progressing carbon neutrality goals
(via sciencedaily.com) Original source Global warming continues to pose a threat to human society and the ecological systems, and carbon dioxide accounts for the largest proportion of the greenhouse gases that dominate climate warming. To combat climate change and move towards the goal of carbon neutrality, researchers have developed a durable, highly selective and energy-efficient carbon dioxide (CO2) electroreduction system that can convert CO2 into ethylene for industrial purposes to provide an effective solution for reducing CO2 emissions.
Published Teaching nature to break human-made chemical bonds
(via sciencedaily.com) Original source A newly evolved enzyme could one day make silicone compounds biodegradable.
Published A new design improves water decontamination via plasma jet
(via sciencedaily.com) Original source Two research groups design a plasma (an ionized gas) reactor maintained by microwaves that makes it possible to decontaminate waters with high concentrations of dye.
Published New study unveils how plants control the production of reactive oxygen species
(via sciencedaily.com) Original source Reactive oxygen species (ROS), though generally regarded as toxic byproducts of biological processes, serve many important functions in plants. However, the precise mechanism that plants use to regulate the production of ROS remains elusive. In a recent study, researchers clarified how an important ROS-generating enzyme is activated, revealing mechanisms likely conserved across all land plants. Their findings could pave the way for breakthroughs in agricultural and environmental remediation tools.