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Categories: Chemistry: Organic Chemistry, Energy: Fossil Fuels

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By controlling the arrangement of multiple inorganic and organic layers within crystals using a novel technique, researchers have shown they can control the energy levels of electrons and holes (positive charge carriers) within a class of materials called perovskites. This tuning influences the materials' optoelectronic properties and their ability to emit light of specific energies, demonstrated by their ability to function as a source of lasers.

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A lab is developing more accurate and powerful liquid biopsy technologies that take advantage of signals from RNA 'dark matter,' an understudied area of the genome.

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Researchers have been able to substantially improve photoclick chemistry. They were able to boost the reactivity of the photoclick compound in the popular PQ-ERA reaction through strategic molecular substitution. They now report a superb photoreaction quantum yield, high reaction rates and notable oxygen tolerance.

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In the atmosphere, gaseous sulfuric acid can form particles that influence the physical properties of clouds. Thus, the formation of sulfuric acid in the gas phase directly affects the radiative forcing and Earth's climate. In addition to the known formation from sulfur dioxide, researchers have now been able to demonstrate through experiments that there is another formation pathway that has been speculated about for decades. Sulfuric acid in the atmosphere can also be formed directly by the oxidation of organic sulfur compounds. This new production pathway can be responsible for up to half of the gaseous sulfuric acid formation over the oceans and is thus of high importance for climate projections -- especially over the oceans of the Southern Hemisphere.

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Molecular photoswitches that can both convert and store energy could be used to make solar energy harvesting more efficient. A team of researchers has used a quantum computing method to find a particularly efficient molecular structure for this purpose. Their procedure was based on a dataset of more than 400,000 molecules, which they screened to find the optimum molecular structure for solar energy storage materials.

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A scientist combines attention neural networks with graph neural networks to better understand and design proteins. The approach couples the strengths of geometric deep learning with those of language models to predict existing protein properties and envision new proteins that nature has not yet devised. The model turns numbers, descriptions, tasks, and other elements into symbols for neural networks to use.

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Iron--sulfur (Fe--S) proteins, essential to all life forms, are difficult to synthesise due to the complicated molecular machinery involved and sensitivity of Fe--S clusters to oxygen. In a new study, a team of researchers devised an innovative protocol for synthesising mature Fe--S proteins, by bringing together a recombinant sulfur assimilation (SUF) system and an oxygen-scavenging system, thereby, paving the way for new technologies and a better understanding of the evolution of life.

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An organometallic capsule that can reversibly assemble and disassemble in response to chemical stimuli was recently developed by chemists. Comprising ferrocene-based bent amphiphiles, this new capsule can act as a host for various types of guest molecules, such as electron acceptors and dyes. Thanks to the controllable release of its cargo, the capsule would find applications in catalysis, medicine, and biotechnology.

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Methylcyclohexane is very promising as a hydrogen carrier that can safely and efficiently transport and store hydrogen. However, the dehydrogenation process using catalysts has issues due to its durability and large energy loss. Recently, researchers have succeeded in using solid oxide fuel cells to generate electricity directly from methylcyclohexane and recover toluene for reuse. This research is expected to not only reduce energy requirements but also explore new chemical synthesis by fuel cells.

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Researchers have looked beyond biochemistry to publish groundbreaking work on the physics of fat droplets found inside many types of cells, revealing them to be a potential threat to a cell's nucleus.They have discovered fat-filled lipid droplets' surprising capability to indent and puncture the nucleus, the organelle which contains and regulates a cell's DNA. The stakes of their findings are high: a ruptured nucleus can lead to elevated DNA damage that is characteristic of many diseases, including cancer.

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Using a trapped-ion quantum computer, the research team witnessed the interference pattern of a single atom caused by a 'conical intersection'. Conical intersections are known throughout chemistry and are vital to rapid photo-chemical processes such as light harvesting in human vision or photosynthesis.

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Researchers have developed and demonstrated a new method for high-throughput single-cell sorting that uses stimulated Raman spectroscopy rather than the traditional approach of fluorescence-activated cell sorting. The new approach could offer a label-free, nondestructive way to sort cells for a variety of applications, including microbiology, cancer detection and cell therapy.

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Mathematical modeling can show how to safely blend hydrogen with natural gas for transport in existing pipeline systems. A secure and reliable transition to hydrogen is one of the proposed solutions for the shift to a net-zero-carbon economy.

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A team of chemists have developed a novel concept in which a mixture of molecules that behave like mirror images is converted to a single form. To this end, they use light as external energy source. The conversion is relevant e.g. for the preparation of drugs.

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In the form of DNA, nature shows how data can be stored in a space-saving and long-term manner. Bioinformatics specialists are developing DNA chips for computer technology. Researchers show how a combination of molecular biology, nanotechnology, novel polymers, electronics and automation, coupled with systematic development, could make DNA data storage useful for everyday use possible in a few years.

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Immunotherapies for cancer aim to induce the immune system to combat cancer cells more effectively. A research team has now described a new, modular strategy for T-cell-based immunotherapy that manages to work without complex genetic modifications. Modulation of cell-cell communications through an ingenious regulatory circuit using various small, specially folded DNA molecules (aptamers) causes cancer cells to directly activate their mortal enemies, T cells.

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Researchers have finally solved the long-standing puzzle of why graphene is so much more permeable to protons than expected by theory.

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If coal and natural gas power generation were 2% more efficient, then, every year, there could be 460 million fewer tons of carbon dioxide released and 2 trillion fewer gallons of water used. A recent innovation to the steam cycle used in fossil fuel power generation could achieve this.

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A research team enhanced hydrogen evolution catalyst through stepwise deposition.

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Which structures do complex proteins adopt in solution? Biophysicists answer this question using the example of ubiquitin dimers as well as a new combination of high-resolution NMR spectroscopy and sophisticated computer simulations.