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Categories: Chemistry: Organic Chemistry, Energy: Fossil Fuels
Published Scientists capture elusive chemical reaction using enhanced X-ray method
(via sciencedaily.com) Original source Researchers have captured one of the fastest movements of a molecule called ferricyanide for the first time by combining two ultrafast X-ray spectroscopy techniques. They think their approach could help map more complex chemical reactions like oxygen transportation in blood cells or hydrogen production using artificial photosynthesis.
Published Researchers use generative AI to design novel proteins
(via sciencedaily.com) Original source Researchers have developed an artificial intelligence system that can create proteins not found in nature using generative diffusion, the same technology behind popular image-creation platforms such as DALL-E and Midjourney.
Published Single-molecule valve: Breakthrough in nanoscale control
(via sciencedaily.com) Original source A research group has succeeded in regulating the flow of single molecules in solution by opening and closing the nanovalve mounted on the nanofluidic device by applying external pressure. The research group fabricated a device with a ribbon-like, thin, soft glass sheet on the top, and at the bottom a hard glass substrate having nanochannels and nanovalve seats. By applying external pressure to the soft glass sheet to open and close the valve, they succeeded in directly manipulating and controlling the flow of individual molecules in solution. They also observed an effect of fluorescence signal amplification when single fluorescent molecules are confined in the tiny nanospace inside the valve. The effect can be ascribed to the nanoconfinement, which suppresses the random motion of the molecules.
Published Upcycling method turns textile trash to functional coatings
(via sciencedaily.com) Original source In an effort to make textiles more sustainable, a new method allows researchers to break old clothing down chemically and reuse polyester compounds to create fire resistant, anti-bacterial or wrinkle-free coatings that could then be applied to clothes and fabrics.
Published Self-folding origami machines powered by chemical reaction
(via sciencedaily.com) Original source Scientists have harnessed chemical reactions to make microscale origami machines self-fold -- freeing them from the liquids in which they usually function, so they can operate in dry environments and at room temperature.
Published Previously unknown intercellular electricity may power biology
(via sciencedaily.com) Original source Researchers have discovered that the electrical fields and activity that exist through a cell's membrane also exist within and around another type of cellular structure called biological condensates. Like oil droplets floating in water, these structures exist because of differences in density. Their foundational discovery could change the way researchers think about biological chemistry. It could also provide a clue as to how the first life on Earth harnessed the energy needed to arise.
Published Pulling the plug on viral infections: CRISPR isn't just about cutting
(via sciencedaily.com) Original source CRISPR claimed scientific fame for its ability to quickly and accurately edit genes. But, at the core, CRISPR systems are immune systems that help bacteria protect themselves from viruses. A new study reveals a previously unrecognized player in one such system -- a membrane protein that enhances anti-viral defense. According to study authors, the finding upends the idea that CRISPR systems mount their defense only by degrading RNA and DNA in cells.
Published A transistor made of wood
(via sciencedaily.com) Original source Researchers have developed the first transistor made of wood. Their study paves the way for further development of wood-based electronics and control of electronic plants.
Published How spheres become worms
(via sciencedaily.com) Original source A previously unknown form of hydrogel formation has been elucidated: chemists found unusual interactions between polymers.
Published A simple paper test could offer early cancer diagnosis
(via sciencedaily.com) Original source Engineers designed a nanoparticle sensor that could enable early diagnosis of cancer with a simple urine test. The sensors, which can detect many cancerous proteins, could also be used to distinguish the type of a tumor or how it is responding to treatment.
Published CO2 recycling: What is the role of the electrolyte?
(via sciencedaily.com) Original source The greenhouse gas carbon dioxide can be converted into useful hydrocarbons by electrolysis. The design of the electrolysis cell is crucial in this process. The so-called zero-gap cell is particularly suitable for industrial processes. But there are still problems: The cathodes clog up quickly.
Published Outstanding performance of organic solar cell using tin oxide
(via sciencedaily.com) Original source Organic solar cells have a photoactive layer that is made from polymers and small molecules. The cells are very thin, can be flexible, and are easy to make. However, the efficiency of these cells is still much below that of conventional silicon-based ones. Applied physicists have now fabricated an organic solar cell with an efficiency of over 17 percent, which is in the top range for this type of material. It has the advantage of using an unusual device structure that is produced using a scalable technique.
Published Researchers team up with national lab for innovative look at copper reactions
(via sciencedaily.com) Original source Researchers are working to get a better look at how peroxides on the surface of copper oxide promote the oxidation of hydrogen but inhibit the oxidation of carbon monoxide, allowing them to steer oxidation reactions.
Published Cryo-imaging lifts the lid on fuel cell catalyst layers
(via sciencedaily.com) Original source Thanks to a novel combination of cryogenic transmission electron tomography and deep learning, EPFL researchers have provided a first look at the nanostructure of platinum catalyst layers, revealing how they could be optimized for fuel cell efficiency.
Published Greener batteries
(via sciencedaily.com) Original source Our modern rechargeable batteries, such as lithium-ion batteries, are anything but sustainable. One alternative is organic batteries with redox-organic electrode materials (OEMs), which can be synthesized from natural 'green' materials. A team has now introduced a new OEM for aqueous organic high-capacity batteries that can be easily and cheaply recycled.
Published Reinforcement learning: From board games to protein design
(via sciencedaily.com) Original source An AI strategy proven adept at board games like Chess and Go, reinforcement learning, has now been adapted for a powerful protein design program. The results show that reinforcement learning can do more than master board games. When trained to solve long-standing puzzles in protein science, the software excelled at creating useful molecules. In one experiment, proteins made with the new approach were found to be more effective at generating useful antibodies in mice than were previous methods. If this method is applied to the right research problems, it likely could accelerate progress in a variety of scientific fields.
Published AI system can generate novel proteins that meet structural design targets
(via sciencedaily.com) Original source A new machine-learning system can generate protein designs with certain structural features, and which do not exist in nature. These proteins could be utilized to make materials that have similar mechanical properties to existing materials, like polymers, but which would have a much smaller carbon footprint.
Published New findings pave the way for stable organic solar cells that may enable cheap and renewable electricity generation
(via sciencedaily.com) Original source Organic solar cells show great promise for clean energy applications. However, photovoltaic modules made from organic semiconductors do not maintain their efficiency for long enough under sunlight for real world applications. Scientists have now revealed an important reason why organic solar cells rapidly degrade under operation. This new insight will drive the design of more stale materials for organic semiconductor-based photovoltaics, thus enabling cheap and renewable electricity generation.
Published Novel nanocages for delivery of small interfering RNAs
(via sciencedaily.com) Original source Small interfering RNAs (siRNAs) are novel therapeutics that can be used to treat a wide range of diseases. This has led to a growing demand for selective, efficient, and safe ways of delivering siRNA in cells. Now, in a cooperation between the Universities of Amsterdam and Leiden, researchers have developed dedicated molecular nanocages for siRNA delivery. In a paper just out in the Journal Chem they present nanocages that are easy to prepare and display tuneable siRNA delivery characteristics.
Published Using machine learning to find reliable and low-cost solar cells
(via sciencedaily.com) Original source Hybrid perovskites are organic-inorganic molecules that have received a lot of attention over the past 10 years for their potential use in renewable energy. Some are comparable in efficiency to silicon for making solar cells, but they are cheaper to make and lighter, potentially allowing a wide range of applications, including light-emitting devices. However, they tend to degrade way more readily than silicon when exposed to moisture, oxygen, light, heat, and voltage. Researchers used machine learning and high-throughput experiments to identify perovskites with optimal qualities out of the very large field of possible structures.