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Categories: Chemistry: Organic Chemistry, Engineering: Biometric
Published AI-driven lab speeds catalysis research
(via sciencedaily.com) Original source Researchers have developed a 'self-driving' lab that uses artificial intelligence (AI) and automated systems to provide in-depth analyses of catalytic reactions used in chemical research and manufacturing. The new tool, called Fast-Cat, can provide more information in five days than is possible in six months of conventional testing.
Published Cutting-edge 'protein lawnmower' created
(via sciencedaily.com) Original source Scientists have designed the first synthetic protein-based motor which harnesses biological reactions to fuel and propel itself. 'Imagine if a Roomba could be powered only by the dirt it picks up,' says one of the authors of the study. The motor uses the digestive enzyme trypsin to cut the peptides and convert them into the energy it needs to propel itself.
Published The mutual neutralization of hydronium and hydroxide
(via sciencedaily.com) Original source Researchers have been able to directly visualize the neutral products of the mutual neutralization of hydronium and hydroxide, and report three different product channels: two channels were attributed to a predominant electron-transfer mechanism, and a smaller channel was associated with proton transfer. The two-beam collision experiment is an important step toward understanding the quantum dynamics of this fundamental reaction.
Published Chemists synthesize unique anticancer molecules using novel approach
(via sciencedaily.com) Original source Nearly 30 years ago, scientists discovered a unique class of anticancer molecules in a family of bryozoans, a phylum of marine invertebrates found in tropical waters. The chemical structures of these molecules, which consist of a dense, highly complex knot of oxidized rings and nitrogen atoms, has attracted the interest of organic chemists worldwide, who aimed to recreate these structures from scratch in the laboratory. However, despite considerable effort, it has remained an elusive task. Until now, that is. A team of chemists has succeeded in synthesizing eight of the compounds for the first time using an approach that combines inventive chemical strategy with the latest technology in small molecule structure determination.
Published This tiny, tamper-proof ID tag can authenticate almost anything
(via sciencedaily.com) Original source A cryptographic tag uses terahertz waves to authenticate items by recognizing the unique pattern of microscopic metal particles that are mixed into the glue that sticks the tag to the item's surface.
Published Advanced artificial photosynthesis catalyst uses CO2 more efficiently to create biodegradable plastics
(via sciencedaily.com) Original source A research team that had previously succeeded in synthesizing fumaric acid using bicarbonate and pyruvic acid, and carbon dioxide collected directly from the gas phase as one of the raw materials, has now created a new photosensitizer and developed a new artificial photosynthesis technology, effectively doubling the yield of fumaric acid production compared to the previous method. The results of this research are expected to reduce carbon dioxide emissions and provide an innovative way to produce biodegradable plastics while reusing waste resources.
Published With just a little electricity, researchers boost common catalytic reactions
(via sciencedaily.com) Original source A simple new technique could boost the efficiency of some key chemical processing, by up to a factor of 100,000, researchers report. The reactions are at the heart of petrochemical processing, pharmaceutical manufacturing, and many other industrial chemical processes.
Published Microscopy: Overcoming the traditional resolution limit for the fast co-tracking of molecules
(via sciencedaily.com) Original source Researchers have developed an innovative method to simultaneously track rapid dynamic processes of multiple molecules at the molecular scale.
Published Not only in information technology: Restart also works in chemical simulations
(via sciencedaily.com) Original source Scientists have discovered that a known practice in information technology can also be applied to chemistry. Researchers found that to enhance the sampling in chemical simulations, all you need to do is stop and restart.
Published Key advance for capturing carbon from the air
(via sciencedaily.com) Original source A chemical element so visually striking that it was named for a goddess shows a 'Goldilocks' level of reactivity -- neither too much nor too little -- that makes it a strong candidate as a carbon scrubbing tool.
Published Towards A Better Way of Releasing Hydrogen Stored in Hydrogen Boride Sheets
(via sciencedaily.com) Original source Hydrogen stored in hydrogen boride sheets can be efficiently released electrochemically, report scientists. Through a series of experiments, they demonstrated that dispersing these sheets in an organic solvent and applying a small voltage is enough to release all the stored hydrogen efficiently. These findings suggest hydrogen boride sheets could soon become a safe and convenient way to store and transport hydrogen, which is a cleaner and more sustainable fuel.
Published Illuminating the invisible: Detecting proteins linked to diseases
(via sciencedaily.com) Original source Engineers have pioneered a new way to visualize the smallest protein clusters, skirting the physical limitations of light-powered microscopes and opening new avenues for detecting the proteins implicated in diseases like Alzheimer's and testing new treatments.
Published Greenhouse gas repurposed
(via sciencedaily.com) Original source Cutting-edge research converted waste carbon dioxide into a potential precursor for chemicals and carbon-free fuel.
Published BESSY II: Molecular orbitals determine stability
(via sciencedaily.com) Original source Carboxylic acid dianions (fumarate, maleate and succinate) play a role in coordination chemistry and to some extent also in the biochemistry of body cells. A team has now analyzed their electronic structures using RIXS in combination with DFT simulations. The results provide information not only on electronic structures but also on the relative stability of these molecules which can influence an industry's choice of carboxylate dianions, optimizing both the stability and geometry of coordination polymers.
Published Chemists decipher reaction process that could improve lithium-sulfur batteries
(via sciencedaily.com) Original source Lithium-sulfur batteries have exceptional theoretical capacity and performance in combination with an element in abundant supply. But the intricate reaction mechanism, particularly during discharge, has been challenging to solve. Researchers have identified the key pathways to a complex sulfur reduction reaction that leads to energy loss and reduced battery life span. The study's findings establish the whole reaction network for the first time and offer insight into electrocatalyst design for improved batteries.
Published Improving fuel cell durability with fatigue-resistant membranes
(via sciencedaily.com) Original source In hydrogen fuel cells, electrolyte membranes frequently undergo deformation and develop cracks during operation. A research team has recently introduced a fatigue-resistant polymer electrolyte membrane for hydrogen fuel cells, employing an interpenetrating network of Nafion (a plastic electrolyte) and perfluoropolyether (a rubbery polymer). This innovation will not only improve fuel cell vehicles but also promises advancements in diverse technologies beyond transportation, spanning applications from drones to desalination filters and backup power sources.
Published Ultra-sensitive lead detector could significantly improve water quality monitoring
(via sciencedaily.com) Original source Engineers have developed an ultra-sensitive sensor made with graphene that can detect extraordinarily low concentrations of lead ions in water. The device achieves a record limit of detection of lead down to the femtomolar range, which is one million times more sensitive than previous technologies.
Published A sleeker facial recognition technology tested on Michelangelo's David
(via sciencedaily.com) Original source Many people are familiar with facial recognition systems that unlock smartphones and game systems or allow access to our bank accounts online. But the current technology can require boxy projectors and lenses. Now, researchers report on a sleeker 3D surface imaging system with flatter, simplified optics. In proof-of-concept demonstrations, the new system recognized the face of Michelangelo's David just as well as an existing smartphone system.
Published Edge-to-edge assembly technique for 2D nanosheets
(via sciencedaily.com) Original source A research team develops edge-to-edge assembly technique for 2D nanosheets.
Published Intensifying the production of high-value compounds from industrial waste
(via sciencedaily.com) Original source New research demonstrates how glycerol carbonate, a biosourced industrial additive, can be produced in record time using CO2 and a by-product of the cooking oil recycling industry. The process relies on a hybrid approach combining fundamental physical organic chemistry and applied flow process technology. Two industrial wastes are thus converted into glycerol carbonate, a biosourced rising star with high added-value.