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Categories: Chemistry: Organic Chemistry, Engineering: Graphene
Published Reduction of esters by a novel photocatalyst
(via sciencedaily.com) Original source A ubiquitous compound, called ester can be broken down to produce desirable alcohols and other chemicals for use across industries including pharmaceuticals and cosmetics, but the process can be costly, both financially and in terms of the environment. Researchers developed a novel photocatalyst 'N-BAP.' When irradiated with blue light, the photocatalyst reduces esters in the presence of oxalate, a negatively charged molecule found widely in nature, resulting in the desired alcohols.
Published Strengthener for graphene
(via sciencedaily.com) Original source Layers of carbon atoms in a honeycomb array are a true supermaterial: their unusually high conductivity and favorable mechanical properties could further the development of bendable electronics, new batteries, and innovative composite materials for aeronautics and space flight. However, the development of elastic and tough films remains a challenge. A research team has now introduced a method to overcome this hurdle: they linked graphene nanolayers via 'extendable' bridging structures.
Published Self-assembling and disassembling swarm molecular robots via DNA molecular controller
(via sciencedaily.com) Original source Researchers have succeeded in developing a DNA-based molecular controller. Crucially, this controller enables the autonomous assembly and disassembly of molecular robots, as opposed to manually directing it.
Published Scientists preserve DNA in an amber-like polymer
(via sciencedaily.com) Original source With their 'T-REX' method, researchers developed a glassy, amber-like polymer that can be used for long-term storage of DNA, such as entire human genomes or digital files such as photos.
Published 'Synthetic' cell shown to follow chemical directions and change shape, a vital biological function
(via sciencedaily.com) Original source In a feat aimed at understanding how cells move and creating new ways to shuttle drugs through the body, scientists say they have built a minimal synthetic cell that follows an external chemical cue and demonstrates a governing principle of biology called 'symmetry breaking.'
Published A 'liquid battery' advance
(via sciencedaily.com) Original source A team aims to improve options for renewable energy storage through work on an emerging technology -- liquids for hydrogen storage.
Published Algae offer real potential as a renewable electricity source
(via sciencedaily.com) Original source The need to transition away from fossil fuels to more sustainable energy production is critical. That's why a team of researchers is looking at a potential power source that not only produces no carbon emissions but removes carbon as it works: algae.
Published Changes Upstream: RIPE team uses CRISPR/Cas9 to alter photosynthesis for the first time
(via sciencedaily.com) Original source Scientists used CRISPR/Cas9 to increase gene expression in rice by changing its upstream regulatory DNA. While other studies have used the technology to knock out or decrease the expression of genes, this study, is an unbiased gene-editing approach to increase gene expression and downstream photosynthetic activity. The approach is more difficult than transgenic breeding, but could potentially preempt regulatory issues by changing DNA already within the plant, allowing the plants to get in the hands of farmers sooner.
Published Scientists 'read' the messages in chemical clues left by coral reef inhabitants
(via sciencedaily.com) Original source What species live in this coral reef, and are they healthy? Chemical clues emitted by marine organisms might hold that information. But in underwater environments, invisible compounds create a complex 'soup' that is hard for scientists to decipher. Now, researchers have demonstrated a way to extract and identify these indicator compounds in seawater. They found metabolites previously undetected on reefs, including three that may represent different reef organisms.
Published Crystal engineering modifies 2D metal halide perovskites into 1D nanowires
(via sciencedaily.com) Original source Engineers have created a patent-pending method that creates layered perovskite nanowires with exceptionally well-defined and flexible cavities that exhibit a wide range of unusual optical properties beyond conventional perovskites.
Published New method of DNA testing: Expanding scientific innovation
(via sciencedaily.com) Original source A team of researchers has developed a new method for target DNA sequence amplification, testing and analysis.
Published Electrified charcoal 'sponge' can soak up CO2 directly from the air
(via sciencedaily.com) Original source Researchers have developed a low-cost, energy-efficient method for making materials that can capture carbon dioxide directly from the air. Researchers used a method similar to charging a battery to instead charge activated charcoal, which is often used in household water filters.
Published Towards next-gen functional materials: direct observation of electron transfer in solids
(via sciencedaily.com) Original source Nanoscale electron transfer (ET) in solids is fundamental to the development of multifunctional materials. However, ET in solids is not yet clearly understood. Now, researchers achieved a direct observation of solid-state ET through X-ray crystal analysis by fabricating a novel double-walled non-covalent crystalline nanotube, which can absorb electron donor molecules and maintain its crystalline structure during ET. This innovative approach can lead to the design of novel functional materials soon.
Published Paving the way for hydrogen from algae enzymes
(via sciencedaily.com) Original source Under certain conditions, some algae are able to produce hydrogen -- a much sought-after green energy source. Its production takes place in the unique catalytic center of the unicellular algae and is only possible if certain cofactors of the relevant proteins are present. Researchers have identified how such a cofactor, the so-called hydrogen cluster, is assembled. Specifically, they describe the previously unexplained role of the enzyme HydF, which is involved in the final steps of assembly.
Published Scientists develop most sensitive way to observe single molecules
(via sciencedaily.com) Original source A technical achievement marks a significant advance in the burgeoning field of observing individual molecules without the aid of fluorescent labels. While these labels are useful in many applications, they alter molecules in ways that can obscure how they naturally interact with one another. The new label-free method makes the molecules so easy to detect, it is almost as if they had labels.
Published New method makes hydrogen from solar power and agricultural waste
(via sciencedaily.com) Original source Engineers have helped design a new method to make hydrogen gas from water using only solar power and agricultural waste such as manure or husks. The method reduces the energy needed to extract hydrogen from water by 600%, creating new opportunities for sustainable, climate-friendly chemical production.
Published Editing without 'cutting': Molecular mechanisms of new gene-editing tool revealed
(via sciencedaily.com) Original source New research has determined the spatial structure of various processes of a novel gene-editing tool called 'prime editor.' Functional analysis based on these structures also revealed how a 'prime editor' could achieve reverse transcription, synthesizing DNA from RNA, without 'cutting' both strands of the double helix. Clarifying these molecular mechanisms contributes greatly to designing gene-editing tools accurate enough for gene therapy treatments.
Published Graphene gets cleaned up
(via sciencedaily.com) Original source Engineers establish the link between oxygen and graphene quality and present an oxygen-free chemical vapor deposition method (OF-CVD) that can reproducibly create high-quality samples for large-scale production. The graphene they synthesized with their new method proved nearly identical to exfoliated samples and was capable of producing the fractional quantum Hall effect.
Published Researchers create materials with unique combo of stiffness, thermal insulation
(via sciencedaily.com) Original source Researchers have demonstrated the ability to engineer materials that are both stiff and capable of insulating against heat. This combination of properties is extremely unusual and holds promise for a range of applications, such as the development of new thermal insulation coatings for electronic devices.
Published Solving the problems of proton-conducting perovskites for next-generation fuel cells
(via sciencedaily.com) Original source As a newly developed perovskite with a large amount of intrinsic oxygen vacancies, BaSc0.8W0.2O2.8 achieves high proton conduction at low and intermediate temperatures, report scientists. By the donor doping of large W6+, this material can take up more water to increase its proton concentration, as well as reduce the proton trapping through electrostatic repulsion between the dopant and proton. These findings could pave the way to the rational design of novel perovskites for protonic ceramic fuel cells (PCFCs) and electrolysis cells (PCECs).