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Categories: Chemistry: Organic Chemistry, Engineering: Nanotechnology

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Nanoscale electron transfer (ET) in solids is fundamental to the development of multifunctional materials. However, ET in solids is not yet clearly understood. Now, researchers achieved a direct observation of solid-state ET through X-ray crystal analysis by fabricating a novel double-walled non-covalent crystalline nanotube, which can absorb electron donor molecules and maintain its crystalline structure during ET. This innovative approach can lead to the design of novel functional materials soon.

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Polarized light waves spin clockwise or counterclockwise as they travel, with one direction behaving differently than the other as it interacts with molecules. This directionality, called chirality or handedness, could provide a way to identify and sort specific molecules for use in biomedicine applications, but researchers have had limited control over the direction of the waves -- until now.

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A team of researchers has created a new way to visualize crystals by peering inside their structures, akin to having X-ray vision. Their new technique -- which they aptly named 'Crystal Clear' -- combines the use of transparent particles and microscopes with lasers that allow scientists to see each unit that makes up the crystal and to create dynamic three-dimensional models.

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Team develops a flexible and stretchable device capable of omnidirectional color wavelength control.

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Scientists have employed artificial intelligence techniques to improve the design and production of nanofibers used in wearable nanofiber acoustic energy harvesters (NAEH). These acoustic devices capture sound energy from the environment and convert it into electrical energy, which can then be applied in useful devices, such as hearing aids.

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Under certain conditions, some algae are able to produce hydrogen -- a much sought-after green energy source. Its production takes place in the unique catalytic center of the unicellular algae and is only possible if certain cofactors of the relevant proteins are present. Researchers have identified how such a cofactor, the so-called hydrogen cluster, is assembled. Specifically, they describe the previously unexplained role of the enzyme HydF, which is involved in the final steps of assembly.

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A technical achievement marks a significant advance in the burgeoning field of observing individual molecules without the aid of fluorescent labels. While these labels are useful in many applications, they alter molecules in ways that can obscure how they naturally interact with one another. The new label-free method makes the molecules so easy to detect, it is almost as if they had labels.

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Engineers have helped design a new method to make hydrogen gas from water using only solar power and agricultural waste such as manure or husks. The method reduces the energy needed to extract hydrogen from water by 600%, creating new opportunities for sustainable, climate-friendly chemical production.

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Researchers probed the transit of cations across a nanopore membrane for the generation of osmotic energy. The team controlled the passage of cations across the membrane using a voltage applied to a gate electrode. This control allowed the cation-selective transport to be tuned from essentially zero to complete cation selectivity. The findings are expected to support the application of blue energy solutions for sustainable energy alternatives worldwide.

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New research has determined the spatial structure of various processes of a novel gene-editing tool called 'prime editor.' Functional analysis based on these structures also revealed how a 'prime editor' could achieve reverse transcription, synthesizing DNA from RNA, without 'cutting' both strands of the double helix. Clarifying these molecular mechanisms contributes greatly to designing gene-editing tools accurate enough for gene therapy treatments.

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Researchers have demonstrated the ability to engineer materials that are both stiff and capable of insulating against heat. This combination of properties is extremely unusual and holds promise for a range of applications, such as the development of new thermal insulation coatings for electronic devices.

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As a newly developed perovskite with a large amount of intrinsic oxygen vacancies, BaSc0.8W0.2O2.8 achieves high proton conduction at low and intermediate temperatures, report scientists. By the donor doping of large W6+, this material can take up more water to increase its proton concentration, as well as reduce the proton trapping through electrostatic repulsion between the dopant and proton. These findings could pave the way to the rational design of novel perovskites for protonic ceramic fuel cells (PCFCs) and electrolysis cells (PCECs).

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Researchers have outlined a way to manipulate water molecules to make CO2R more efficient, with the ultimate goal of creating a clean energy loop. Through their new method, the team was able to perform CO2R with nearly 100% efficiency under mildly acidic conditions, using either gold or zinc as catalysts.

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Researchers have developed a new technique to view living mammalian cells. The team used a powerful laser, called a soft X-ray free electron laser, to emit ultrafast pulses of illumination at the speed of femtoseconds, or quadrillionths of a second. With this they could capture images of carbon-based structures in living cells for the first time, before the soft X-ray radiation damaged them.

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Researchers have fabricated a device no wider than a human hair that will help physicists investigate the fundamental nature of matter and light. Their findings could also support the development of more efficient lasers, which are used in fields ranging from medicine to manufacturing.

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Researchers discovered that sulfur trioxide can form products other than sulfuric acid in the atmosphere by interacting with organic and inorganic acids. These previously uncharacterized acid sulfuric anhydride products are almost certainly key contributors to atmospheric new particle formation and a way to efficiently incorporate carboxylic acids into atmospheric nanoparticles. Better prediction of aerosol formation can help curb air pollution and reduce uncertainties concerning climate change.

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In a recent study, researchers developed modified norcorrole molecules whose side chains favored the formation of columnar -stacking structures. Using these compounds, they produced liquid crystals with high electrical conductivity and thermotropic properties. Their findings open up new design avenues for materials useful in electronics, sensing, optics, and biomedicine.

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Organosulfur skeletons are crucial in many fields, including pharmaceuticals and electronics. Synthesizing organosulfur skeletons requires o-bromobenzenethiols. However, conventional methods face challenges due to quick oxidation and formation of highly reactive intermediates. Researchers have now developed a new method for synthesizing o-bromobenzenethiols from aryne intermediates via bromothiolation. This method can pave the way for the synthesis of new organosulfur compounds with applications in diverse fields.

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Engineers have developed a wearable ultrasound patch that can offer continuous, non-invasive monitoring of blood flow in the brain. The soft and stretchy patch can be comfortably worn on the temple to provide three-dimensional data on cerebral blood flow--a first in wearable technology.

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Researchers have used computational design methods to develop non-metal organic porous framework materials, with potential applications in areas such as catalysis, water capture or hydrogen storage.